General, Organic, and Biological Chemistry (3rd Edition)
3rd Edition
ISBN: 9780134042428
Author: Laura D. Frost, S. Todd Deal
Publisher: PEARSON
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Chapter 2, Problem 2.17PP
Summary Introduction
To determine:
The explanation for difference between mass of isotope and
Introduction:
The mass of the isotope is the sum of mass of protons and neutrons in the atom.
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Students have asked these similar questions
Part VII. The H-NMR of a compound with molecular formula C5 H 10 O2 is given below.
Find the following:
(a) The no. of protons corresponding to each signal in the spectra
(6) Give the structure of the compound and assign the signals to each
proton in the compound.
a
70.2
Integration Values
C5H10O2
b
47.7
C
46.5
d
69.5
3.6 3.5
3.4 3.3 3.2 3.1 3.0
2.9 2.8
2.7
2.6 2.5
2.4 2.3 2.2 2.1 2.0
Chemical Shift (ppm)
1.9
1.8
1.7 1.6
1.5
1.4 1.3 1.2
1.1 1.0
0.9 0.8
Part 111. 1 H-NMR spectrum of a compound with integration values in red is given below.
Answer the following:
(a) write the signals in the 'H-NMR spectrum to the corresponding protons on the structure
of the molecule below.
(b) Identify the theoretical multiplicities for each proton in the compound. Also give the possible.
complex splitting patterns assuming J values are not similar.
там
Br
22
2
3
6
4 7.2 7.0 6.8 6.6 6.4 6.2 6.0 5.8 5.6 5.4 5.2 5.0 4.8 4.6 4.4 4.2 4.0 3.8 3.6 3.4 3.2 3.0 2.8 2.6 2.4 2.2 2.0 1.8 1.6 1.4 1.2 1.0 0.8 0
Chemical Shift (ppm)
ra.
Br
2
3
6
6
2.5
2.4
2.3
2.2
2.1
2.0
1.9
1.8
1.7
1.6
1.5
1.4
1.3
1.2
1.1
1.0
0.9
0.8
Chemical Shift (ppm)
2
2
Br
7.3
7.2
7.1
7.0 6.9
6.7 6.6 6.5
6.4
6.3
6.2
6.1
6.0
Chemical Shift (ppm)
5.9
5.8 5.7
5.5 5.4 5.3 5.2
5.0 4.9
1600°
1538°C
1493°C
In the diagram, the letter L indicates
that it is a liquid. Indicate its
components in the upper region
where only L is indicated.
The
iron-iron carbide phase
diagram.
Temperature (°C)
1400
8
1394°C
y+L
1200
2.14
y, Austenite
10000
912°C
800a
0.76
0.022
600
400
(Fe)
a, Ferrite
Composition (at% C)
15
1147°C
a + Fe3C
2
3
Composition (wt% C)
L
2500
4.30
2000
y + Fe3C
727°C
1500
Cementite (Fe3C)
1000
4
5
6
6.70
Temperature (°F)
Chapter 2 Solutions
General, Organic, and Biological Chemistry (3rd Edition)
Ch. 2 - Where are the subatomic particles located in an...Ch. 2 - Prob. 2.2PPCh. 2 - Prob. 2.3PPCh. 2 - Prob. 2.4PPCh. 2 - How can you determine the following? a. the number...Ch. 2 - What can be determined from the following? a. the...Ch. 2 - Provide the name and atomic symbol of the element...Ch. 2 - Provide the name and atomic symbol of the element...Ch. 2 - Prob. 2.9PPCh. 2 - Prob. 2.10PP
Ch. 2 - Determine the number of protons, neutrons, and...Ch. 2 - Determine the number of protons, neutrons, and...Ch. 2 - Prob. 2.13PPCh. 2 - Prob. 2.14PPCh. 2 - Prob. 2.15PPCh. 2 - Prob. 2.16PPCh. 2 - Prob. 2.17PPCh. 2 - How are atomic mass and mass number similar? How...Ch. 2 - There are three naturally occurring isotopes of...Ch. 2 - Prob. 2.20PPCh. 2 - Prob. 2.21PPCh. 2 - Prob. 2.22PPCh. 2 - Prob. 2.23PPCh. 2 - Prob. 2.24PPCh. 2 - Prob. 2.25PPCh. 2 - Prob. 2.26PPCh. 2 - Prob. 2.27PPCh. 2 - Prob. 2.28PPCh. 2 - Prob. 2.29PPCh. 2 - Prob. 2.30PPCh. 2 - Prob. 2.31PPCh. 2 - Prob. 2.32PPCh. 2 - What does the unit sievert measure?Ch. 2 - Prob. 2.34PPCh. 2 - Prob. 2.35PPCh. 2 - Prob. 2.36PPCh. 2 - Prob. 2.37PPCh. 2 - Prob. 2.38PPCh. 2 - Prob. 2.39PPCh. 2 - Prob. 2.40PPCh. 2 - Prob. 2.41PPCh. 2 - Prob. 2.42PPCh. 2 - Prob. 2.43PPCh. 2 - Prob. 2.44PPCh. 2 - Complete the following statements: a. A...Ch. 2 - Complete the following statements: a. The mass...Ch. 2 - Prob. 2.47APCh. 2 - Prob. 2.48APCh. 2 - Prob. 2.49APCh. 2 - Prob. 2.50APCh. 2 - Prob. 2.51APCh. 2 - Prob. 2.52APCh. 2 - Prob. 2.53APCh. 2 - Prob. 2.54APCh. 2 - Prob. 2.55APCh. 2 - Prob. 2.56APCh. 2 - Prob. 2.57APCh. 2 - Prob. 2.58APCh. 2 - Prob. 2.59APCh. 2 - Prob. 2.60APCh. 2 - Prob. 2.61APCh. 2 - Prob. 2.62APCh. 2 - Prob. 2.63APCh. 2 - Prob. 2.64APCh. 2 - Prob. 2.65APCh. 2 - Prob. 2.66APCh. 2 - Prob. 2.67APCh. 2 - Prob. 2.68APCh. 2 - A 25-mL sample of chromium-51 contains 1.00 mCi....Ch. 2 - Prob. 2.70APCh. 2 - Prob. 2.71APCh. 2 - Prob. 2.72APCh. 2 - Prob. 2.73APCh. 2 - Prob. 2.74APCh. 2 - Prob. 2.75APCh. 2 - Prob. 2.76APCh. 2 - Prob. 2.77CPCh. 2 - Prob. 2.78CPCh. 2 - PET scans are useful for imaging areas of high...Ch. 2 - Prob. 1IA.1QCh. 2 - Prob. 1IA.2QCh. 2 - Prob. 1IA.3QCh. 2 - Prob. 1IA.4QCh. 2 - Prob. 1IA.5QCh. 2 - Prob. 1IA.6QCh. 2 - Prob. 1IA.7QCh. 2 - Prob. 1IA.8QCh. 2 - Prob. 1IA.9QCh. 2 - Prob. 1IA.10QCh. 2 - Prob. 1IA.11QCh. 2 - Prob. 2IA.1QCh. 2 - Prob. 2IA.2QCh. 2 - Prob. 2IA.3QCh. 2 - Prob. 2IA.4QCh. 2 - Prob. 1ICCh. 2 - Prob. 2IC
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- Nonearrow_forwardPart II. Given below are the 'H-NMR spectrum at 300 MHz in CDC13 and mass spectrum using electron ionization of compound Brian. The FTIR of the said compound showed a strong peak at 1710 cm"). Determine the following: (a) molecular Formula and Degree of unsaturation of compound Brian (b) Basing on the given H-NMR spectrum tabulate the following (i) chemical shifts (ii) integration, ciii) multiplicity and (iv) interferences made for each signal (c) Draw the structure of compound Brian. ) ΕΙ 43 41 27 71 114 (M+) Hmmm 20 30 40 50 60 70 80 90 100 110 120 1H NMR spectrum 300 MHz in CDCl3 2.0 alle 1.0arrow_forwardThe iron-iron carbide phase diagram. In the diagram, the letter L indicates that it is a liquid. Indicate what its components are. Temperature (°C) 1600 10 Composition (at% C) 15 25 1538°C -1493°C 8 1400 1200 1394°C y+L L 2500 1147°C y. Austenite 2.14 4.30 2000 1000 912°C y + Fe3C 800ㅏ 0.76 0.022 600 a, Ferrite a + Fe3C 400 0 (Fe) Composition (wt% C) 727°C 1500 Cementite (Fe3C) 1000 6 6.70 Temperature (°F)arrow_forward
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