Modified Mastering Chemistry with Pearson eText -- Standalone Access Card -- for Chemistry: Structure and Properties (2nd Edition)
2nd Edition
ISBN: 9780134565613
Author: Nivaldo J. Tro
Publisher: PEARSON
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Chapter 19, Problem 129E
Interpretation Introduction
To determine: the time required to deposit an even layer of gold on the object.
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Draw the stepwise mechanism for the reactions
Part I.
a)
Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone
b) Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone
(3,3-dimethyl-2-butanone) and 2, 3-dimethyl - 1,3-butadiene. Give reasonable mechanism
the formation of
the products
For
3. The explosive decomposition of 2 mole of TNT (2,4,6-trinitrotoluene) is shown below:
Assume the C(s) is soot-basically atomic carbon (although it isn't actually atomic carbon in real life).
2
CH3
H
NO2
NO2
3N2 (g)+7CO (g) + 5H₂O (g) + 7C (s)
H
a. Use bond dissociation energies to calculate how much AU is for this reaction in kJ/mol.
Chapter 19 Solutions
Modified Mastering Chemistry with Pearson eText -- Standalone Access Card -- for Chemistry: Structure and Properties (2nd Edition)
Ch. 19 - Prob. 1ECh. 19 - Explain the difference between a voltaic (or...Ch. 19 - Prob. 3ECh. 19 - Prob. 4ECh. 19 - Prob. 5ECh. 19 - Prob. 6ECh. 19 - What is the definition of the standard cell...Ch. 19 - Describe the basic features of a cell diagram (or...Ch. 19 - Why do some electrochemical cells employ inert...Ch. 19 - Describe the standard hydrogen electrode (SHE) and...
Ch. 19 - How is the cell potential of an electrochemical...Ch. 19 - Prob. 12ECh. 19 - Prob. 13ECh. 19 - How can Table 19.1be used to predict whether or...Ch. 19 - Explain why Ecell , Grxn , and K are all...Ch. 19 - Does a redox reaction with a small equilibrium...Ch. 19 - How does Ecell depend on the concentrations of the...Ch. 19 - Prob. 18ECh. 19 - What is a concentration electrochemical cell?Ch. 19 - What are the anode and cathode reactions in a...Ch. 19 - What are the anode and cathode reactions in a...Ch. 19 - Prob. 22ECh. 19 - What is a fuel cell? What is the most common type...Ch. 19 - The anode of an electrolytic cell must be...Ch. 19 - What species is oxidized, and what species is...Ch. 19 - If an electrolytic cell contains a mixture of...Ch. 19 - Why does the electrolysis of an aqueous sodium...Ch. 19 - What is overvoltage in an electrochemical cell?...Ch. 19 - How is the amount of current flowing through an...Ch. 19 - Prob. 30ECh. 19 - Prob. 31ECh. 19 - Prob. 32ECh. 19 - Balance each redox reaction occurring in acidic...Ch. 19 - Prob. 34ECh. 19 - Balance each redox reaction occurring in acidic...Ch. 19 - Prob. 36ECh. 19 - Prob. 37ECh. 19 - Balance each redox reaction occurring in basic...Ch. 19 - Prob. 39ECh. 19 - Prob. 40ECh. 19 - Calculate the standard cell potential for each of...Ch. 19 - Prob. 42ECh. 19 - Consider the voltaic cell: Determine the direction...Ch. 19 - Prob. 44ECh. 19 - Use line notation to represent each...Ch. 19 - Use line notation to represent each...Ch. 19 - a sketch of the voltaic cell represented by the...Ch. 19 - Prob. 48ECh. 19 - Determine whether or not each redox reaction...Ch. 19 - Prob. 50ECh. 19 - Which metal could you use to reduce Mn2+ ions but...Ch. 19 - Prob. 52ECh. 19 - Prob. 53ECh. 19 - Prob. 54ECh. 19 - Prob. 55ECh. 19 - Prob. 56ECh. 19 - Calculate Ecell for each balanced redox reaction...Ch. 19 - Prob. 58ECh. 19 - Prob. 59ECh. 19 - Which metal is the best reducing agent? Mn Al Ni...Ch. 19 - Use tabulated electrode potentials to calculate...Ch. 19 - Use tabulated electrode potentials to calculate...Ch. 19 - Prob. 63ECh. 19 - Calculate the equilibrium constant for each of the...Ch. 19 - Calculate the equilibrium constant for the...Ch. 19 - Prob. 66ECh. 19 - Calculate Grxn and Ecell for a redox reaction with...Ch. 19 - Prob. 68ECh. 19 - Prob. 69ECh. 19 - Prob. 70ECh. 19 - Prob. 71ECh. 19 - Prob. 72ECh. 19 - Prob. 73ECh. 19 - Prob. 74ECh. 19 - Prob. 75ECh. 19 - Consider the concentration cell: Label the anode...Ch. 19 - Prob. 77ECh. 19 - Prob. 78ECh. 19 - Prob. 79ECh. 19 - Prob. 80ECh. 19 - Refer to the tabulated values of Gf in Appendix...Ch. 19 - Refer to the tabulated values of Gf in Appendix...Ch. 19 - Prob. 83ECh. 19 - Prob. 84ECh. 19 - Prob. 85ECh. 19 - Prob. 86ECh. 19 - Prob. 87ECh. 19 - Which products are obtained in the electrolysis of...Ch. 19 - Write equations for the half-reactions that occur...Ch. 19 - Which products are obtained in the electrolysis of...Ch. 19 - Prob. 91ECh. 19 - Write equations for the half-reactions that occur...Ch. 19 - Prob. 93ECh. 19 - Prob. 94ECh. 19 - Prob. 95ECh. 19 - Silver can be electroplated at the cathode of an...Ch. 19 - A major source of sodium metal is the electrolysis...Ch. 19 - Prob. 98ECh. 19 - Prob. 99ECh. 19 - Prob. 100ECh. 19 - Consider the molecular view of an AL strip and...Ch. 19 - Consider the molecular view of an electrochemical...Ch. 19 - Prob. 103ECh. 19 - Prob. 104ECh. 19 - The cell potential of this electrochemical cell...Ch. 19 - Prob. 106ECh. 19 - Prob. 107ECh. 19 - Consider the reaction shown here occurring at...Ch. 19 - Prob. 109ECh. 19 - What voltage can theoretically be achieved in a...Ch. 19 - A battery relies on the oxidation of magnesium and...Ch. 19 - A rechargeable battery is constructed based on a...Ch. 19 - If a water electrolysis cell operates at a current...Ch. 19 - Prob. 114ECh. 19 - Prob. 115ECh. 19 - Prob. 116ECh. 19 - Calculate Grxn and K for each reaction. The...Ch. 19 - Calculate Grxn and K for each reaction. The...Ch. 19 - The molar mass of a metal (M) is 50.9 g/mol; it...Ch. 19 - A metal forms the fluoride MF3. Electrolysis of...Ch. 19 - A sample of impure tin of mass 0.535 g is...Ch. 19 - Prob. 122ECh. 19 - Prob. 123ECh. 19 - A 215 mL sample of a 0.500 M NaCl solution with an...Ch. 19 - Prob. 125ECh. 19 - Prob. 126ECh. 19 - Prob. 127ECh. 19 - Prob. 128ECh. 19 - Prob. 129ECh. 19 - Prob. 130ECh. 19 - Prob. 131ECh. 19 - Three electrolytic cells are connected in a...Ch. 19 - Prob. 133ECh. 19 - Prob. 134ECh. 19 - Prob. 135ECh. 19 - Prob. 136ECh. 19 - Prob. 137ECh. 19 - Prob. 138ECh. 19 - Prob. 139ECh. 19 - Prob. 140ECh. 19 - Design a device that uses as electrochemical cell...Ch. 19 - Using a library or the Internet, research a fuel...Ch. 19 - Prob. 143ECh. 19 - Balance the redox reaction equation (occurring in...Ch. 19 - Prob. 2SAQCh. 19 - Prob. 3SAQCh. 19 - Refer to Table 19.1 to determine which statement...Ch. 19 - Prob. 5SAQCh. 19 - The Zn/Zn2+ electrode has a standard electrode...Ch. 19 - Refer to Table 19.1 to calculate G for the...Ch. 19 - A redox reaction has an Ecell=0.56V . What can you...Ch. 19 - Prob. 9SAQCh. 19 - Prob. 10SAQCh. 19 - Prob. 11SAQCh. 19 - Prob. 12SAQCh. 19 - Which reaction occurs at the cathode of an...Ch. 19 - Copper is plated onto the cathode of an...Ch. 19 - Prob. 15SAQ
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- Part I. Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff: Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone and (3,3-dimethyl-2-butanone) 2,3-dimethyl-1,3-butadiene. Give reasonable mechanism the formation of the products Forarrow_forwardShow the mechanism for these reactionsarrow_forwardDraw the stepwise mechanismarrow_forward
- Draw a structural formula of the principal product formed when benzonitrile is treated with each reagent. (a) H₂O (one equivalent), H₂SO₄, heat (b) H₂O (excess), H₂SO₄, heat (c) NaOH, H₂O, heat (d) LiAlH4, then H₂Oarrow_forwardDraw the stepwise mechanism for the reactionsarrow_forwardDraw stepwise mechanismarrow_forward
- Part I. Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff: a) Give the major reason for the exposure of benzophenone al isopropyl alcohol (w/acid) to direct sunlight of pina colone Mechanism For b) Pinacol (2,3-dimethy 1, 1-3-butanediol) on treatment w/ acid gives a mixture (3,3-dimethyl-2-butanone) and 2, 3-dimethyl-1,3-butadiene. Give reasonable the formation of the productsarrow_forwardwhat are the Iupac names for each structurearrow_forwardWhat are the IUPAC Names of all the compounds in the picture?arrow_forward
- 1) a) Give the dominant Intermolecular Force (IMF) in a sample of each of the following compounds. Please show your work. (8) SF2, CH,OH, C₂H₂ b) Based on your answers given above, list the compounds in order of their Boiling Point from low to high. (8)arrow_forward19.78 Write the products of the following sequences of reactions. Refer to your reaction road- maps to see how the combined reactions allow you to "navigate" between the different functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18 roadmaps along with your new Chapter 19 roadmap for these. (a) 1. BHS 2. H₂O₂ 3. H₂CrO4 4. SOCI₂ (b) 1. Cl₂/hv 2. KOLBU 3. H₂O, catalytic H₂SO4 4. H₂CrO4 Reaction Roadmap An alkene 5. EtOH 6.0.5 Equiv. NaOEt/EtOH 7. Mild H₂O An alkane 1.0 2. (CH3)₂S 3. H₂CrO (d) (c) 4. Excess EtOH, catalytic H₂SO OH 4. Mild H₂O* 5.0.5 Equiv. NaOEt/EtOH An alkene 6. Mild H₂O* A carboxylic acid 7. Mild H₂O* 1. SOC₁₂ 2. EtOH 3.0.5 Equiv. NaOEt/E:OH 5.1.0 Equiv. NaOEt 6. NH₂ (e) 1. 0.5 Equiv. NaOEt/EtOH 2. Mild H₂O* Br (f) i H An aldehyde 1. Catalytic NaOE/EtOH 2. H₂O*, heat 3. (CH,CH₂)₂Culi 4. Mild H₂O* 5.1.0 Equiv. LDA Br An ester 4. NaOH, H₂O 5. Mild H₂O* 6. Heat 7. MgBr 8. Mild H₂O* 7. Mild H₂O+arrow_forwardLi+ is a hard acid. With this in mind, which if the following compounds should be most soluble in water? Group of answer choices LiBr LiI LiF LiClarrow_forward
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