Introductory Chemistry
8th Edition
ISBN: 9781285453132
Author: Steven S. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
expand_more
expand_more
format_list_bulleted
Concept explainers
Videos
Question
Chapter 2, Problem 157AP
Interpretation Introduction
(a)
Interpretation:
Three examples should be given for how the developing sophisticated measuring devices are useful in our society.
Concept Introduction:
Developing sophisticated measuring devices is helpful in solving complicated problems in our modern world.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
I
Draw the anti-Markovnikov product of the hydration of this alkene.
this problem.
Note for advanced students: draw only one product, and don't worry about showing any stereochemistry. Drawing dash and wedge bonds has been disabled for
esc
esc
☐
Explanation
Check
F1
1
2
F2
# 3
F3
+
$
14
×
1. BH THE
BH3
2. H O NaOH
'2 2'
Click and drag to start
drawing a structure.
F4
Q
W
E
R
A
S
D
%
905
LL
F5
F6
F7
© 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center | Accessibility
<
&
6
7
27
8
T
Y
U
G
H
I
F8
F9
F10
F11
F12
9
0
J
K
L
P
+ //
command option
Z
X
C
V B
N
M
H
H
rol
option
command
AG/F-2° V
3. Before proceeding with this problem you may want to glance at p. 466 of your textbook
where various oxo-phosphorus derivatives and their oxidation states are summarized.
Shown below are Latimer diagrams for phosphorus at pH values at 0 and 14:
-0.93
+0.38
-0.50
-0.51 -0.06
H3PO4 →H4P206 →H3PO3 →→H3PO₂ → P → PH3
Acidic solution
Basic solution
-0.28
-0.50
3--1.12
-1.57
-2.05 -0.89
PO HPO H₂PO₂ →P → PH3
-1.73
a) Under acidic conditions, H3PO4 can be reduced into H3PO3 directly (-0.28V), or via the
formation and reduction of H4P206 (-0.93/+0.38V). Calculate the values of AG's for both
processes; comment.
(3 points)
0.5
PH
P
0.0
-0.5
-1.0-
-1.5-
-2.0
H.PO,
-2.3+
-3 -2
-1
1
2
3
2
H,PO,
b) Frost diagram for phosphorus under acidic
conditions is shown. Identify possible
disproportionation and comproportionation processes;
write out chemical equations describing them. (2 points)
H,PO
4
S
Oxidation stale, N
Chapter 2 Solutions
Introductory Chemistry
Ch. 2.1 - Exercise 2.1 Write the numbers 357 and 0.0055 in...Ch. 2.2 - What if you were not allowed to use units for one...Ch. 2.5 - Exercise 2.2 Give the number of significant...Ch. 2.5 - Exercise 2.3 Give the answer for each calculation...Ch. 2.6 - Exercise 2.4 Wine is often bottled in 0.750-L...Ch. 2.6 - Exercise 2.5 Racing cars at the Indianapolis Motor...Ch. 2.7 - Exercise 2.6 Which temperature is colder, 172 K or...Ch. 2.7 - Exercise 2.7 Hot tubs are often maintained at 41...Ch. 2.7 - Exercise 2.8 An antifreeze solution in a car’s...Ch. 2.8 - Exercise 2.9A student wants to identify the main...
Ch. 2 - a. There are 365 days/year, 24 hours/day, 12...Ch. 2 - You go to a convenience store to buy candy and...Ch. 2 - When a marble is dropped into a beaker of water,...Ch. 2 - Consider water in each graduated cylinder as...Ch. 2 - What is the numerical value of a conversion...Ch. 2 - For each of the following numbers, indicate which...Ch. 2 - Consider the addition of “1 5.4” to “28.” What...Ch. 2 - Consider multiplying “26.2” by “16.43.” What would...Ch. 2 - In lab you report a measured volume of 128.7 mL of...Ch. 2 - Sketch two pieces of glassware: one that can...Ch. 2 - Oil floats on water but is “thicker” than water....Ch. 2 - Show how converting numbers to scientific notation...Ch. 2 - You are driving 65mph and take your eyes oil the...Ch. 2 - You have a1.0cm3 sample of lead and a1.0cm3 sample...Ch. 2 - The beakers shown below have different precisions....Ch. 2 - True or false? For any mathematical operation...Ch. 2 - Complete the following and explain each in your...Ch. 2 - For each of the following figures, a through d,...Ch. 2 - For the pin shown below, why is the third digit...Ch. 2 - Why can the length of the pin shown below not be...Ch. 2 - Use the figure below to answer the following...Ch. 2 - A represents a quantitative observation.Ch. 2 - Although your textbook lists (he rules for...Ch. 2 - When a large or small number is written in...Ch. 2 - When a large or small number is written in...Ch. 2 - Will the power of 10 have apositiveor...Ch. 2 - Will the power of 10 have a positive, negative, or...Ch. 2 - Express each of the following numbers...Ch. 2 - Rewrite each of the following as an “ordinary”...Ch. 2 - By how many places must the decimal point be...Ch. 2 - By how many places must the decimal point be...Ch. 2 - Prob. 11QAPCh. 2 - Write each of the following numbers as “ordinary”...Ch. 2 - Write each of the following numbers...Ch. 2 - Prob. 14QAPCh. 2 - What are the fundamental units of mass, length,...Ch. 2 - Give the metric prefix that corresponds to each of...Ch. 2 - Students often have trouble relating measurements...Ch. 2 - Students often have trouble relating measurements...Ch. 2 - Students often have trouble relating measurements...Ch. 2 - Students often have trouble relating measurements...Ch. 2 - The road sign I just passed says “New York City...Ch. 2 - The GPS in my car indicates that t have 100. mi...Ch. 2 - The tablecloth on my dining room table is 2 in...Ch. 2 - Who is taller, a man who is 1.62 in tall or a...Ch. 2 - The fundamental SI unit of length is the meter....Ch. 2 - 26. Which English unit of length or distance is...Ch. 2 - The unit of volume in the metric system is the...Ch. 2 - Which metric system unit is most appropriate for...Ch. 2 - When a measuring scale is used properly to the...Ch. 2 - What does it mean to say LI1amevery measurement we...Ch. 2 - For the pin shown in Fig. 2.5, why is the third...Ch. 2 - Why can the length of the pin shown in Fig. 2.5...Ch. 2 - Indicate the number of significant figures in each...Ch. 2 - Indicate the number of significant figures implied...Ch. 2 - When we round off a number, if the number to the...Ch. 2 - In a multiple-step calculation, is it better to...Ch. 2 - Round off each of the following numbers to three...Ch. 2 - Round off each of the following numbers to two...Ch. 2 - Round off each of the following numbers to the...Ch. 2 - Round off each of the following numbers to the...Ch. 2 - Consider the calculation indicated below:...Ch. 2 - The following water measurements are made: 18 mL...Ch. 2 - When the calculation(2.31)(4.9795103)/(1.9971104)...Ch. 2 - Prob. 44QAPCh. 2 - When the sum 4.9965 + 2.11 + 3.887 is calculated,...Ch. 2 - How many digits after the decimal point should he...Ch. 2 - Evaluate each of the following mathematical...Ch. 2 - Evaluate each of the following mathematical...Ch. 2 - Without actually performing the calculations...Ch. 2 - Without actually performing the calculations...Ch. 2 - How many significant digits should be used to...Ch. 2 - Evaluate each of the following and write the...Ch. 2 - A represents a ratio based on an equivalence...Ch. 2 - How many significant figures are understood for...Ch. 2 - Given that 1 mi = 1760 yd, determine what...Ch. 2 - Prob. 56QAPCh. 2 - For Exercises 57 and 58, apples cost $1.75 per...Ch. 2 - What conversion factor could be used to determine...Ch. 2 - Perform each of the following conversions, being...Ch. 2 - Perform each of the following conversions, being...Ch. 2 - Perform each of the following conversions, being...Ch. 2 - Perform each of the following conversions, being...Ch. 2 - 12.01 g of carbon contains6.021023 carbon atoms....Ch. 2 - Los Angeles and Honolulu are 2558 mi apart. What...Ch. 2 - The United States has high-speed trains running...Ch. 2 - The radius of an atom is on the order of1010 m....Ch. 2 - The temperature scale used in everyday life in...Ch. 2 - The point of water is at 32° on the Fahrenheit...Ch. 2 - Prob. 69QAPCh. 2 - The freezing point of water is _________ K.Ch. 2 - On both the Celsius and Kelvin temperature scales,...Ch. 2 - On which temperature scale (°F, °C, or K) does 1...Ch. 2 - Make the following temperature conversions: 44.2...Ch. 2 - Prob. 74QAPCh. 2 - Convert the following Fahrenheit temperatures to...Ch. 2 - Convert the following Celsius temperatures to...Ch. 2 - The “Chemistry in Focus” segmentTiny...Ch. 2 - Perform the indicated temperature conversions. 275...Ch. 2 - Prob. 79QAPCh. 2 - The most common units for density are ___________.Ch. 2 - A kilogram of lead occupies a much smaller volume...Ch. 2 - If a solid block of glass, with a volume of...Ch. 2 - Is the density of a gaseous substance likely to be...Ch. 2 - What property of density makes it useful as an aid...Ch. 2 - Referring to Table 2.8, which substance listed is...Ch. 2 - Referring to Table 2.8, determine whether...Ch. 2 - For the masses and volumes indicated, calculate...Ch. 2 - For the masses and volumes indicated, calculate...Ch. 2 - The element bromine at room temperature is a...Ch. 2 - Sunflower oil has a density of 0.920 g/mL. What is...Ch. 2 - If 1000. mL of linseed oil has a mass of 929 g....Ch. 2 - A material will float on the surface of a liquid...Ch. 2 - Iron has a density of 7.87 g/cm3. If 52.4 g of...Ch. 2 - The density of pure gold is 19.32 g/cm3 at 20 °C....Ch. 2 - Use the information in Table 2.8 to calculate the...Ch. 2 - Use the information in Table 2.8 to calculate the...Ch. 2 - 97. Indicate the number of significant digits in...Ch. 2 - Express each of the following as an “ordinary”...Ch. 2 - Write each of the following numbers in standard...Ch. 2 - Prob. 100APCh. 2 - Make the following conversions. 1 .25 in. to feet...Ch. 2 - On the planet Xgnu, the most common units of...Ch. 2 - You pass a road sign saying “New York 110 km.” If...Ch. 2 - Convert 45 mi/h to m/s, showing how the units...Ch. 2 - Suppose your car is rated at 45 mi/gal for highway...Ch. 2 - Prob. 106APCh. 2 - For a pharmacist dispensing pills or capsules, it...Ch. 2 - On the planet Xgnu, the natives have 14 fingers....Ch. 2 - For a material to float on the surface of water,...Ch. 2 - A gas cylinder having a volume of 10.5 L contains...Ch. 2 - Using Table 2.8, calculate the volume of 25.0 g of...Ch. 2 - Ethanol and benzene dissolve in each other. When...Ch. 2 - When 2891 is written in scientific notation, the...Ch. 2 - For each of the following numbers, if the number...Ch. 2 - For each of the following numbers, if the number...Ch. 2 - Prob. 116APCh. 2 - For each of the following numbers, by how many...Ch. 2 - For each of the following numbers, by how many...Ch. 2 - Express each of the following numbers in...Ch. 2 - Express each of the following as an “ordinary”...Ch. 2 - Prob. 121APCh. 2 - Prob. 122APCh. 2 - Prob. 123APCh. 2 - Draw a piece of lab glassware that can...Ch. 2 - Which distance is farther, 100 km or 50 mi?Ch. 2 - 1L= ________dm3= ________cm3= ________mLCh. 2 - The volume 0.250 L could also be expressed as mL.Ch. 2 - The distance 10.5 cm could also be expressed as m.Ch. 2 - Would an automobile moving at a constant speed of...Ch. 2 - Which weighs more, 0.001 g of water or 1 mg of...Ch. 2 - Which weighs more, 4.25 g of gold or 425 mg of...Ch. 2 - The length 500 m can also be expressed as nm.Ch. 2 - The ratio of an object’s mass to its is called the...Ch. 2 - You are working on a project where you need the...Ch. 2 - Indicate the number of significant figures in each...Ch. 2 - Prob. 136APCh. 2 - Round off each of the following numbers to the...Ch. 2 - Prob. 138APCh. 2 - Prob. 139APCh. 2 - Prob. 140APCh. 2 - Prob. 141APCh. 2 - Prob. 142APCh. 2 - Perform each of the following conversions, being...Ch. 2 - Perform each of the following conversions, being...Ch. 2 - The mean distance from the earth to (he sun ismi....Ch. 2 - Given that one metric ton = 1000 kg, how many...Ch. 2 - Convert the following temperatures to kelvins. 0°C...Ch. 2 - Carry out the indicated temperature conversions....Ch. 2 - For the masses and volumes indicated, calculate...Ch. 2 - A sample of a liquid solvent has a density of...Ch. 2 - An organic solvent has a density of 1.31 g/mL....Ch. 2 - A solid metal sphere has a volume of 4.2 ft3. The...Ch. 2 - A sample containing 33.42 g of metal pellets is...Ch. 2 - Prob. 154APCh. 2 - Prob. 155APCh. 2 - Prob. 156APCh. 2 - Prob. 157APCh. 2 - Prob. 158APCh. 2 - Complete the following table: Number Exponential...Ch. 2 - For each of the mathematical expressions given: a....Ch. 2 - The longest river in the world is the Nile River...Ch. 2 - Secretariat is known as the horse with the fastest...Ch. 2 - A friend tells you that it is 69. 1 °F outside....Ch. 2 - The hottest temperature recorded in the United...Ch. 2 - The density of osmium (the densest metal)...Ch. 2 - The radius of a neon atom is 69 pm, and its mass...
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- 4. For the following complexes, draw the structures and give a d-electron count of the metal: a) Tris(acetylacetonato)iron(III) b) Hexabromoplatinate(2-) c) Potassium diamminetetrabromocobaltate(III) (6 points)arrow_forward2. Calculate the overall formation constant for [Fe(CN)6]³, given that the overall formation constant for [Fe(CN)6] 4 is ~1032, and that: Fe3+ (aq) + e = Fe²+ (aq) E° = +0.77 V [Fe(CN)6]³ (aq) + e¯ = [Fe(CN)6] (aq) E° = +0.36 V (4 points)arrow_forward5. Consider the compounds shown below as ligands in coordination chemistry and identify their denticity; comment on their ability to form chelate complexes. (6 points) N N A B N N N IN N Carrow_forward
- 1. Use standard reduction potentials to rationalize quantitatively why: (6 points) (a) Al liberates H2 from dilute HCl, but Ag does not; (b) Cl2 liberates Br2 from aqueous KBr solution, but does not liberate C12 from aqueous KCl solution; c) a method of growing Ag crystals is to immerse a zinc foil in an aqueous solution of AgNO3.arrow_forwardWhat would be the best choices for the missing reagents 1 and 3 in this synthesis? 1 1. PPh3 2. n-BuLi 3 2 • Draw the missing reagents in the drawing area below. You can draw them in any arrangement you like. • Do not draw the missing reagent 2. If you draw 1 correctly, we'll know what it is. • Note: if one of your reagents needs to contain a halogen, use bromine. Click and drag to start drawing a structure. Xarrow_forwardWhat is the missing reactant R in this organic reaction? N N H3O+ +R + • Draw the structure of R in the drawing area below. • Be sure to use wedge and dash bonds if it's necessary to draw one particular enantiomer. Click and drag to start drawing a structure. fmarrow_forward
- The product on the right-hand side of this reaction can be prepared from two organic reactants, under the conditions shown above and below the arrow. Draw 1 and 2 below, in any arrangement you like. 1+2 NaBH3CN H+ N Click and drag to start drawing a structure. 5arrow_forwardAssign this HSQC Spectrum ( please editing clearly on the image)arrow_forward(a 4 shows scanning electron microscope (SEM) images of extruded actions of packing bed for two capillary columns of different diameters, al 750 (bottom image) and b) 30-μm-i.d. Both columns are packed with the same stationary phase, spherical particles with 1-um diameter. A) When the columns were prepared, the figure shows that the column with the larger diameter has more packing irregularities. Explain this observation. B) Predict what affect this should have on band broadening and discuss your prediction using the van Deemter terms. C) Does this figure support your explanations in application question 33? Explain why or why not and make any changes in your answers in light of this figure. Figure 4 SEM images of sections of packed columns for a) 750 and b) 30-um-i.d. capillary columns.³arrow_forward
- fcrip = ↓ bandwidth Il temp 32. What impact (increase, decrease, or no change) does each of the following conditions have on the individual components of the van Deemter equation and consequently, band broadening? Increase temperature Longer column Using a gas mobile phase instead of liquid Smaller particle stationary phase Multiple Paths Diffusion Mass Transferarrow_forward34. Figure 3 shows Van Deemter plots for a solute molecule using different column inner diameters (i.d.). A) Predict whether decreasing the column inner diameters increase or decrease bandwidth. B) Predict which van Deemter equation coefficient (A, B, or C) has the greatest effect on increasing or decreasing bandwidth as a function of i.d. and justify your answer. Figure 3 Van Deemter plots for hydroquinone using different column inner diameters (i.d. in μm). The data was obtained from liquid chromatography experiments using fused-silica capillary columns packed with 1.0-μm particles. 35 20 H(um) 큰 20 15 90 0+ 1500 100 75 550 01 02 594 05 μ(cm/sec) 30 15 10arrow_forwardelow are experimentally determined van Deemter plots of column efficiency, H, vs. flow rate. H is a quantitative measurement of band broadening. The left plot is for a liquid chromatography application and the night is for gas chromatography. Compare and contrast these two plots in terms of the three band broadening mechanisms presented in this activity. How are they similar? How do they differ? Justify your answers.? 0.4 H (mm) 0.2 0.1- 0.3- 0 0.5 H (mm) 8.0 7.0 6.0 5.0 4.0- 3.0 T +++ 1.0 1.5 0 2.0 4.0 Flow Rate, u (cm/s) 6.0 8.0 Flow Rate, u (cm/s)arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Introductory Chemistry: A FoundationChemistryISBN:9781337399425Author:Steven S. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
Chemistry for Engineering StudentsChemistryISBN:9781285199023Author:Lawrence S. Brown, Tom HolmePublisher:Cengage LearningChemistry: Matter and ChangeChemistryISBN:9780078746376Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl WistromPublisher:Glencoe/McGraw-Hill School Pub Co
Living By Chemistry: First Edition TextbookChemistryISBN:9781559539418Author:Angelica StacyPublisher:MAC HIGHER
Introductory Chemistry: A Foundation
Chemistry
ISBN:9781337399425
Author:Steven S. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Chemistry for Engineering Students
Chemistry
ISBN:9781285199023
Author:Lawrence S. Brown, Tom Holme
Publisher:Cengage Learning
Chemistry: Matter and Change
Chemistry
ISBN:9780078746376
Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom
Publisher:Glencoe/McGraw-Hill School Pub Co
Living By Chemistry: First Edition Textbook
Chemistry
ISBN:9781559539418
Author:Angelica Stacy
Publisher:MAC HIGHER
Measurement and Significant Figures; Author: Professor Dave Explains;https://www.youtube.com/watch?v=Gn97hpEkTiM;License: Standard YouTube License, CC-BY
Trigonometry: Radians & Degrees (Section 3.2); Author: Math TV with Professor V;https://www.youtube.com/watch?v=U5a9e1J_V1Y;License: Standard YouTube License, CC-BY