CHEMISTRY,AP EDITION-W/ACCESS (HS)
CHEMISTRY,AP EDITION-W/ACCESS (HS)
9th Edition
ISBN: 9781285732930
Author: ZUMDAHL
Publisher: CENGAGE L
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Chapter 19, Problem 47E
Interpretation Introduction

Interpretation:

Given the mass defect of L6i nucleus its atomic mass has to be calculated.

Concept Introduction:

Atomic mass of an atom is often referred to as the sum of number of protons and number of neutrons.  But the actual mass of nucleus is not equivalent to the sum of number of protons and number of neutrons.  The difference between these two is called mass defect which occurs due to the loss of energy during the formation of nucleus. It is represented as,

Δm = [ Z(mp + me) + (AZ)mn ]  matomΔm  = mass defect, Z = atomic number(number of protons), A = mass numbermp   = mass of proton, me = mass of electron, mn = mass of neutronmatom= mass of nuclide XZA

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Part II. two unbranched ketone have molecular formulla (C8H100). El-ms showed that both of them have a molecular ion peak at m/2 =128. However ketone (A) has a fragment peak at m/2 = 99 and 72 while ketone (B) snowed a fragment peak at m/2 = 113 and 58. 9) Propose the most plausible structures for both ketones b) Explain how you arrived at your conclusion by drawing the Structures of the distinguishing fragments for each ketone, including their fragmentation mechanisms.
Part V. Draw the structure of compound tecla using the IR spectrum Cobtained from the compound in KBr pellet) and the mass spectrum as shown below. The mass spectrum of compound Tesla showed strong mt peak at 71. TRANSMITTANCE LOD Relative Intensity 100 MS-NW-1539 40 20 80 T 44 55 10 15 20 25 30 35 40 45 50 55 60 65 70 75 m/z D 4000 3000 2000 1500 1000 500 HAVENUMBERI-11

Chapter 19 Solutions

CHEMISTRY,AP EDITION-W/ACCESS (HS)

Ch. 19 - Prob. 1QCh. 19 - Prob. 2QCh. 19 - Prob. 3QCh. 19 - Prob. 4QCh. 19 - Prob. 5QCh. 19 - Prob. 6QCh. 19 - Prob. 7QCh. 19 - Prob. 8QCh. 19 - Prob. 9QCh. 19 - Prob. 10QCh. 19 - Prob. 11ECh. 19 - Prob. 12ECh. 19 - Prob. 13ECh. 19 - Prob. 14ECh. 19 - Prob. 15ECh. 19 - Prob. 16ECh. 19 - Prob. 17ECh. 19 - Prob. 18ECh. 19 - Prob. 19ECh. 19 - Prob. 20ECh. 19 - Prob. 21ECh. 19 - Prob. 23ECh. 19 - Prob. 24ECh. 19 - Prob. 26ECh. 19 - Prob. 27ECh. 19 - Prob. 28ECh. 19 - Prob. 29ECh. 19 - Prob. 30ECh. 19 - Prob. 31ECh. 19 - Prob. 32ECh. 19 - Prob. 33ECh. 19 - Prob. 34ECh. 19 - Prob. 35ECh. 19 - Prob. 36ECh. 19 - Prob. 37ECh. 19 - Prob. 38ECh. 19 - Prob. 39ECh. 19 - Prob. 40ECh. 19 - Prob. 41ECh. 19 - Prob. 42ECh. 19 - Prob. 43ECh. 19 - Prob. 44ECh. 19 - Prob. 46ECh. 19 - Prob. 47ECh. 19 - Prob. 48ECh. 19 - Prob. 49ECh. 19 - Prob. 50ECh. 19 - Prob. 51ECh. 19 - Prob. 52ECh. 19 - Prob. 53ECh. 19 - Prob. 54ECh. 19 - Prob. 55ECh. 19 - Prob. 56ECh. 19 - Prob. 57ECh. 19 - Prob. 58ECh. 19 - Prob. 59AECh. 19 - Prob. 60AECh. 19 - Prob. 61AECh. 19 - Prob. 62AECh. 19 - Prob. 63AECh. 19 - Prob. 64AECh. 19 - Prob. 65AECh. 19 - Prob. 66AECh. 19 - Prob. 67AECh. 19 - Prob. 68AECh. 19 - Prob. 69AECh. 19 - Prob. 70AECh. 19 - Prob. 71AECh. 19 - Prob. 72AECh. 19 - Prob. 73CWPCh. 19 - Prob. 74CWPCh. 19 - Prob. 75CWPCh. 19 - Prob. 76CWPCh. 19 - Prob. 77CWPCh. 19 - Prob. 78CWPCh. 19 - Prob. 79CPCh. 19 - Prob. 80CPCh. 19 - Prob. 81CPCh. 19 - Prob. 82CPCh. 19 - Prob. 83CPCh. 19 - Prob. 84CPCh. 19 - Prob. 85CPCh. 19 - Prob. 86CPCh. 19 - Prob. 87IPCh. 19 - Prob. 88IP
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