GENERAL, ORGANIC, BIOCHEM (LL W/ ACCESS)
10th Edition
ISBN: 9781260885958
Author: Denniston
Publisher: MCG
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Chapter 2, Problem 2.125QP
(a)
Interpretation Introduction
Interpretation:
The reason why a positive ion is always smaller than its parent atom has to be explained.
(b)
Interpretation Introduction
Interpretation:
The reason why a fluoride ion is always found in nature but a fluorine atom is not has to be explained.
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Draw the stepwise mechanism for the reactions
Part I.
a)
Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone
b) Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone
(3,3-dimethyl-2-butanone) and 2, 3-dimethyl - 1,3-butadiene. Give reasonable mechanism
the formation of
the products
For
3. The explosive decomposition of 2 mole of TNT (2,4,6-trinitrotoluene) is shown below:
Assume the C(s) is soot-basically atomic carbon (although it isn't actually atomic carbon in real life).
2
CH3
H
NO2
NO2
3N2 (g)+7CO (g) + 5H₂O (g) + 7C (s)
H
a. Use bond dissociation energies to calculate how much AU is for this reaction in kJ/mol.
Chapter 2 Solutions
GENERAL, ORGANIC, BIOCHEM (LL W/ ACCESS)
Ch. 2.1 - Calculate the number of protons, neutrons, and...Ch. 2.1 - How many protons, neutrons, and electrons are...Ch. 2.1 - How many protons, neutrons, and electrons are...Ch. 2.1 - The element nitrogen has two naturally occurring...Ch. 2.1 - Prob. 2.3PPCh. 2.3 - Prob. 2.3QCh. 2.3 - Prob. 2.4QCh. 2.4 - Prob. 2.5QCh. 2.4 - Using the periodic table, write the symbol for...Ch. 2.4 - Refer to the periodic table, and find the...
Ch. 2.4 - Refer to the periodic table, and find the...Ch. 2.4 - Prob. 2.9QCh. 2.4 - For each of the following element symbols, give...Ch. 2.5 - Prob. 2.4PPCh. 2.5 - Prob. 2.5PPCh. 2.5 - Prob. 2.6PPCh. 2.6 - Prob. 2.7PPCh. 2.6 - Prob. 2.8PPCh. 2.6 - Determine the number of protons and electrons in...Ch. 2.6 - Prob. 2.12QCh. 2.6 - Provide the charge of the most probable ion...Ch. 2.6 - Prob. 2.13QCh. 2.6 - Which of the following pairs of atoms and ions are...Ch. 2.6 - Prob. 2.10PPCh. 2.6 - Prob. 2.15QCh. 2.6 - Prob. 2.16QCh. 2.7 - Prob. 2.17QCh. 2.7 - Prob. 2.18QCh. 2 - Prob. 2.19QPCh. 2 - Why is the number of electrons not part of the...Ch. 2 - Fill in the blanks:
Isotopes of an element differ...Ch. 2 - Identify which of the following isotopic symbols...Ch. 2 - Identify the major difference and the major...Ch. 2 - Label each of the following statements as true or...Ch. 2 - Label each of the following statements as true or...Ch. 2 - The nuclei of three different atoms are depicted...Ch. 2 - Calculate the number of protons, neutrons, and...Ch. 2 - Calculate the number of protons, neutrons, and...Ch. 2 - An atom has nine protons, ten neutrons, and nine...Ch. 2 - An atom has nineteen protons, twenty neutrons, and...Ch. 2 - How many protons are in the nucleus of the isotope...Ch. 2 - Prob. 2.32QPCh. 2 - Selenium-80 is a naturally occurring isotope used...Ch. 2 - Prob. 2.34QPCh. 2 - Write symbols for each isotope:
Each atom contains...Ch. 2 - Prob. 2.36QPCh. 2 - The element copper has two naturally occurring...Ch. 2 - The element lithium has two naturally occurring...Ch. 2 - Prob. 2.39QPCh. 2 - Prob. 2.40QPCh. 2 - Describe the experiment that provided the basis...Ch. 2 - Prob. 2.42QPCh. 2 - Prob. 2.43QPCh. 2 - Prob. 2.44QPCh. 2 - Prob. 2.45QPCh. 2 - Prob. 2.46QPCh. 2 - Prob. 2.47QPCh. 2 - Prob. 2.48QPCh. 2 - Prob. 2.49QPCh. 2 - Prob. 2.50QPCh. 2 - Prob. 2.51QPCh. 2 - Prob. 2.52QPCh. 2 - Describe electromagnetic radiation according to...Ch. 2 - Prob. 2.54QPCh. 2 - Is the following statement true or false?
Light of...Ch. 2 - Prob. 2.56QPCh. 2 - Prob. 2.57QPCh. 2 - Prob. 2.58QPCh. 2 - Describe the process that occurs when electrical...Ch. 2 - When electrical energy is applied to an element in...Ch. 2 - Prob. 2.61QPCh. 2 - Prob. 2.62QPCh. 2 - Prob. 2.63QPCh. 2 - Prob. 2.64QPCh. 2 - What was the major contribution of Bohr’s atomic...Ch. 2 - What was the major deficiency of Bohr’s atomic...Ch. 2 - Provide the atomic number, atomic mass, and name...Ch. 2 - Provide the atomic number, atomic mass, and name...Ch. 2 - Prob. 2.69QPCh. 2 - Prob. 2.70QPCh. 2 - Which group of the periodic table is known as the...Ch. 2 - Prob. 2.72QPCh. 2 - For each of the elements Na, Ni, Al, P, Cl, and...Ch. 2 - Prob. 2.74QPCh. 2 - Prob. 2.75QPCh. 2 - Prob. 2.76QPCh. 2 - Distinguish between a principal energy level and a...Ch. 2 - Distinguish between a sublevel and an orbital.
Ch. 2 - Sketch a diagram and describe our current model of...Ch. 2 - How is a 2s orbital different from a 1s orbital?
Ch. 2 - Prob. 2.81QPCh. 2 - For any given principal energy level, what is the...Ch. 2 - State the Pauli exclusion principle. Explain how...Ch. 2 - State Hund’s rule. Determine whether the following...Ch. 2 - Using the periodic table, write the electron...Ch. 2 - Using the periodic table, write the electron...Ch. 2 - Using the periodic table, write the electron...Ch. 2 - Using the periodic table, write the electron...Ch. 2 - Which of the following electron configurations are...Ch. 2 - Prob. 2.90QPCh. 2 - Determine whether the following orbital diagrams...Ch. 2 - Identify the element for each of the orbital...Ch. 2 - Use the periodic table and determine the shorthand...Ch. 2 - Prob. 2.94QPCh. 2 - Prob. 2.95QPCh. 2 - Prob. 2.96QPCh. 2 - State the octet rule.
Ch. 2 - Prob. 2.98QPCh. 2 - Prob. 2.99QPCh. 2 - Prob. 2.100QPCh. 2 - How many total electrons and valence electrons are...Ch. 2 - Prob. 2.102QPCh. 2 - Prob. 2.103QPCh. 2 - Prob. 2.104QPCh. 2 - Prob. 2.105QPCh. 2 - Predict the number of valence electrons in an atom...Ch. 2 - Prob. 2.107QPCh. 2 - Prob. 2.108QPCh. 2 - Prob. 2.109QPCh. 2 - Prob. 2.110QPCh. 2 - Prob. 2.111QPCh. 2 - Prob. 2.112QPCh. 2 - Prob. 2.113QPCh. 2 - Prob. 2.114QPCh. 2 - Prob. 2.115QPCh. 2 - Prob. 2.116QPCh. 2 - Prob. 2.117QPCh. 2 - Prob. 2.118QPCh. 2 - Prob. 2.119QPCh. 2 - Prob. 2.120QPCh. 2 - Prob. 2.121QPCh. 2 - Prob. 2.122QPCh. 2 - Prob. 2.123QPCh. 2 - Prob. 2.124QPCh. 2 - Explain why a positive ion is always smaller than...Ch. 2 - Prob. 2.126QPCh. 2 - Prob. 2.127QPCh. 2 - Prob. 2.128QPCh. 2 - For the isotope chlorine-37:
How many protons are...Ch. 2 - A natural sample of chromium, taken from the...Ch. 2 - For the element sulfur, provide the following...Ch. 2 - Prob. 5MCPCh. 2 - Prob. 7MCP
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- Part I. Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff: Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone and (3,3-dimethyl-2-butanone) 2,3-dimethyl-1,3-butadiene. Give reasonable mechanism the formation of the products Forarrow_forwardShow the mechanism for these reactionsarrow_forwardDraw the stepwise mechanismarrow_forward
- Draw a structural formula of the principal product formed when benzonitrile is treated with each reagent. (a) H₂O (one equivalent), H₂SO₄, heat (b) H₂O (excess), H₂SO₄, heat (c) NaOH, H₂O, heat (d) LiAlH4, then H₂Oarrow_forwardDraw the stepwise mechanism for the reactionsarrow_forwardDraw stepwise mechanismarrow_forward
- Part I. Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff: a) Give the major reason for the exposure of benzophenone al isopropyl alcohol (w/acid) to direct sunlight of pina colone Mechanism For b) Pinacol (2,3-dimethy 1, 1-3-butanediol) on treatment w/ acid gives a mixture (3,3-dimethyl-2-butanone) and 2, 3-dimethyl-1,3-butadiene. Give reasonable the formation of the productsarrow_forwardwhat are the Iupac names for each structurearrow_forwardWhat are the IUPAC Names of all the compounds in the picture?arrow_forward
- 1) a) Give the dominant Intermolecular Force (IMF) in a sample of each of the following compounds. Please show your work. (8) SF2, CH,OH, C₂H₂ b) Based on your answers given above, list the compounds in order of their Boiling Point from low to high. (8)arrow_forward19.78 Write the products of the following sequences of reactions. Refer to your reaction road- maps to see how the combined reactions allow you to "navigate" between the different functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18 roadmaps along with your new Chapter 19 roadmap for these. (a) 1. BHS 2. H₂O₂ 3. H₂CrO4 4. SOCI₂ (b) 1. Cl₂/hv 2. KOLBU 3. H₂O, catalytic H₂SO4 4. H₂CrO4 Reaction Roadmap An alkene 5. EtOH 6.0.5 Equiv. NaOEt/EtOH 7. Mild H₂O An alkane 1.0 2. (CH3)₂S 3. H₂CrO (d) (c) 4. Excess EtOH, catalytic H₂SO OH 4. Mild H₂O* 5.0.5 Equiv. NaOEt/EtOH An alkene 6. Mild H₂O* A carboxylic acid 7. Mild H₂O* 1. SOC₁₂ 2. EtOH 3.0.5 Equiv. NaOEt/E:OH 5.1.0 Equiv. NaOEt 6. NH₂ (e) 1. 0.5 Equiv. NaOEt/EtOH 2. Mild H₂O* Br (f) i H An aldehyde 1. Catalytic NaOE/EtOH 2. H₂O*, heat 3. (CH,CH₂)₂Culi 4. Mild H₂O* 5.1.0 Equiv. LDA Br An ester 4. NaOH, H₂O 5. Mild H₂O* 6. Heat 7. MgBr 8. Mild H₂O* 7. Mild H₂O+arrow_forwardLi+ is a hard acid. With this in mind, which if the following compounds should be most soluble in water? Group of answer choices LiBr LiI LiF LiClarrow_forward
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