The Science and Engineering of Materials (MindTap Course List)
7th Edition
ISBN: 9781305076761
Author: Donald R. Askeland, Wendelin J. Wright
Publisher: Cengage Learning
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Chapter 2, Problem 2.44P
To determine
The reason of the low modulus of elasticity of thermoplastic polymers
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sketch the generalized stress-strain curve for a semi-crystalline thermoplastic polymer.
1. Explain in 1-3 bullets how as a practicing engineer you determine the yield strength of a thermoplastic polymer from a tensile stress-strain curve.
2. Explain what is happening at the yield strength for a thermoplastic polymer from a physical standpoint in 1-3 bullets. (e.g. what are the atoms or polymer chains doing?)
Many thermoplastics are brittle below their glass transition temperature. Describe the particular phenomenon that can precede fracture (crack propagation) in some of these?
Chapter 2 Solutions
The Science and Engineering of Materials (MindTap Course List)
Ch. 2 - Prob. 2.1PCh. 2 - Prob. 2.2PCh. 2 - Prob. 2.3PCh. 2 - Why is it important to consider the structure of a...Ch. 2 - Prob. 2.5PCh. 2 - Prob. 2.6PCh. 2 - Prob. 2.7PCh. 2 - Prob. 2.8PCh. 2 - Prob. 2.9PCh. 2 - Prob. 2.10P
Ch. 2 - Write the electron configuration for the element...Ch. 2 - Prob. 2.12PCh. 2 - Prob. 2.13PCh. 2 - Prob. 2.14PCh. 2 - Prob. 2.15PCh. 2 - Prob. 2.16PCh. 2 - Prob. 2.17PCh. 2 - Prob. 2.18PCh. 2 - Prob. 2.19PCh. 2 - Prob. 2.20PCh. 2 - Prob. 2.21PCh. 2 - Prob. 2.22PCh. 2 - Prob. 2.23PCh. 2 - Prob. 2.24PCh. 2 - Prob. 2.25PCh. 2 - Prob. 2.26PCh. 2 - What are the bonding mechanisms in thermoplastics?Ch. 2 - Prob. 2.28PCh. 2 - Materials such as silicon carbide (SiC) and...Ch. 2 - Prob. 2.30PCh. 2 - Prob. 2.31PCh. 2 - Prob. 2.32PCh. 2 - Prob. 2.33PCh. 2 - Prob. 2.34PCh. 2 - In order to increase the operating temperature of...Ch. 2 - Prob. 2.36PCh. 2 - Prob. 2.37PCh. 2 - Prob. 2.38PCh. 2 - Prob. 2.39PCh. 2 - Prob. 2.40PCh. 2 - Would you expect MgO or magnesium to have the...Ch. 2 - Would you expect (Al2O3) or aluminum to have the...Ch. 2 - Prob. 2.43PCh. 2 - Prob. 2.44PCh. 2 - Steel is coated with a thin layer of ceramic to...Ch. 2 - Prob. 2.46PCh. 2 - Prob. 2.47PCh. 2 - Prob. 2.48PCh. 2 - Prob. 2.49PCh. 2 - Prob. 2.50PCh. 2 - Prob. 2.51DPCh. 2 - Turbine blades used in jet engines can be made...Ch. 2 - You want to use a material that can be used for...Ch. 2 - Prob. 2.1KP
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- There are 4 classifications of structural molecular characteristics of polymers - Linear, Network, Crosslinked. What is the final type? Answer:arrow_forwardMolecular weight data for some polymer are tabulated here. Compute (a) the number-average molecular weight, (b) the weight-average molecular weight. (c) If it is known that this material's degree of polymerization is 710, which one of the polymers listed in Table 14.3 is this polymer? Why? Molecular Weight Range g/mol 15,000-30,000 Xi Wi 0.04 0.01 30,000-45,000 0.07 0.04 45,000-60,000 0.16 0.11 60,000-75,000 0.26 0.24 75,000-90,000 0.24 0.27 90,000 105,000 0.12 0.16 105,000-120,000 0.08 0.12 120,000-135,000 0.03 0.05arrow_forwardA panel of poly(methyl methacrylate) is bolted in the long direction only at 50°C between two other components with zero coefficients of expansion. What is the stress on the polymer at 0°C? Will the polymer break?arrow_forward
- A composite sample of carbon reinforced epoxy has dimensions of 12 in x 12 in x 0.25 in and mass of 1.8 lb. The carbon fibers have a modulus of elasticity of 50(106) lb/in² and a density of 0.069 lb/in³. The epoxy matrix has modulus of elasticity of 0.61(106) lb/in² and a density of 0.042 lb/in³. What is the volume fraction of (a) the carbon fibers and (b) the epoxy matrix in the sample? Assume there are no voids in the sample. What is the predicted value for the modulus of elasticity (c) in the longitudinal direction and (d) the perpendicular to the carbon fibers?arrow_forwardFrom the attached image. Annotate and explain the phases of the polymer stress-strain curve.arrow_forwardIn comparison with a brittle polymer, a ductile polymer yields and then breaks at a higher stress and strain The elongation at break reduces as the temperature of the sample is reduced The stress-strain curve for vulcanized elastomers has a greater slope than unvulcanized polymers throughout The elongation at break is greater for elastomers than tough, hard thermoplasticsarrow_forward
- Calculate the modulus of rigidity (shear modulus) of an epoxy resin if the modulus of elasticity (Young's modulus) E = 3.5 GPa and the Poisson's ratio = 0.35. Select one: a. G = 2.6 GPa b. G = 10 GPa c. G = 3.15 GPa d. G= 0.1 GPa e. G = 1.3 GPaarrow_forwardCalculate the composite elastic modulus for polyester reinforced with 60% volume fraction of carbon fibers under isostrain longitudinal conditions. Modulus of elasticity of polyester is 2900 MPa and for carbon fiber is 175,000 MPa.arrow_forwardDraw stress-strain graphs for two polymers: one is stiffer than the other and exhibits ayield point and the other shows no clear yield point but is much tougher.arrow_forward
- Why do thermoplastic polymers start to turn white as they are plastically deformed?arrow_forwardConnecting rod (as shown below) is a car part that connects engine piston to crankshaft and converts reciprocating motion into rotating motion. It performs under load at high temperature around 150°C. Long carbon fiber thermoplastic composite (LFT) with 30% carbon fiber has been considered to replace metal (steel or aluminum) rod to improve efficiency. Based on the data for different polymers listed in the table above, which polymer(s) would you choose as the polymer matrix for the connecting rod? What is your rationale?arrow_forwardFor a given polymer, the activation energy for the stress relaxation was measured to be 59kj/mol. If the stress relaxation time for this polymer at 7 degree Celsius is 3150 seconds. What is the relaxation time at 110 degree Celsiusarrow_forward
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