Crossword Puzzle: In the 2 × 2 box shown here, each answer must be correct four ways: horizontally, vertically, diagonally, and by itself. Instead of words, use symbols of elements. When the puzzle is complete, the four spaces will contain the over-lapping symbols of 10 elements. There is only one correct solution. Horizontal 1–2: two-letter symbol for a metal used in ancient times 3–4: two-letter symbol for a metal that burns in air and is found in Croup 5A Vertical 1–3: two-letter symbol for a metalloid 2–4: two-letter symbol for a metal used in U.S. coins Single squares: All one-letter symbols 1: a colorful non-metal 2: colorless, gaseous non-metal 3: an element that makes fireworks green 4: an element that has medicinal uses Diagonal 1-4: two-letter symbol for an element used in electronics 2-3: two-letter symbol for a metal used with Zr to make wires for superconducting magnets This puzzle first appeared in Chemical & Engineering News , p. 86, December 14, 1987 (submitted by S. J. Cyvin) and in Chem Matters , October 1988.
Crossword Puzzle: In the 2 × 2 box shown here, each answer must be correct four ways: horizontally, vertically, diagonally, and by itself. Instead of words, use symbols of elements. When the puzzle is complete, the four spaces will contain the over-lapping symbols of 10 elements. There is only one correct solution. Horizontal 1–2: two-letter symbol for a metal used in ancient times 3–4: two-letter symbol for a metal that burns in air and is found in Croup 5A Vertical 1–3: two-letter symbol for a metalloid 2–4: two-letter symbol for a metal used in U.S. coins Single squares: All one-letter symbols 1: a colorful non-metal 2: colorless, gaseous non-metal 3: an element that makes fireworks green 4: an element that has medicinal uses Diagonal 1-4: two-letter symbol for an element used in electronics 2-3: two-letter symbol for a metal used with Zr to make wires for superconducting magnets This puzzle first appeared in Chemical & Engineering News , p. 86, December 14, 1987 (submitted by S. J. Cyvin) and in Chem Matters , October 1988.
Solution Summary: The author explains that the table of crossword puzzle is to be completed by using the symbols of elements.
Crossword Puzzle: In the 2 × 2 box shown here, each answer must be correct four ways: horizontally, vertically, diagonally, and by itself. Instead of words, use symbols of elements. When the puzzle is complete, the four spaces will contain the over-lapping symbols of 10 elements. There is only one correct solution.
Horizontal
1–2: two-letter symbol for a metal used in ancient times
3–4: two-letter symbol for a metal that burns in air and is found in Croup 5A
Vertical
1–3: two-letter symbol for a metalloid
2–4: two-letter symbol for a metal used in U.S. coins
Single squares: All one-letter symbols
1: a colorful non-metal
2: colorless, gaseous non-metal
3: an element that makes fireworks green
4: an element that has medicinal uses
Diagonal
1-4: two-letter symbol for an element used in electronics
2-3: two-letter symbol for a metal used with Zr to make wires for superconducting magnets
This puzzle first appeared in Chemical & Engineering News, p. 86, December 14, 1987 (submitted by S. J. Cyvin) and in Chem Matters, October 1988.
There is an instrument in Johnson 334 that measures total-reflectance x-ray fluorescence (TXRF) to do elemental analysis (i.e., determine what elements are present in a sample). A researcher is preparing a to measure calcium content in a series of well water samples by TXRF with an internal standard of vanadium (atomic symbol: V). She has prepared a series of standard solutions to ensure a linear instrument response over the expected Ca concentration range of 40-80 ppm. The concentrations of Ca and V (ppm) and the instrument response (peak area, arbitrary units) are shown below. Also included is a sample spectrum. Equation 1 describes the response factor, K, relating the analyte signal (SA) and the standard signal (SIS) to their respective concentrations (CA and CIS).
Ca, ppm
V, ppm
SCa, arb. units
SV, arb. units
20.0
10.0
14375.11
14261.02
40.0
10.0
36182.15
17997.10
60.0
10.0
39275.74
12988.01
80.0
10.0
57530.75
14268.54
100.0…
A mixture of 0.568 M H₂O, 0.438 M Cl₂O, and 0.710 M HClO are enclosed in a vessel at 25 °C.
H₂O(g) + C₁₂O(g) = 2 HOCl(g)
K = 0.0900 at 25°C
с
Calculate the equilibrium concentrations of each gas at 25 °C.
[H₂O]=
[C₁₂O]=
[HOCI]=
M
Σ
M
What units (if any) does the response factor (K) have? Does the response factor (K) depend upon how the concentration is expressed (e.g. molarity, ppm, ppb, etc.)?
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