The use of amine synthesis for the conversion of allybromide to allylamine is to be shown. Concept introduction: The Gabriel synthesis is used for the preparation of primary amines . It is also called Gabriel phthalimide synthesis. In this synthesis N − alkylated potassium or sodium salt of phthalimide is hydrolysed with alkalies. Such alkaline hydrolysis results in corresponding primary amine.

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Answer 1

Question

Chapter 19, Problem 19.48SP

(a)

Interpretation Introduction

Interpretation:

The use of amine synthesis for the conversion of allybromide to allylamine is to be shown.

Concept introduction:

The Gabriel synthesis is used for the preparation of primary amines. It is also called Gabriel phthalimide synthesis. In this synthesis N− alkylated potassium or sodium salt of phthalimide is hydrolysed with alkalies. Such alkaline hydrolysis results in corresponding primary amine.

(b)

Interpretation Introduction

Interpretation:

The use of amine synthesis for the conversion of ethylbenzene to p-ethylaniline is to be shown.

Concept introduction:

The Gabriel synthesis is used for the preparation of primary amines. It is also called Gabriel phthalimide synthesis. In this synthesis N− alkylated potassium or sodium salt of phthalimide is hydrolysed with alkalies. Such alkaline hydrolysis results in corresponding primary amine.

(c)

Interpretation Introduction

Interpretation:

The use of amine synthesis for the conversion of 1-bromo-3-phenylheptane to 3-phenylheptan-1-amine is to be shown.

Concept introduction:

The Gabriel synthesis is used for the preparation of primary amines. It is also called Gabriel phthalimide synthesis. In this synthesis N− alkylated potassium or sodium salt of phthalimide is hydrolysed with alkalies. Such alkaline hydrolysis results in corresponding primary amine.

(d)

Interpretation Introduction

Interpretation:

The use of amine synthesis for the conversion of 1-bromo-3-phenylheptane to 4-phenyloctan-1-amine is to be shown.

Concept introduction:

The Gabriel synthesis is used for the preparation of primary amines. It is also called Gabriel phthalimide synthesis. In this synthesis N− alkylated potassium or sodium salt of phthalimide is hydrolysed with alkalies. Such alkaline hydrolysis results in corresponding primary amine.

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Please choose the best reagents to complete the following reaction

Problem 6-17 Look at the following energy diagram: Energy Reaction progress (a) Is AG for the reaction positive or negative? Label it on the diagram. (b) How many steps are involved in the reaction? (c) How many transition states are there? Label them on the diagram. Problem 6-19 What is the difference between a transition state and an intermediate? Problem 6-21 Draw an energy diagram for a two-step reaction with Keq > 1. Label the overall AG°, transition states, and intermediate. Is AG° positive or negative? Problem 6-23 Draw an energy diagram for a reaction with Keq = 1. What is the value of AG° in this reaction?

Problem 6-37 Draw the different monochlorinated constitutional isomers you would obtain by the radical chlorination of the following compounds. (b) (c) Problem 6-39 Show the structure of the carbocation that would result when each of the following alkenes reacts with an acid, H+. (a) (b) (c)

Answer 2

Question

Chapter 19, Problem 19.48SP

(a)

Interpretation Introduction

Interpretation:

The use of amine synthesis for the conversion of allybromide to allylamine is to be shown.

Concept introduction:

The Gabriel synthesis is used for the preparation of primary amines. It is also called Gabriel phthalimide synthesis. In this synthesis N− alkylated potassium or sodium salt of phthalimide is hydrolysed with alkalies. Such alkaline hydrolysis results in corresponding primary amine.

(b)

Interpretation Introduction

Interpretation:

The use of amine synthesis for the conversion of ethylbenzene to p-ethylaniline is to be shown.

Concept introduction:

The Gabriel synthesis is used for the preparation of primary amines. It is also called Gabriel phthalimide synthesis. In this synthesis N− alkylated potassium or sodium salt of phthalimide is hydrolysed with alkalies. Such alkaline hydrolysis results in corresponding primary amine.

(c)

Interpretation Introduction

Interpretation:

The use of amine synthesis for the conversion of 1-bromo-3-phenylheptane to 3-phenylheptan-1-amine is to be shown.

Concept introduction:

The Gabriel synthesis is used for the preparation of primary amines. It is also called Gabriel phthalimide synthesis. In this synthesis N− alkylated potassium or sodium salt of phthalimide is hydrolysed with alkalies. Such alkaline hydrolysis results in corresponding primary amine.

(d)

Interpretation Introduction

Interpretation:

The use of amine synthesis for the conversion of 1-bromo-3-phenylheptane to 4-phenyloctan-1-amine is to be shown.

Concept introduction:

The Gabriel synthesis is used for the preparation of primary amines. It is also called Gabriel phthalimide synthesis. In this synthesis N− alkylated potassium or sodium salt of phthalimide is hydrolysed with alkalies. Such alkaline hydrolysis results in corresponding primary amine.

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Answer 3

Question

Chapter 19, Problem 19.48SP

(a)

Interpretation Introduction

Interpretation:

The use of amine synthesis for the conversion of allybromide to allylamine is to be shown.

Concept introduction:

The Gabriel synthesis is used for the preparation of primary amines. It is also called Gabriel phthalimide synthesis. In this synthesis N− alkylated potassium or sodium salt of phthalimide is hydrolysed with alkalies. Such alkaline hydrolysis results in corresponding primary amine.

(b)

Interpretation Introduction

Interpretation:

The use of amine synthesis for the conversion of ethylbenzene to p-ethylaniline is to be shown.

Concept introduction:

The Gabriel synthesis is used for the preparation of primary amines. It is also called Gabriel phthalimide synthesis. In this synthesis N− alkylated potassium or sodium salt of phthalimide is hydrolysed with alkalies. Such alkaline hydrolysis results in corresponding primary amine.

(c)

Interpretation Introduction

Interpretation:

The use of amine synthesis for the conversion of 1-bromo-3-phenylheptane to 3-phenylheptan-1-amine is to be shown.

Concept introduction:

The Gabriel synthesis is used for the preparation of primary amines. It is also called Gabriel phthalimide synthesis. In this synthesis N− alkylated potassium or sodium salt of phthalimide is hydrolysed with alkalies. Such alkaline hydrolysis results in corresponding primary amine.

(d)

Interpretation Introduction

Interpretation:

The use of amine synthesis for the conversion of 1-bromo-3-phenylheptane to 4-phenyloctan-1-amine is to be shown.

Concept introduction:

The Gabriel synthesis is used for the preparation of primary amines. It is also called Gabriel phthalimide synthesis. In this synthesis N− alkylated potassium or sodium salt of phthalimide is hydrolysed with alkalies. Such alkaline hydrolysis results in corresponding primary amine.

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Answer 4

Question

Chapter 19, Problem 19.48SP

(a)

Interpretation Introduction

Interpretation:

The use of amine synthesis for the conversion of allybromide to allylamine is to be shown.

Concept introduction:

The Gabriel synthesis is used for the preparation of primary amines. It is also called Gabriel phthalimide synthesis. In this synthesis N− alkylated potassium or sodium salt of phthalimide is hydrolysed with alkalies. Such alkaline hydrolysis results in corresponding primary amine.

(b)

Interpretation Introduction

Interpretation:

The use of amine synthesis for the conversion of ethylbenzene to p-ethylaniline is to be shown.

Concept introduction:

The Gabriel synthesis is used for the preparation of primary amines. It is also called Gabriel phthalimide synthesis. In this synthesis N− alkylated potassium or sodium salt of phthalimide is hydrolysed with alkalies. Such alkaline hydrolysis results in corresponding primary amine.

(c)

Interpretation Introduction

Interpretation:

The use of amine synthesis for the conversion of 1-bromo-3-phenylheptane to 3-phenylheptan-1-amine is to be shown.

Concept introduction:

The Gabriel synthesis is used for the preparation of primary amines. It is also called Gabriel phthalimide synthesis. In this synthesis N− alkylated potassium or sodium salt of phthalimide is hydrolysed with alkalies. Such alkaline hydrolysis results in corresponding primary amine.

(d)

Interpretation Introduction

Interpretation:

The use of amine synthesis for the conversion of 1-bromo-3-phenylheptane to 4-phenyloctan-1-amine is to be shown.

Concept introduction:

The Gabriel synthesis is used for the preparation of primary amines. It is also called Gabriel phthalimide synthesis. In this synthesis N− alkylated potassium or sodium salt of phthalimide is hydrolysed with alkalies. Such alkaline hydrolysis results in corresponding primary amine.

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Answer 5

Chapter 19, Problem 19.48SP

(a)

Interpretation Introduction

Interpretation:

The use of amine synthesis for the conversion of allybromide to allylamine is to be shown.

Concept introduction:

The Gabriel synthesis is used for the preparation of primary amines. It is also called Gabriel phthalimide synthesis. In this synthesis N− alkylated potassium or sodium salt of phthalimide is hydrolysed with alkalies. Such alkaline hydrolysis results in corresponding primary amine.

(b)

Interpretation Introduction

Interpretation:

The use of amine synthesis for the conversion of ethylbenzene to p-ethylaniline is to be shown.

Concept introduction:

The Gabriel synthesis is used for the preparation of primary amines. It is also called Gabriel phthalimide synthesis. In this synthesis N− alkylated potassium or sodium salt of phthalimide is hydrolysed with alkalies. Such alkaline hydrolysis results in corresponding primary amine.

(c)

Interpretation Introduction

Interpretation:

The use of amine synthesis for the conversion of 1-bromo-3-phenylheptane to 3-phenylheptan-1-amine is to be shown.

Concept introduction:

The Gabriel synthesis is used for the preparation of primary amines. It is also called Gabriel phthalimide synthesis. In this synthesis N− alkylated potassium or sodium salt of phthalimide is hydrolysed with alkalies. Such alkaline hydrolysis results in corresponding primary amine.

(d)

Interpretation Introduction

Interpretation:

The use of amine synthesis for the conversion of 1-bromo-3-phenylheptane to 4-phenyloctan-1-amine is to be shown.

Concept introduction:

The Gabriel synthesis is used for the preparation of primary amines. It is also called Gabriel phthalimide synthesis. In this synthesis N− alkylated potassium or sodium salt of phthalimide is hydrolysed with alkalies. Such alkaline hydrolysis results in corresponding primary amine.

Answer 6

Chapter 19, Problem 19.48SP

(a)

Interpretation Introduction

Interpretation:

The use of amine synthesis for the conversion of allybromide to allylamine is to be shown.

Concept introduction:

The Gabriel synthesis is used for the preparation of primary amines. It is also called Gabriel phthalimide synthesis. In this synthesis N− alkylated potassium or sodium salt of phthalimide is hydrolysed with alkalies. Such alkaline hydrolysis results in corresponding primary amine.

Answer 7

Chapter 19, Problem 19.48SP

(a)

Interpretation Introduction

Interpretation:

The use of amine synthesis for the conversion of allybromide to allylamine is to be shown.

Concept introduction:

The Gabriel synthesis is used for the preparation of primary amines. It is also called Gabriel phthalimide synthesis. In this synthesis N− alkylated potassium or sodium salt of phthalimide is hydrolysed with alkalies. Such alkaline hydrolysis results in corresponding primary amine.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The use of amine synthesis for the conversion of ethylbenzene to p-ethylaniline is to be shown.

Concept introduction:

The Gabriel synthesis is used for the preparation of primary amines. It is also called Gabriel phthalimide synthesis. In this synthesis N− alkylated potassium or sodium salt of phthalimide is hydrolysed with alkalies. Such alkaline hydrolysis results in corresponding primary amine.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The use of amine synthesis for the conversion of ethylbenzene to p-ethylaniline is to be shown.

Concept introduction:

The Gabriel synthesis is used for the preparation of primary amines. It is also called Gabriel phthalimide synthesis. In this synthesis N− alkylated potassium or sodium salt of phthalimide is hydrolysed with alkalies. Such alkaline hydrolysis results in corresponding primary amine.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The use of amine synthesis for the conversion of 1-bromo-3-phenylheptane to 3-phenylheptan-1-amine is to be shown.

Concept introduction:

The Gabriel synthesis is used for the preparation of primary amines. It is also called Gabriel phthalimide synthesis. In this synthesis N− alkylated potassium or sodium salt of phthalimide is hydrolysed with alkalies. Such alkaline hydrolysis results in corresponding primary amine.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The use of amine synthesis for the conversion of 1-bromo-3-phenylheptane to 3-phenylheptan-1-amine is to be shown.

Concept introduction:

The Gabriel synthesis is used for the preparation of primary amines. It is also called Gabriel phthalimide synthesis. In this synthesis N− alkylated potassium or sodium salt of phthalimide is hydrolysed with alkalies. Such alkaline hydrolysis results in corresponding primary amine.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The use of amine synthesis for the conversion of 1-bromo-3-phenylheptane to 4-phenyloctan-1-amine is to be shown.

Concept introduction:

The Gabriel synthesis is used for the preparation of primary amines. It is also called Gabriel phthalimide synthesis. In this synthesis N− alkylated potassium or sodium salt of phthalimide is hydrolysed with alkalies. Such alkaline hydrolysis results in corresponding primary amine.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The use of amine synthesis for the conversion of 1-bromo-3-phenylheptane to 4-phenyloctan-1-amine is to be shown.

Concept introduction:

The Gabriel synthesis is used for the preparation of primary amines. It is also called Gabriel phthalimide synthesis. In this synthesis N− alkylated potassium or sodium salt of phthalimide is hydrolysed with alkalies. Such alkaline hydrolysis results in corresponding primary amine.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 19.2A - Prob. 19.1P Ch. 19.2B - Prob. 19.2P Ch. 19.2B - Give correct names for the following amines:Ch. 19.3 - Prob. 19.4P Ch. 19.4 - Prob. 19.5P Ch. 19.6 - Rank each set of compounds in order of increasing...Ch. 19.8A - Prob. 19.7P Ch. 19.8C - Prob. 19.8P Ch. 19.8C - Prob. 19.9P Ch. 19.8D - a. Show how fragmentation occurs to give the base...

Solution Summary: The author explains the Gabriel synthesis, which is used for the preparation of primary amines.

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Chapter 19 Solutions