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Interpretation:
The difference between the expansion of work against constant pressure and work of reversible expansion has to be explained along with their consequences.
Concept Introduction:
Reversible process:
A
Irreversible process:
An irreversible process is the process where the system and surrounding both cannot come back to their original state if the process is reversed.
Expansion work:
Expansion work is the work done when a system expands against an opposing pressure. When a gas expands, work is done on the surroundings and the work done is equal to the area under the pressure-volume curve.
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Chapter 2 Solutions
Elements Of Physical Chemistry
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- Use a textbook or other valid source to research the physical and chemical properties of each element listed in Data Table 1 using the following as a guideline: Ductile (able to be deformed without losing toughness) and malleable (able to be hammered or pressed permanently out of shape without breaking or cracking) or not ductile or malleable Good, semi, or poor conductors of electricity and heat High or low melting and boiling points Occur or do not occur uncombined/freely in nature High, intermediate, or low reactivity Loses or gains electrons during reactions or is not reactivearrow_forwardProvide the Physical and Chemical Properties of Elements of the following elements listedarrow_forwardQuestions 4 and 5arrow_forward
- For a titration of 40.00 mL of 0.0500 M oxalic acid H2C2O4 with 0.1000 M KOH, calculate the pH at each of the following volume of KOH used in the titration: 1) before the titration begin;2) 15 mL; 3) 20 mL; 4) 25 mL; 5) 40 mL; 6) 50 mL. Ka1 = 5.90×10^-2, Ka2 = 6.50×10^-5 for oxalic acid.arrow_forwardPredict the major organic product(s), if any, of the following reactions. Assume all reagents are in excess unless otherwise indicated.arrow_forwardPredict the major organic product(s), if any, of the following reactions. Assume all reagents are in excess unless otherwise indicated.arrow_forward
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