Chemistry: An Introduction to General, Organic, and Biological Chemistry (13th Edition)
13th Edition
ISBN: 9780134421353
Author: Karen C. Timberlake
Publisher: PEARSON
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Chapter 18.6, Problem 18.48PP
Interpretation Introduction
To determine:
The oxidation process of FMNH2in the electron transport
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Synthesis of Ibuprofen-Part 2:
1. Some pain relievers including ibuprofen (MotrinⓇ) and naproxen (Aleve®) are "α-arylpropanoic acids." Look up the structure
of naproxen (AleveⓇ), another a-arylpropionic acid. Using the same reactions that we used for making ibuprofen, show how
to make naproxen from the compound below. Show all intermediates and reagents in your synthesis.
Show how you would prepare ibuprofen starting from p-isobutylbenzene rather than p-isobutylacetophenenone. What reaction
steps would need to change/add?
3. What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What
other impurities are present in your product and how do you know?
Acid Catalyzed Aromatization of Carvone:
1. Starting with the ketone, below, draw a mechanism for the reaction to give the phenol as shown.
H2SO4
HO-
H₂O
2. Why do we use CDCl instead of CHCl, for acquiring our NMR spectra?
3. Why does it not matter which enantiomer of carvone is used for this reaction?
What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material?
What other impurities are present in your product and how do you know?
Assign this H NMR
Chapter 18 Solutions
Chemistry: An Introduction to General, Organic, and Biological Chemistry (13th Edition)
Ch. 18.1 - Prob. 18.1PPCh. 18.1 - Prob. 18.2PPCh. 18.1 - Prob. 18.3PPCh. 18.1 - Prob. 18.4PPCh. 18.1 - Prob. 18.5PPCh. 18.1 - Prob. 18.6PPCh. 18.2 - Prob. 18.7PPCh. 18.2 - Prob. 18.8PPCh. 18.2 - Prob. 18.9PPCh. 18.2 - Prob. 18.10PP
Ch. 18.2 - Prob. 18.11PPCh. 18.2 - Prob. 18.12PPCh. 18.3 - Prob. 18.13PPCh. 18.3 - Prob. 18.14PPCh. 18.3 - Prob. 18.15PPCh. 18.3 - Prob. 18.16PPCh. 18.3 - Prob. 18.17PPCh. 18.3 - Prob. 18.18PPCh. 18.4 - Prob. 18.19PPCh. 18.4 - Prob. 18.20PPCh. 18.4 - Prob. 18.21PPCh. 18.4 - Prob. 18.22PPCh. 18.4 - Prob. 18.23PPCh. 18.4 - Prob. 18.24PPCh. 18.4 - Prob. 18.25PPCh. 18.4 - Prob. 18.26PPCh. 18.4 - Prob. 18.27PPCh. 18.4 - Prob. 18.28PPCh. 18.4 - Prob. 18.29PPCh. 18.4 - Prob. 18.30PPCh. 18.4 - Prob. 18.31PPCh. 18.4 - Prob. 18.32PPCh. 18.4 - Prob. 18.33PPCh. 18.4 - Prob. 18.34PPCh. 18.5 - Prob. 18.35PPCh. 18.5 - Prob. 18.36PPCh. 18.5 - Prob. 18.37PPCh. 18.5 - Prob. 18.38PPCh. 18.5 - Prob. 18.39PPCh. 18.5 - Prob. 18.40PPCh. 18.5 - Prob. 18.41PPCh. 18.5 - Prob. 18.42PPCh. 18.6 - Prob. 18.43PPCh. 18.6 - Prob. 18.44PPCh. 18.6 - Prob. 18.45PPCh. 18.6 - Prob. 18.46PPCh. 18.6 - Prob. 18.47PPCh. 18.6 - Prob. 18.48PPCh. 18.6 - Prob. 18.49PPCh. 18.6 - Prob. 18.50PPCh. 18.6 - Prob. 18.51PPCh. 18.6 - Prob. 18.52PPCh. 18.6 - Prob. 18.53PPCh. 18.6 - Prob. 18.54PPCh. 18.6 - Prob. 18.55PPCh. 18.6 - Prob. 18.56PPCh. 18.7 - Prob. 18.57PPCh. 18.7 - Prob. 18.58PPCh. 18.7 - Prob. 18.59PPCh. 18.7 - Prob. 18.60PPCh. 18.7 - Prob. 18.61PPCh. 18.7 - Prob. 18.62PPCh. 18.7 - Prob. 18.63PPCh. 18.7 - Prob. 18.64PPCh. 18.8 - 18.65 Draw the condensed structural formula for...Ch. 18.8 - 18.66 Draw the condensed structural formula for...Ch. 18.8 - 18.67 Why does the body convert NH4+ to urea?
Ch. 18.8 - Prob. 18.68PPCh. 18.8 - Prob. 18.69PPCh. 18.8 - Prob. 18.70PPCh. 18.8 - Draw the condensed structural formulas for the...Ch. 18.8 - Prob. 18.72PPCh. 18 - Prob. 18.73UTCCh. 18 - Prob. 18.74UTCCh. 18 - Prob. 18.75UTCCh. 18 - Prob. 18.76UTCCh. 18 - Prob. 18.77APPCh. 18 - Prob. 18.78APPCh. 18 - Prob. 18.79APPCh. 18 - Prob. 18.80APPCh. 18 - Prob. 18.81APPCh. 18 - Prob. 18.82APPCh. 18 - Prob. 18.83APPCh. 18 - Prob. 18.84APPCh. 18 - Prob. 18.85APPCh. 18 - Prob. 18.86APPCh. 18 - Prob. 18.87APPCh. 18 - Prob. 18.88APPCh. 18 - Prob. 18.89APPCh. 18 - Prob. 18.90APPCh. 18 - Prob. 18.91APPCh. 18 - Prob. 18.92APPCh. 18 - Prob. 18.93CPCh. 18 - Prob. 18.94CPCh. 18 - Prob. 18.95CPCh. 18 - Prob. 18.96CPCh. 18 - Prob. 18.97CPCh. 18 - Prob. 18.98CPCh. 18 - Prob. 33CICh. 18 - CI.34 In response to signals from the nervous...Ch. 18 - Prob. 35CICh. 18 - Prob. 36CICh. 18 - Prob. 37CICh. 18 - Prob. 38CICh. 18 - Prob. 39CICh. 18 - Thalassemia is an inherited genetic mutation that...
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- Please complete these blanks need that asaparrow_forwardNitration of Methyl Benzoate: 1. Predict the major product for the reaction below AND provide a mechanism. Include ALL resonance structures for the intermediate. C(CH3)3 NO₂* ? 2. Assuming the stoichiometry is 1:1 for the reaction above, what volume of concentrated nitric acid would be required to mononitrate 0.50 grams of the compound above? What product(s) might you expect if you nitrated phenol instead of methyl benzoate? Explain your reasoning. What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What other impurities are present in your product and how do you know?arrow_forwardSodium Borohydride Reduction (continued on the next page): 1. Draw the product of each of the reactions below and give the formula mass to the nearest whole number. ? (1) NaBH (2) acid (1) NaBD4 (2) acid ? 2. In mass spectra, alcohols typically break as shown in equation 8 in chapter 11 (refer to your lab manual). The larger group is generally lost and this gives rise to the base peak in the mass spectrum. For the products of each of the reactions in question # 1, draw the ion corresponding to the base peak for that product and give its mass to charge ratio (m/z). 3. Given the reaction below, calculate how many mg of 1-phenyl-1-butanol that can be produced using 31 mg NaBH4 and an excess of butyrophenone. 4. + NaBH4 OH (after workup with dilute HCI) What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What other impurities are present in your product and how do you know?arrow_forward
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