CHEMISTRY:MOLECULAR...(LL)-W/CONNECT
CHEMISTRY:MOLECULAR...(LL)-W/CONNECT
9th Edition
ISBN: 9781264094202
Author: SILBERBERG
Publisher: MCG
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Chapter 19, Problem 19.70P

(a)

Interpretation Introduction

Interpretation:

For lead(II) iodide, the ion-product expression has to be given.

Concept Introduction:

Solubility product constant:

The equilibrium constant of a more soluble ionic compound in water at the higher solubility is known as solubility product constant.

The equilibrium constant of more soluble ionic compound is given by KSP and it is expressed by product of each ion present in the compound which are raised to the power of number respective ion present in the compound to give a maximum solubility of the compound.

MmXx(s) mMn+(aq) + xXy-(aq)Ksp = [Mn+]m[Xy-]x

Ion product:

The multiplication of concentrations of ions which are raised to the power of number of respective ions present in the molecular formula.  This gives the ion product.

MmXx(s) mMn+(aq) + xXy-(aq)IP = [Mn+]tm×[Xy-]x

Precipitation occurs when solution is supersaturated, IP>Ksp.

Precipitation will not occurs when solution is saturated and in equilibrium, IP>Ksp.

Precipitation will not occurs when solution is unsaturated, IP<Ksp.

(b)

Interpretation Introduction

Interpretation:

For strontium sulfate, the ion-product expression has to be given.

Concept Introduction:

Solubility product constant:

The equilibrium constant of a more soluble ionic compound in water at the higher solubility is known as solubility product constant.

The equilibrium constant of more soluble ionic compound is given by KSP and it is expressed by product of each ion present in the compound which are raised to the power of number respective ion present in the compound to give a maximum solubility of the compound.

MmXx(s) mMn+(aq) + xXy-(aq)Ksp = [Mn+]m[Xy-]x

Ion product:

The multiplication of concentrations of ions which are raised to the power of number of respective ions present in the molecular formula.  This gives the ion product.

MmXx(s) mMn+(aq) + xXy-(aq)IP = [Mn+]tm×[Xy-]x

Precipitation occurs when solution is supersaturated, IP>Ksp.

Precipitation will not occurs when solution is saturated and in equilibrium, IP>Ksp.

Precipitation will not occurs when solution is unsaturated, IP<Ksp.

(c)

Interpretation Introduction

Interpretation:

For chromium(III) hydroxide, the ion-product expression has to be given.

Concept Introduction:

Solubility product constant:

The equilibrium constant of a more soluble ionic compound in water at the higher solubility is known as solubility product constant.

The equilibrium constant of more soluble ionic compound is given by KSP and it is expressed by product of each ion present in the compound which are raised to the power of number respective ion present in the compound to give a maximum solubility of the compound.

MmXx(s) mMn+(aq) + xXy-(aq)Ksp = [Mn+]m[Xy-]x

Ion product:

The multiplication of concentrations of ions which are raised to the power of number of respective ions present in the molecular formula.  This gives the ion product.

MmXx(s) mMn+(aq) + xXy-(aq)IP = [Mn+]tm×[Xy-]x

Precipitation occurs when solution is supersaturated, IP>Ksp.

Precipitation will not occurs when solution is saturated and in equilibrium, IP>Ksp.

Precipitation will not occurs when solution is unsaturated, IP<Ksp.

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Transmitance 3. Which one of the following compounds corresponds to this IR spectrum? Point out the absorption band(s) that helped you decide. OH H3C OH H₂C CH3 H3C CH3 H3C INFRARED SPECTRUM 0.8- 0.6 0.4- 0.2 3000 2000 1000 Wavenumber (cm-1) 4. Consider this compound: H3C On the structure above, label the different types of H's as A, B, C, etc. In table form, list the labeled signals, and for each one state the number of hydrogens, their shifts, and the splitting you would observe for these hydrogens in the ¹H NMR spectrum. Label # of hydrogens splitting Shift (2)
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