
Introductory Chemistry, Books a la Carte Edition (6th Edition)
6th Edition
ISBN: 9780134564074
Author: Nivaldo J. Tro
Publisher: PEARSON
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Textbook Question
Chapter 2, Problem 10E
What are the rules for rounding number?
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Consider the following chemical equilibrium:
2SO2(g) + O2(g) = 2SO3(g)
•
Write the equilibrium constant expression for this reaction.
Now compare it to the equilibrium constant expression for the related reaction:
•
.
1
SO2(g) + O2(g) = SO3(g)
2
How do these two equilibrium expressions differ?
What important principle about the dependence of equilibrium constants on the stoichiometry of a
reaction can you learn from this comparison?
Given Kp for 2 reactions. Find the Kp for the following reaction:
BrCl(g)+ 1/2 I2(g) ->IBr(g) + 1/2 Cl2(g)
For a certain gas-phase reaction at constant pressure, the equilibrium constant Kp is observed to double
when the temperature increases from 300 K to 400 K.
Calculate the enthalpy change of the reaction, Ah, using this information.
Chapter 2 Solutions
Introductory Chemistry, Books a la Carte Edition (6th Edition)
Ch. 2 - Q1.Express the number 0.000042 in scientific...Ch. 2 - Q2. A graduated cylinder has markings every...Ch. 2 - How many significant figures are in the number...Ch. 2 - Round the number 89.04997 to three significant...Ch. 2 - Q5.Perform this multiplication to the correct...Ch. 2 - Q6.Perform this addition to the correct number of...Ch. 2 - Q7. Perform this calculation to the correct number...Ch. 2 - Convert 76.8 cm to m. a. 0.0768 m b. 7.68 m c....Ch. 2 - Q9.Convert 2855 mg to kg.
a.
b. 2.855 kg
c....Ch. 2 - Q10. A runner runs 4875 ft in 6.85 minutes. What...
Ch. 2 - An automobile travels 97.2 km on 7.88 L of...Ch. 2 - Convert 876.9 in.3 tom3. a. 0.01437m3 b. 22.27 m3...Ch. 2 - Convert 27 m/s to km/hr. a. 97 km/hr b. 7.5 km/hr...Ch. 2 - Q14. A cube measures 2.5cm on each edge and has a...Ch. 2 - What is the mass of 225 mL of a liquid that has a...Ch. 2 - Q16. What is the edge length of a 155-g iron cube?...Ch. 2 - 1. Why is it necessary to include units when...Ch. 2 - Why are the number of digits reported in...Ch. 2 - Why is scientific notation useful?Ch. 2 - If a measured quantity is written correctly, which...Ch. 2 - 5. When do zeros count as significant digits, and...Ch. 2 - 6. How many significant digits are there in exact...Ch. 2 - 7. What limits the number of significant digits in...Ch. 2 - What limits the number of significant digits in a...Ch. 2 - 9. How do we determine significant figures in...Ch. 2 - What are the rules for rounding number?Ch. 2 - 11. What are the basic SI units of length, mass,...Ch. 2 - 12. List the common units of volume.
Ch. 2 - Suppose you are trying to measure the diameter of...Ch. 2 - What is the difference between mass and weight?Ch. 2 - 15. Using a metric ruler, measure these objects to...Ch. 2 - Using a stopwatch, measure each time to the...Ch. 2 - Explain why units are important in calculations.Ch. 2 - How are units treated in a calculation?Ch. 2 - 19. What is a conversion factor?
Ch. 2 - Why does the fundamental value of a quantity not...Ch. 2 - Write the conversion factor that converts a...Ch. 2 - Write conversion factors for each. a. miles to...Ch. 2 - This book outlines a four-step problem-solving...Ch. 2 - Experienced problem solvers always consider both...Ch. 2 - 25. Draw solution map to convert a measurement in...Ch. 2 - Draw a solution map to convert a measurement in...Ch. 2 - 27. Draw a solution map to convert a measurement...Ch. 2 - Draw a solution map to convert a measurement in...Ch. 2 - What density? Explain why density can work as a...Ch. 2 - Explain how you would calculate the density of a...Ch. 2 - 31. Express each number in scientific notation.
a....Ch. 2 - Express each number in scientific notation. a....Ch. 2 - Note: The exercises in the problems section are...Ch. 2 - Express each number in scientific notation. a....Ch. 2 - 35. Express each number in decimal notation (i.e.,...Ch. 2 - 36. Express each number in decimal notation (i.e.,...Ch. 2 - 37. Express each number in decimal notation (i.e.,...Ch. 2 - 38. Express each number in decimal notation (i.e.,...Ch. 2 - 39. Complete the table.
Decimal...Ch. 2 - Complete the table. Decimal Notation Scientific...Ch. 2 - 41. Read each instrument to the correct number of...Ch. 2 - Read each instrument to the correct number of...Ch. 2 - For each measured quantity, underline the zeros...Ch. 2 - For each measured quantity, underline the zeros...Ch. 2 - How many significant figures are in each measured...Ch. 2 - Significant Figures
46. How many significant...Ch. 2 - 47 Correct any entries in the table that are...Ch. 2 - Correct any entries in the table that are wrong....Ch. 2 - Round each number to four significant figures. a....Ch. 2 - Round each number to three significant figures. a....Ch. 2 - 51. Round each number to two significant...Ch. 2 - 52. Round each number to three significant...Ch. 2 - 53. Each number is supposed to be rounded to three...Ch. 2 - Each number is supposed to be rounded to two...Ch. 2 - Round the number on the left to the number of...Ch. 2 - 56. Round the number on the left to the number of...Ch. 2 - Perform each calculation to the correct number of...Ch. 2 - Perform each calculation to the correct number of...Ch. 2 - 59. Correct any answers that have the incorrect...Ch. 2 - 60. Correct any answers that have the incorrect...Ch. 2 - Perform each calculation to the correct number of...Ch. 2 - Perform each calculation to the correct number of...Ch. 2 - Correct any answers that have the incorrect number...Ch. 2 - Correct any answers that have the incorrect number...Ch. 2 - Perform each calculation to the correct number of...Ch. 2 - 66. Perform each calculation to the correct number...Ch. 2 - Correct any answers that have the incorrect number...Ch. 2 - Correct any answers that have the incorrect number...Ch. 2 - Perform each conversion. a.3.55 kg to grams b.8944...Ch. 2 - Perform each conversion. a.155.5 cm to meters...Ch. 2 - Perform each conversion. a.5.88 dL to liters b....Ch. 2 - 72. Perform each conversion.
a.1.08 Mm to...Ch. 2 - Perform each conversion. a. 22.5 in. to...Ch. 2 - Perform each conversion. a. 78.3 in. to...Ch. 2 - Perform each conversion. a.40.0 cm to inches b....Ch. 2 - 76. Perform each conversion.
a.254 cm to inches
b....Ch. 2 - 77. Complete the...Ch. 2 - 78. Complete the...Ch. 2 - 79. Convert g to each unit.
a.kg
b.Mg
c.mg
d....Ch. 2 - Convert 188106 g to each unit. a. mg b. cg c. ng...Ch. 2 - A student loses 3.3 lb in one month. How many...Ch. 2 - 82. A student gains 1.9 lb in two weeks. How many...Ch. 2 - A runner wants to run 10.0 km. She knows that her...Ch. 2 - A cyclist rides at an average speed of 24 mi/h. If...Ch. 2 - 85. A recipe calls for 5.0 qt of milk. What is...Ch. 2 - A gas can hold 2.0 gal of gasoline. What is this...Ch. 2 - 87. Fill in the blanks.
a.
b.
c.
Ch. 2 - Prob. 88ECh. 2 - The hydrogen atom has a volume of approximately...Ch. 2 - 90. Earth has a surface area of 197 million square...Ch. 2 - 91. A house has an area of What is its area in...Ch. 2 - A classroom has a volume of 285m3. What is its...Ch. 2 - Total U.S farmland occupies 954 million acres. How...Ch. 2 - 94. Total average U.S farm occupies 435 acres. How...Ch. 2 - 95. The speed limit on many U.S highways is 65...Ch. 2 - 96. A form of children’s Tylenol is sold as a...Ch. 2 - A prescription medication requires 7.55 mg per kg...Ch. 2 - A prescription medication requires 0.00225 g per...Ch. 2 - A sample of an unknown metal has a mass of 35.4...Ch. 2 - A new penny has a mass 2.49 g and a valume of...Ch. 2 - Glycerol is a syrupy liquid often used in...Ch. 2 - 102. An aluminum engine block has a valume of 4.77...Ch. 2 - A supposedly gold crown is tested to determine its...Ch. 2 - 104. A vase is said to be solid platinum. It...Ch. 2 - Ethylene glycol (antifreeze) has a density of...Ch. 2 - Acetone (fingernailpolish remover) has density of...Ch. 2 - A thief uses a bag of sand to replace a gold...Ch. 2 - One of the particles in an atom is the proton. A...Ch. 2 - A block of metal has a volume 13.4in.3 and weight...Ch. 2 - 110. A log is either oak or pine. it displaces 2.7...Ch. 2 - 111. The density of aluminum is . What is its...Ch. 2 - 112. The density of platinum is . What is its...Ch. 2 - A typical backyard swimming pool holds 150 yd3 of...Ch. 2 - 114. An iceberg has a volume of . What is the mass...Ch. 2 - The mass of fuel in an airplane must be determined...Ch. 2 - Prob. 116ECh. 2 - Honda produces a hybrid electric car called the...Ch. 2 - You rent a car in Germany with a gas mileage...Ch. 2 - Prob. 119ECh. 2 - 120. A hybrid SUV consumes fuel at a rate of 12.8...Ch. 2 - Prob. 121ECh. 2 - Consider these observations on two blocks of...Ch. 2 - 123. You measure the masses and volumes of two...Ch. 2 - A bag contains a mixture of copper and lead BBs....Ch. 2 - Prob. 125ECh. 2 - A copper cube has a mass of 87.2 g. Find the edge...Ch. 2 - 127. Recall from Section 2.1 that NASA lost the...Ch. 2 - 28. A NASA satellite showed that in 2012 the ozone...Ch. 2 - 129. In 1999, scientists discovered a new class of...Ch. 2 - 130. A titanium bicycle frame contains the same...Ch. 2 - Look up the thickness of a human hair. a. Convert...Ch. 2 - 132. The following statements are all true.
a....Ch. 2 - Convert the height of each group member from feet...
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- Hydrogen bonding in water plays a key role in its physical properties. Assume that the energy required to break a hydrogen bond is approximately 8 kJ/mol. Consider a simplified two-state model where a "formed" hydrogen bond is in the ground state and a "broken" bond is in the excited state. Using this model: • Calculate the fraction of broken hydrogen bonds at T = 300 K, and also at T = 273 K and T = 373 K. • At what temperature would approximately 50% of the hydrogen bonds be broken? • What does your result imply about the accuracy or limitations of the two-state model in describing hydrogen bonding in water? Finally, applying your understanding: • Would you expect it to be easier or harder to vaporize water at higher temperatures? Why? If you were to hang wet laundry outside, would it dry more quickly on a warm summer day or on a cold winter day, assuming humidity is constant?arrow_forward(3 pts) Use the Kapustinskii equation to calculate the lattice enthalpy for MgBr2 anddiscuss any differences between this result and that from #4.arrow_forward(3 pts) Silver metal adopts a fcc unit cell structure and has an atomic radius of 144 pm. Fromthis information, calculate the density of silver. Show all work.arrow_forward
- 4. (3 pts) From the information below, determine the lattice enthalpy for MgBr2. Show all work. AH/(kJ mol-¹) Sublimation of Mg(s) +148 lonization of Mg(g) +2187 to Mg2+(g) Vaporization of Br₂(1) +31 Dissociation of Br,(g) +193 Electron gain by Br(g) -331 Formation of MgBr₂(s) -524arrow_forward1. (4 pts-2 pts each part) Consider the crystal structures of NaCl, ZnS, and CsCl (not necessarily shown in this order). a. For one of the three compounds, justify that the unit cell is consistent with stoichiometry of the compound. b. In each of the crystal structures, the cations reside in certain holes in the anions' packing structures. For each compound, what type of holes are occupied by the cations and explain why those particular types of holes are preferred.arrow_forward(2 pts) What do you expect to happen in a Na2O crystal if a Cl− ion replaces one of the O2−ions in the lattice?arrow_forward
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- From the following reduction potentials I2 (s) + 2e- = 2I- (aq) E0= 0.535 V I2 (aq) + 2e- = 2I- (aq) E0= 0.620 V I3- (aq) + 2e- = 3I- (aq) E0= 0.535 V a) Calculate the equilibrium constant for I2 (aq) + I- (aq) = I3- (aq). b) Calculate the equilibrium constant for I2 (s) + I- (aq) = I3- (aq). c) Calculate the solubility of I2 (s) in water.arrow_forward2. (3 pts) Consider the unit cell for the spinel compound, CrFe204. How many total particles are in the unit cell? Also, show how the number of particles and their positions are consistent with the CrFe204 stoichiometry - this may or may not be reflected by the particle colors in the diagram. (HINT: In the diagram, the blue particle is in an interior position while each red particle is either in a corner or face position.)arrow_forwardFrom the following potentials, calculate the activity of Cl- in saturated KCl. E0 (calomel electrode)= 0.268 V E (calomel electrode, saturated KCl)= 0.241 Varrow_forward
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