Solution Manual for Quantitative Chemical Analysis
Solution Manual for Quantitative Chemical Analysis
9th Edition
ISBN: 9781464175633
Author: Daniel Harris
Publisher: Palgrave Macmillan Higher Ed
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Chapter 19, Problem 19.14P
Interpretation Introduction

Interpretation:

The minimization of cell E7 by varying cell A7 has to be estimated.

To estimate the minimization of cell E7 by varying cell A7

Concept Introduction:

Scatchard plot:

The equilibrium constant can be measured by measuring the concentration of the species at equilibrium.

Consider, a species P reacting with ligand X to form PX

P+X

Neglect the activity coefficients, we get,

K=[PX][P][X]

Suppose a series of solutions increments of X are added to a constant volume of P.

Let P0 be total concentration of P,

[P]=P0+[PX]

The expression for equilibrium can be rearranged as below,

[PX][X]=K[P]=K(P0-[PX])

A graph of [PX]/[X] versus [X] along with slope of –K is called Scatchard plot.

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