Bundle: Chemistry for Engineering Students, 3rd, Loose-Leaf + OWLv2 with QuickPrep 24-Months Printed Access Card
3rd Edition
ISBN: 9781305367388
Author: Lawrence S. Brown, Tom Holme
Publisher: Cengage Learning
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Question
Chapter 2, Problem 2.38PAE
Interpretation Introduction
Interpretation:
differentiate covalent and ionic bonds.
Concept introduction:
The bonds are formed due to mutual interactions between two atoms. The bonds are formed to gain stability.
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(a
4 shows scanning electron microscope (SEM) images of extruded
actions of packing bed for two capillary columns of different diameters,
al 750 (bottom image) and b) 30-μm-i.d. Both columns are packed with the
same stationary phase, spherical particles with 1-um diameter.
A) When the columns were prepared, the figure shows that the column with
the larger diameter has more packing irregularities. Explain this observation.
B) Predict what affect this should have on band broadening and discuss your
prediction using the van Deemter terms.
C) Does this figure support your explanations in application question 33?
Explain why or why not and make any changes in your answers in light of
this figure.
Figure 4 SEM images of
sections of packed columns
for a) 750 and b) 30-um-i.d.
capillary columns.³
fcrip
= ↓ bandwidth Il temp
32. What impact (increase, decrease, or no change) does each of the following conditions have on the individual
components of the van Deemter equation and consequently, band broadening?
Increase temperature
Longer column
Using a gas mobile phase
instead of liquid
Smaller particle stationary phase
Multiple Paths
Diffusion
Mass Transfer
34. Figure 3 shows Van Deemter plots for a solute molecule using different column inner diameters (i.d.).
A) Predict whether decreasing the column inner diameters increase or decrease bandwidth.
B) Predict which van Deemter equation coefficient (A, B, or C) has the greatest effect on increasing or
decreasing bandwidth as a function of i.d. and justify your answer.
Figure 3 Van Deemter plots for hydroquinone using different column inner diameters (i.d. in μm). The data was
obtained from liquid chromatography experiments using fused-silica capillary columns packed with 1.0-μm particles.
35
20
H(um)
큰 20
15
90
0+
1500
100
75
550
01
02
594
05
μ(cm/sec)
30
15
10
Chapter 2 Solutions
Bundle: Chemistry for Engineering Students, 3rd, Loose-Leaf + OWLv2 with QuickPrep 24-Months Printed Access Card
Ch. 2 - Name at least three common polymers and give...Ch. 2 - Prob. 2COCh. 2 - Describe the nuclear model for the atom and...Ch. 2 - Prob. 4COCh. 2 - Prob. 5COCh. 2 - Prob. 6COCh. 2 - Prob. 7COCh. 2 - Prob. 8COCh. 2 - Prob. 9COCh. 2 - Prob. 10CO
Ch. 2 - Prob. 2.1PAECh. 2 - How do polymers compare to their respective...Ch. 2 - Look around you and identify several objects that...Ch. 2 - Prob. 2.4PAECh. 2 - The fact that a polymer’s physical properties...Ch. 2 - Use the web to research the amount of PVC polymer...Ch. 2 - Prob. 2.7PAECh. 2 - Prob. 2.8PAECh. 2 - Why is the number of protons called the atomic...Ch. 2 - 2.10 Which isotope in each pair contains more...Ch. 2 - 2.11 Define the term isotope.Ch. 2 - 2.12 Write the complete atomic symbol for each of...Ch. 2 - 2.13 How many electrons, protons, and neutrons are...Ch. 2 - 2.14 Consider the following nuclear symbols. How...Ch. 2 - 2.15 Mercury is 16.716 times more massive than...Ch. 2 - Prob. 2.16PAECh. 2 - Prob. 2.17PAECh. 2 - The element gallium, used in gallium arsenide...Ch. 2 - 2.17 The atomic weight of copper is 63.55 amu....Ch. 2 - The following table presents the abundances and...Ch. 2 - 2.19 Naturally occurring uranium consists of two...Ch. 2 - Prob. 2.22PAECh. 2 - Prob. 2.23PAECh. 2 - Prob. 2.24PAECh. 2 - Prob. 2.25PAECh. 2 - 2.22 Provide the symbol of the following...Ch. 2 - Prob. 2.27PAECh. 2 - 2.24 Identify each of the following species as an...Ch. 2 - 2.25 Write the atomic symbol for the element whose...Ch. 2 - 2.26 In what region of the periodic table are you...Ch. 2 - Prob. 2.31PAECh. 2 - Prob. 2.32PAECh. 2 - Prob. 2.33PAECh. 2 - 2.30 Using Coulomb’s law, explain how the...Ch. 2 - Prob. 2.35PAECh. 2 - 2.32 Which of the following formulas contains the...Ch. 2 - Prob. 2.37PAECh. 2 - Prob. 2.38PAECh. 2 - Prob. 2.39PAECh. 2 - Prob. 2.40PAECh. 2 - Prob. 2.41PAECh. 2 - Prob. 2.42PAECh. 2 - Describe how a covalently bonded molecule is...Ch. 2 - 2.36 Explain the difference between a molecular...Ch. 2 - 2.37 Why are empirical formulas preferred for...Ch. 2 - 2.38 The molecular formula for the ethylene...Ch. 2 - 239 Polybutadiene is a synthetic elastomer, or...Ch. 2 - 2.40 What distinguished the work of Mendeleev that...Ch. 2 - 2.41 How does the periodic table help to make the...Ch. 2 - 2.42 What is a period in the periodic table? From...Ch. 2 - How do binary compounds with hydrogen illustrate...Ch. 2 - Prob. 2.52PAECh. 2 - 2.43 Name of the group to which each of the...Ch. 2 - Prob. 2.54PAECh. 2 - Prob. 2.55PAECh. 2 - 2.46 Why are nonmetals important even though they...Ch. 2 - Prob. 2.57PAECh. 2 - A materials engineer has filed for a patent for a...Ch. 2 - Prob. 2.59PAECh. 2 - 2.50 A materials engineer wants to make a new...Ch. 2 - Prob. 2.61PAECh. 2 - Prob. 2.62PAECh. 2 - 2.53 What is meant by the phrase organic...Ch. 2 - 2.54 Based on what you have learned in this...Ch. 2 - 2.55 What is a functional group? How does the...Ch. 2 - Prob. 2.66PAECh. 2 - Prob. 2.67PAECh. 2 - Prob. 2.68PAECh. 2 - 2.59 The accompanying figure shows the structure...Ch. 2 - Prob. 2.70PAECh. 2 - Prob. 2.71PAECh. 2 - Prob. 2.72PAECh. 2 - 2.61 Name the following covalent compounds: (a)...Ch. 2 - Prob. 2.74PAECh. 2 - Prob. 2.75PAECh. 2 - Prob. 2.76PAECh. 2 - Prob. 2.77PAECh. 2 - Prob. 2.78PAECh. 2 - Prob. 2.79PAECh. 2 - 2.68 What is a free radical? How are free radicals...Ch. 2 - Prob. 2.81PAECh. 2 - 2.70 Why do you think an inhibitor molecule is...Ch. 2 - 2.71 Use the web to determine the amount of...Ch. 2 - 2.88 Describe how you can identify the isotope, X,...Ch. 2 - 2.90 Naturally occurring europium has an average...Ch. 2 - 2.91 Strontium has four stable isotopes....Ch. 2 - 2.92 A candy manufacturer makes chocolate-covered...Ch. 2 - Prob. 2.88PAECh. 2 - 2.94 Use a molecular level description to...Ch. 2 - 2.95 Engineers who design bicycle frames are...Ch. 2 - 2.96 Use the web to look up the density of...Ch. 2 - 2.97 LDPE has a density in the range of...
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