Atkins' Physical Chemistry
11th Edition
ISBN: 9780198769866
Author: ATKINS, P. W. (peter William), De Paula, Julio, Keeler, JAMES
Publisher: Oxford University Press
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Chapter 19, Problem 19B.2P
Interpretation Introduction
Interpretation:
The value of alpha for the adsorption equilibrium and the adsorption volume corresponding to complete coverage has to be calculated.
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Predict the major products of this organic reaction.
Be sure to use wedge and dash bonds when necessary, for example to distinguish between different major products.
☐
☐
: ☐
+
NaOH
HO
2
Click and drag to start
drawing a structure.
Shown below are five NMR spectra for five different C6H10O2 compounds. For each spectrum, draw the structure of the compound, and assign the spectrum by labeling H's in your structure (or in a second drawing of the structure) with the chemical shifts of the corresponding signals (which can be estimated to nearest 0.1 ppm). IR information is also provided. As a reminder, a peak near 1700 cm-1 is consistent with the presence of a carbonyl (C=O), and a peak near 3300 cm-1 is consistent with the presence of an O–H.
Extra information: For C6H10O2 , there must be either 2 double bonds, or 1 triple bond, or two rings to account for the unsaturation. There is no two rings for this problem.
A strong band was observed in the IR at 1717 cm-1
Predict the major products of the organic reaction below.
: ☐
+
Х
ك
OH
1. NaH
2. CH₂Br
Click and drag to start
drawing a structure.
Chapter 19 Solutions
Atkins' Physical Chemistry
Ch. 19 - Prob. 19A.1STCh. 19 - Prob. 19B.1STCh. 19 - Prob. 19B.2STCh. 19 - Prob. 19D.2STCh. 19 - Prob. 19A.2DQCh. 19 - Prob. 19A.2AECh. 19 - Prob. 19A.2BECh. 19 - Prob. 19A.2PCh. 19 - Prob. 19A.4PCh. 19 - Prob. 19B.1AE
Ch. 19 - Prob. 19B.1BECh. 19 - Prob. 19B.2AECh. 19 - Prob. 19B.5AECh. 19 - Prob. 19B.5BECh. 19 - Prob. 19B.6AECh. 19 - Prob. 19B.6BECh. 19 - Prob. 19B.7AECh. 19 - Prob. 19B.7BECh. 19 - Prob. 19B.8AECh. 19 - Prob. 19B.8BECh. 19 - Prob. 19B.9AECh. 19 - Prob. 19B.9BECh. 19 - Prob. 19B.2PCh. 19 - Prob. 19B.4PCh. 19 - Prob. 19B.11PCh. 19 - Prob. 19C.1DQCh. 19 - Prob. 19C.1AECh. 19 - Prob. 19C.1BECh. 19 - Prob. 19C.1PCh. 19 - Prob. 19C.2PCh. 19 - Prob. 19C.3PCh. 19 - Prob. 19D.1DQCh. 19 - Prob. 19D.2DQCh. 19 - Prob. 19D.1AECh. 19 - Prob. 19D.1BECh. 19 - Prob. 19D.2AECh. 19 - Prob. 19D.2BECh. 19 - Prob. 19D.3AECh. 19 - Prob. 19D.3BECh. 19 - Prob. 19D.4AECh. 19 - Prob. 19D.4BECh. 19 - Prob. 19D.5BECh. 19 - Prob. 19D.6AECh. 19 - Prob. 19D.6BECh. 19 - Prob. 19D.8AECh. 19 - Prob. 19D.8BECh. 19 - Prob. 19D.2PCh. 19 - Prob. 19D.3PCh. 19 - Prob. 19D.5PCh. 19 - Prob. 19D.6PCh. 19 - Prob. 19.5IA
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