(a) Interpretation: The structure of geometrical isomers (if present) of the complex [ Mn ( H 2 O ) 2 ( NO 2 ) 4 2 − ] needs to be determined. Concept introduction: Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cation or anion. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The chemical and physical properties of the complex ions and the coordination compounds formed by them depend on the spatial arrangement of ligands which are attached directly to the central metal atom.

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Answer 1

Question

Chapter 19, Problem 28QAP

Interpretation Introduction

(a)

Interpretation:

The structure of geometrical isomers (if present) of the complex [Mn(H2O)2(NO2)42−] needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cation or anion. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The chemical and physical properties of the complex ions and the coordination compounds formed by them depend on the spatial arrangement of ligands which are attached directly to the central metal atom.

Interpretation Introduction

(b)

Interpretation:

The structure of geometrical isomers (if present) of the complex [Pt(NH3)3(Cl3)+] needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cation or anion. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The chemical and physical properties of the complex ions and the coordination compounds formed by them depend on the spatial arrangement of ligands which are attached directly to the central metal atom.

Interpretation Introduction

(c)

Interpretation:

The structure of geometrical isomers (if present) of the complex 13 [Al(C2O4)(CO)2(Br)2−] needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cation or anion. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The chemical and physical properties of the complex ions and the coordination compounds formed by them depend on the spatial arrangement of ligands which are attached directly to the central metal atom.

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You are asked to use curved arrows to generate the significant resonance structures for the following series of compounds and to label the most significant contributor. Identify the errors that would occur if you do not expand the Lewis structures or double-check the mechanisms. Also provide the correct answers.

how to get limiting reactant and % yield based off this data Compound Mass 6) Volume(mL Ben zaphone-5008 ne Acetic Acid 1. Sam L 2-propanot 8.00 Benzopin- a col 030445 Benzopin a Colone 0.06743 Results Compound Melting Point (°c) Benzopin acol 172°c - 175.8 °c Benzoping to lone 1797-180.9

Assign ALL signals for the proton and carbon NMR spectra on the following pages.

Answer 2

Question

Chapter 19, Problem 28QAP

Interpretation Introduction

(a)

Interpretation:

The structure of geometrical isomers (if present) of the complex [Mn(H2O)2(NO2)42−] needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cation or anion. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The chemical and physical properties of the complex ions and the coordination compounds formed by them depend on the spatial arrangement of ligands which are attached directly to the central metal atom.

Interpretation Introduction

(b)

Interpretation:

The structure of geometrical isomers (if present) of the complex [Pt(NH3)3(Cl3)+] needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cation or anion. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The chemical and physical properties of the complex ions and the coordination compounds formed by them depend on the spatial arrangement of ligands which are attached directly to the central metal atom.

Interpretation Introduction

(c)

Interpretation:

The structure of geometrical isomers (if present) of the complex 13 [Al(C2O4)(CO)2(Br)2−] needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cation or anion. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The chemical and physical properties of the complex ions and the coordination compounds formed by them depend on the spatial arrangement of ligands which are attached directly to the central metal atom.

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Answer 3

Question

Chapter 19, Problem 28QAP

Interpretation Introduction

(a)

Interpretation:

The structure of geometrical isomers (if present) of the complex [Mn(H2O)2(NO2)42−] needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cation or anion. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The chemical and physical properties of the complex ions and the coordination compounds formed by them depend on the spatial arrangement of ligands which are attached directly to the central metal atom.

Interpretation Introduction

(b)

Interpretation:

The structure of geometrical isomers (if present) of the complex [Pt(NH3)3(Cl3)+] needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cation or anion. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The chemical and physical properties of the complex ions and the coordination compounds formed by them depend on the spatial arrangement of ligands which are attached directly to the central metal atom.

Interpretation Introduction

(c)

Interpretation:

The structure of geometrical isomers (if present) of the complex 13 [Al(C2O4)(CO)2(Br)2−] needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cation or anion. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The chemical and physical properties of the complex ions and the coordination compounds formed by them depend on the spatial arrangement of ligands which are attached directly to the central metal atom.

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Answer 4

Question

Chapter 19, Problem 28QAP

Interpretation Introduction

(a)

Interpretation:

The structure of geometrical isomers (if present) of the complex [Mn(H2O)2(NO2)42−] needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cation or anion. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The chemical and physical properties of the complex ions and the coordination compounds formed by them depend on the spatial arrangement of ligands which are attached directly to the central metal atom.

Interpretation Introduction

(b)

Interpretation:

The structure of geometrical isomers (if present) of the complex [Pt(NH3)3(Cl3)+] needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cation or anion. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The chemical and physical properties of the complex ions and the coordination compounds formed by them depend on the spatial arrangement of ligands which are attached directly to the central metal atom.

Interpretation Introduction

(c)

Interpretation:

The structure of geometrical isomers (if present) of the complex 13 [Al(C2O4)(CO)2(Br)2−] needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cation or anion. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The chemical and physical properties of the complex ions and the coordination compounds formed by them depend on the spatial arrangement of ligands which are attached directly to the central metal atom.

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Answer 5

Chapter 19, Problem 28QAP

Interpretation Introduction

(a)

Interpretation:

The structure of geometrical isomers (if present) of the complex [Mn(H2O)2(NO2)42−] needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cation or anion. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The chemical and physical properties of the complex ions and the coordination compounds formed by them depend on the spatial arrangement of ligands which are attached directly to the central metal atom.

Interpretation Introduction

(b)

Interpretation:

The structure of geometrical isomers (if present) of the complex [Pt(NH3)3(Cl3)+] needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cation or anion. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The chemical and physical properties of the complex ions and the coordination compounds formed by them depend on the spatial arrangement of ligands which are attached directly to the central metal atom.

Interpretation Introduction

(c)

Interpretation:

The structure of geometrical isomers (if present) of the complex 13 [Al(C2O4)(CO)2(Br)2−] needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cation or anion. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The chemical and physical properties of the complex ions and the coordination compounds formed by them depend on the spatial arrangement of ligands which are attached directly to the central metal atom.

Answer 6

Chapter 19, Problem 28QAP

Interpretation Introduction

(a)

Interpretation:

The structure of geometrical isomers (if present) of the complex [Mn(H2O)2(NO2)42−] needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cation or anion. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The chemical and physical properties of the complex ions and the coordination compounds formed by them depend on the spatial arrangement of ligands which are attached directly to the central metal atom.

Answer 7

Chapter 19, Problem 28QAP

Interpretation Introduction

(a)

Interpretation:

The structure of geometrical isomers (if present) of the complex [Mn(H2O)2(NO2)42−] needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cation or anion. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The chemical and physical properties of the complex ions and the coordination compounds formed by them depend on the spatial arrangement of ligands which are attached directly to the central metal atom.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The structure of geometrical isomers (if present) of the complex [Pt(NH3)3(Cl3)+] needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cation or anion. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The chemical and physical properties of the complex ions and the coordination compounds formed by them depend on the spatial arrangement of ligands which are attached directly to the central metal atom.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The structure of geometrical isomers (if present) of the complex [Pt(NH3)3(Cl3)+] needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cation or anion. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The chemical and physical properties of the complex ions and the coordination compounds formed by them depend on the spatial arrangement of ligands which are attached directly to the central metal atom.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The structure of geometrical isomers (if present) of the complex 13 [Al(C2O4)(CO)2(Br)2−] needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cation or anion. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The chemical and physical properties of the complex ions and the coordination compounds formed by them depend on the spatial arrangement of ligands which are attached directly to the central metal atom.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The structure of geometrical isomers (if present) of the complex 13 [Al(C2O4)(CO)2(Br)2−] needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cation or anion. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The chemical and physical properties of the complex ions and the coordination compounds formed by them depend on the spatial arrangement of ligands which are attached directly to the central metal atom.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 19 - Prob. 1QAP Ch. 19 - Prob. 2QAP Ch. 19 - Prob. 3QAP Ch. 19 - Platinum(II) forms many complexes, among them...Ch. 19 - Prob. 5QAP Ch. 19 - What is the coordination number of the central...Ch. 19 - Prob. 7QAP Ch. 19 - Prob. 8QAP Ch. 19 - Prob. 9QAP Ch. 19 - Prob. 10QAP

Solution Summary: The author explains the structure of geometrical isomers of a complex ion, which is octahedral and square planer.

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Chapter 19 Solutions