EBK PHYSICAL CHEMISTRY
EBK PHYSICAL CHEMISTRY
3rd Edition
ISBN: 9780133556094
Author: Reid
Publisher: YUZU
Question
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Chapter 2, Problem 2.39NP

(a)

Interpretation Introduction

Interpretation: The largest mass lifted through a height h in the expression needs to be determined.

Concept Introduction: The change in internal energy is calculated as follows:

  ΔU=nCV.m(TfTi)

Here, n is number of moles, CV,m is molar heat at constant volume and T is temperature.

The work done is represented as follows:

  w=PexternalΔV

Here, P is external pressure and ΔV is change in volume.

The enthalpy of a reaction is represented as follows:

  ΔH=ΔU+nRΔT

Here, n is number of moles, R is Universal gas constant and ΔT is change in temperature.

(b)

Interpretation Introduction

Interpretation: The smallest mass that must fall through the height in order to restore the system needs to be determined.

Concept Introduction: The change in internal energy is calculated as follows:

  ΔU=nCV.m(TfTi)

Here, n is number of moles, CV,m is molar heat at constant volume and T is temperature.

The work done is represented as follows:

  w=PexternalΔV

Here, P is external pressure and ΔV is change in volume.

The enthalpy of a reaction is represented as follows:

  ΔH=ΔU+nRΔT

Here, n is number of moles, R is Universal gas constant and ΔT is change in temperature.

(c)

Interpretation Introduction

Interpretation: The values of masses needs to be calculate in part (a) and (b).

Concept Introduction: The change in internal energy is calculated as follows:

  ΔU=nCV.m(TfTi)

Here, n is number of moles, CV,m is molar heat at constant volume and T is temperature.

The work done is represented as follows:

  w=PexternalΔV

Here, P is external pressure and ΔV is change in volume.

The enthalpy of a reaction is represented as follows:

  ΔH=ΔU+nRΔT

Here, n is number of moles, R is Universal gas constant and ΔT is change in temperature.

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