(a) Interpretation: A diene that would react with Grubbs catalyst to produce the given compound is to be drawn. Concept introduction: An alkene metathesis occurs when one or more alkenes are treated with Grubbs catalyst, which contains a Ru=C bond. In the product of an alkene metathesis, the fragments that are joined by a double bond were initially part of a double bond to other fragments in the reactant. These reactions are particularly useful when the reactants are terminal alkenes. When the reaction produces a new ring, it is called ring-closing metathesis. A ring is formed in the reaction; therefore, two C=C terminal groups in the reactant must be on the same molecule.

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Answer 1

Question

Chapter 19, Problem 19.63P

Interpretation Introduction

(a)

Interpretation:

A diene that would react with Grubbs catalyst to produce the given compound is to be drawn.

Concept introduction:

An alkene metathesis occurs when one or more alkenes are treated with Grubbs catalyst, which contains a Ru=C bond. In the product of an alkene metathesis, the fragments that are joined by a double bond were initially part of a double bond to other fragments in the reactant. These reactions are particularly useful when the reactants are terminal alkenes. When the reaction produces a new ring, it is called ring-closing metathesis. A ring is formed in the reaction; therefore, two C=C terminal groups in the reactant must be on the same molecule.

Interpretation Introduction

(b)

Interpretation:

A diene that would react with Grubbs catalyst to produce the given compound is to be drawn.

Concept introduction:

An alkene metathesis occurs when one or more alkenes is treated with Grubbs catalyst, which contains a Ru=C bond. In the product of an alkene metathesis, the fragments that are joined by a double bond were initially part of a double bond to other fragments in the reactant. These reactions are particularly useful when the reactants are terminal alkenes. When the reaction produces a new ring, it is called a ring-closing metathesis. A ring is formed in the reaction, therefore, two C=C terminal groups in the reactant must be on the same molecule.

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#1. Retro-Electrochemical Reaction: A ring has been made, but the light is causing the molecule to un- cyclize. Undo the ring into all possible molecules. (2pts, no partial credit) hv

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I have a question about this problem involving mechanisms and drawing curved arrows for acids and bases. I know we need to identify the nucleophile and electrophile, but are there different types of reactions? For instance, what about Grignard reagents and other types that I might not be familiar with? Can you help me with this? I want to identify the names of the mechanisms for problems 1-14, such as Gilman reagents and others. Are they all the same? Also, could you rewrite it so I can better understand? The handwriting is pretty cluttered. Additionally, I need to label the nucleophile and electrophile, but my main concern is whether those reactions differ, like the "Brønsted-Lowry acid-base mechanism, Lewis acid-base mechanism, acid-catalyzed mechanisms, acid-catalyzed reactions, base-catalyzed reactions, nucleophilic substitution mechanisms (SN1 and SN2), elimination reactions (E1 and E2), organometallic mechanisms, and so forth."

Answer 2

Question

Chapter 19, Problem 19.63P

Interpretation Introduction

(a)

Interpretation:

A diene that would react with Grubbs catalyst to produce the given compound is to be drawn.

Concept introduction:

An alkene metathesis occurs when one or more alkenes are treated with Grubbs catalyst, which contains a Ru=C bond. In the product of an alkene metathesis, the fragments that are joined by a double bond were initially part of a double bond to other fragments in the reactant. These reactions are particularly useful when the reactants are terminal alkenes. When the reaction produces a new ring, it is called ring-closing metathesis. A ring is formed in the reaction; therefore, two C=C terminal groups in the reactant must be on the same molecule.

Interpretation Introduction

(b)

Interpretation:

A diene that would react with Grubbs catalyst to produce the given compound is to be drawn.

Concept introduction:

An alkene metathesis occurs when one or more alkenes is treated with Grubbs catalyst, which contains a Ru=C bond. In the product of an alkene metathesis, the fragments that are joined by a double bond were initially part of a double bond to other fragments in the reactant. These reactions are particularly useful when the reactants are terminal alkenes. When the reaction produces a new ring, it is called a ring-closing metathesis. A ring is formed in the reaction, therefore, two C=C terminal groups in the reactant must be on the same molecule.

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Answer 3

Question

Chapter 19, Problem 19.63P

Interpretation Introduction

(a)

Interpretation:

A diene that would react with Grubbs catalyst to produce the given compound is to be drawn.

Concept introduction:

An alkene metathesis occurs when one or more alkenes are treated with Grubbs catalyst, which contains a Ru=C bond. In the product of an alkene metathesis, the fragments that are joined by a double bond were initially part of a double bond to other fragments in the reactant. These reactions are particularly useful when the reactants are terminal alkenes. When the reaction produces a new ring, it is called ring-closing metathesis. A ring is formed in the reaction; therefore, two C=C terminal groups in the reactant must be on the same molecule.

Interpretation Introduction

(b)

Interpretation:

A diene that would react with Grubbs catalyst to produce the given compound is to be drawn.

Concept introduction:

An alkene metathesis occurs when one or more alkenes is treated with Grubbs catalyst, which contains a Ru=C bond. In the product of an alkene metathesis, the fragments that are joined by a double bond were initially part of a double bond to other fragments in the reactant. These reactions are particularly useful when the reactants are terminal alkenes. When the reaction produces a new ring, it is called a ring-closing metathesis. A ring is formed in the reaction, therefore, two C=C terminal groups in the reactant must be on the same molecule.

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Answer 4

Question

Chapter 19, Problem 19.63P

Interpretation Introduction

(a)

Interpretation:

A diene that would react with Grubbs catalyst to produce the given compound is to be drawn.

Concept introduction:

An alkene metathesis occurs when one or more alkenes are treated with Grubbs catalyst, which contains a Ru=C bond. In the product of an alkene metathesis, the fragments that are joined by a double bond were initially part of a double bond to other fragments in the reactant. These reactions are particularly useful when the reactants are terminal alkenes. When the reaction produces a new ring, it is called ring-closing metathesis. A ring is formed in the reaction; therefore, two C=C terminal groups in the reactant must be on the same molecule.

Interpretation Introduction

(b)

Interpretation:

A diene that would react with Grubbs catalyst to produce the given compound is to be drawn.

Concept introduction:

An alkene metathesis occurs when one or more alkenes is treated with Grubbs catalyst, which contains a Ru=C bond. In the product of an alkene metathesis, the fragments that are joined by a double bond were initially part of a double bond to other fragments in the reactant. These reactions are particularly useful when the reactants are terminal alkenes. When the reaction produces a new ring, it is called a ring-closing metathesis. A ring is formed in the reaction, therefore, two C=C terminal groups in the reactant must be on the same molecule.

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Answer 5

Chapter 19, Problem 19.63P

Interpretation Introduction

(a)

Interpretation:

A diene that would react with Grubbs catalyst to produce the given compound is to be drawn.

Concept introduction:

An alkene metathesis occurs when one or more alkenes are treated with Grubbs catalyst, which contains a Ru=C bond. In the product of an alkene metathesis, the fragments that are joined by a double bond were initially part of a double bond to other fragments in the reactant. These reactions are particularly useful when the reactants are terminal alkenes. When the reaction produces a new ring, it is called ring-closing metathesis. A ring is formed in the reaction; therefore, two C=C terminal groups in the reactant must be on the same molecule.

Interpretation Introduction

(b)

Interpretation:

A diene that would react with Grubbs catalyst to produce the given compound is to be drawn.

Concept introduction:

An alkene metathesis occurs when one or more alkenes is treated with Grubbs catalyst, which contains a Ru=C bond. In the product of an alkene metathesis, the fragments that are joined by a double bond were initially part of a double bond to other fragments in the reactant. These reactions are particularly useful when the reactants are terminal alkenes. When the reaction produces a new ring, it is called a ring-closing metathesis. A ring is formed in the reaction, therefore, two C=C terminal groups in the reactant must be on the same molecule.

Answer 6

Chapter 19, Problem 19.63P

Interpretation Introduction

(a)

Interpretation:

A diene that would react with Grubbs catalyst to produce the given compound is to be drawn.

Concept introduction:

An alkene metathesis occurs when one or more alkenes are treated with Grubbs catalyst, which contains a Ru=C bond. In the product of an alkene metathesis, the fragments that are joined by a double bond were initially part of a double bond to other fragments in the reactant. These reactions are particularly useful when the reactants are terminal alkenes. When the reaction produces a new ring, it is called ring-closing metathesis. A ring is formed in the reaction; therefore, two C=C terminal groups in the reactant must be on the same molecule.

Answer 7

Chapter 19, Problem 19.63P

Interpretation Introduction

(a)

Interpretation:

A diene that would react with Grubbs catalyst to produce the given compound is to be drawn.

Concept introduction:

An alkene metathesis occurs when one or more alkenes are treated with Grubbs catalyst, which contains a Ru=C bond. In the product of an alkene metathesis, the fragments that are joined by a double bond were initially part of a double bond to other fragments in the reactant. These reactions are particularly useful when the reactants are terminal alkenes. When the reaction produces a new ring, it is called ring-closing metathesis. A ring is formed in the reaction; therefore, two C=C terminal groups in the reactant must be on the same molecule.

Answer 8

Interpretation Introduction

(b)

Interpretation:

A diene that would react with Grubbs catalyst to produce the given compound is to be drawn.

Concept introduction:

An alkene metathesis occurs when one or more alkenes is treated with Grubbs catalyst, which contains a Ru=C bond. In the product of an alkene metathesis, the fragments that are joined by a double bond were initially part of a double bond to other fragments in the reactant. These reactions are particularly useful when the reactants are terminal alkenes. When the reaction produces a new ring, it is called a ring-closing metathesis. A ring is formed in the reaction, therefore, two C=C terminal groups in the reactant must be on the same molecule.

Answer 9

Interpretation Introduction

(b)

Interpretation:

A diene that would react with Grubbs catalyst to produce the given compound is to be drawn.

Concept introduction:

An alkene metathesis occurs when one or more alkenes is treated with Grubbs catalyst, which contains a Ru=C bond. In the product of an alkene metathesis, the fragments that are joined by a double bond were initially part of a double bond to other fragments in the reactant. These reactions are particularly useful when the reactants are terminal alkenes. When the reaction produces a new ring, it is called a ring-closing metathesis. A ring is formed in the reaction, therefore, two C=C terminal groups in the reactant must be on the same molecule.

Answer 10

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Answer 12

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Answer 13

Ch. 19 - Prob. 19.1P Ch. 19 - Prob. 19.2P Ch. 19 - Prob. 19.3P Ch. 19 - Prob. 19.4P Ch. 19 - Prob. 19.5P Ch. 19 - Prob. 19.6P Ch. 19 - Prob. 19.7P Ch. 19 - Prob. 19.8P Ch. 19 - Prob. 19.9P Ch. 19 - Prob. 19.10P

Solution Summary: The author explains how a diene reacts with Grubbs catalyst to produce the given compound by undoing alkene metathesis.

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Chapter 19 Solutions