PRINCIPLES OF MODERN CHEMISTRY-OWLV2
8th Edition
ISBN: 9781305271609
Author: OXTOBY
Publisher: CENGAGE L
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Macmillan Learning
X
Chapter 12 HW - General, Organic, and E
Ubiquinone, or coenzyme Q, is an electron acceptor in the electron transport chain.
H3CO.
CH3
(CH2CH=C-CH2)10H
H3CO
ubiquinone
CH3
Modify the molecule so that it represents the reduced form of ubiquinone. You may need to add or remove atoms or
bonds. Let the letter X represent the (CH2CH=C(CH3)CH2)10H group.
Select
/
Draw
Templates Groups
More
C
0
H
о
0
Erase
Q2Q
Draw the enolate anion and the ester that would be needed to
make this product through a Claisen condensation reaction.
ол
1. (10 points). Draw a stepwise detailed mechanism for the following reaction
showing all the substitution and the elimination products formed. Label the
type of the mechanism (SN1, SN2, E1 or E2). Show stereochemistry when
applicable.
Br
CH3CH2OH
H₂O
2. (10 points)
0
Br
CH3O Na
DMSO
Draw the detailed mechanism
showing ALL possible products
formed including stereochemistry
and Label mechanism as SN1,
SN2, E1 or E2. Show
stereochemistry when applicable.
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