CHEMISTRY
13th Edition
ISBN: 9781292228860
Author: Timberlake
Publisher: PEARSON
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Chapter 18.4, Problem 18.25PP
Interpretation Introduction
To determine:
Three carbon intermediates when fructose-1,6-bisphosphate splits
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Students have asked these similar questions
5.
Use the MS data to answer the questions on the next page.
14.0
1.4
15.0
8.1
100-
MS-IW-5644
26.0
2.8
27.0
6.7
28.0
1.8
29.0
80
4.4
38.0
1.0
39.0
1.5
41.0
1.2
42.0
11.2
43.0
100.0
44.0
4.3
79.0
1.9
80.0
2.6
Relative Intensity
40
81.0
1.9
82.0
2.5
93.0
8.7
20-
95.0
8.2
121.0
2.0
123.0
2.0
136.0
11.8
0
138.0
11.5
20
40
8.
60
a.
Br
- 0
80
100
120
140
160
180
200
220
m/z
Identify the m/z of the base peak and molecular ion.
2
b.
Draw structures for each of the following fragments (include electrons and charges): 43.0, 93.0,
95.0, 136.0, and 138.0 m/z.
C.
Draw a reasonable a-fragmentation mechanism for the fragmentation of the molecular ion to
fragment 43.0 m/z. Be sure to include all electrons and formal charges.
6. Using the values provided in Appendix E of your lab manual, calculate the monoisotopic mass for the pyridinium
ion (CsH6N) and show your work.
None
Stereochemistry: Three possible answers- diastereomers, enantiomers
OH
CH₂OH
I
-c=0
21108 1101
41745 HOR
CH₂OH
IL
Но
CH₂OH
TIL
a. Compounds I and III have this relationship with each other: enantiomers
b. Compounds II and IV have this relationship with each other:
c. Compounds I and II have this relationship with each other:
d. *Draw one structure that is a stereoisomer of II, but neither a
diastereomer nor an enantiomer. (more than one correct answer)
Chapter 18 Solutions
CHEMISTRY
Ch. 18.1 - Prob. 18.1PPCh. 18.1 - Prob. 18.2PPCh. 18.1 - Prob. 18.3PPCh. 18.1 - Prob. 18.4PPCh. 18.1 - Prob. 18.5PPCh. 18.1 - Prob. 18.6PPCh. 18.2 - Prob. 18.7PPCh. 18.2 - Prob. 18.8PPCh. 18.2 - Prob. 18.9PPCh. 18.2 - Prob. 18.10PP
Ch. 18.2 - Prob. 18.11PPCh. 18.2 - Prob. 18.12PPCh. 18.3 - Prob. 18.13PPCh. 18.3 - Prob. 18.14PPCh. 18.3 - Prob. 18.15PPCh. 18.3 - Prob. 18.16PPCh. 18.3 - Prob. 18.17PPCh. 18.3 - Prob. 18.18PPCh. 18.4 - Prob. 18.19PPCh. 18.4 - Prob. 18.20PPCh. 18.4 - Prob. 18.21PPCh. 18.4 - Prob. 18.22PPCh. 18.4 - Prob. 18.23PPCh. 18.4 - Prob. 18.24PPCh. 18.4 - Prob. 18.25PPCh. 18.4 - Prob. 18.26PPCh. 18.4 - Prob. 18.27PPCh. 18.4 - Prob. 18.28PPCh. 18.4 - Prob. 18.29PPCh. 18.4 - Prob. 18.30PPCh. 18.4 - Prob. 18.31PPCh. 18.4 - Prob. 18.32PPCh. 18.4 - Prob. 18.33PPCh. 18.4 - Prob. 18.34PPCh. 18.5 - Prob. 18.35PPCh. 18.5 - Prob. 18.36PPCh. 18.5 - Prob. 18.37PPCh. 18.5 - Prob. 18.38PPCh. 18.5 - Prob. 18.39PPCh. 18.5 - Prob. 18.40PPCh. 18.5 - Prob. 18.41PPCh. 18.5 - Prob. 18.42PPCh. 18.6 - Prob. 18.43PPCh. 18.6 - Prob. 18.44PPCh. 18.6 - Prob. 18.45PPCh. 18.6 - Prob. 18.46PPCh. 18.6 - Prob. 18.47PPCh. 18.6 - Prob. 18.48PPCh. 18.6 - Prob. 18.49PPCh. 18.6 - Prob. 18.50PPCh. 18.6 - Prob. 18.51PPCh. 18.6 - Prob. 18.52PPCh. 18.6 - Prob. 18.53PPCh. 18.6 - Prob. 18.54PPCh. 18.6 - Prob. 18.55PPCh. 18.6 - Prob. 18.56PPCh. 18.7 - Prob. 18.57PPCh. 18.7 - Prob. 18.58PPCh. 18.7 - Prob. 18.59PPCh. 18.7 - Prob. 18.60PPCh. 18.7 - Prob. 18.61PPCh. 18.7 - Prob. 18.62PPCh. 18.7 - Prob. 18.63PPCh. 18.7 - Prob. 18.64PPCh. 18.8 - 18.65 Draw the condensed structural formula for...Ch. 18.8 - 18.66 Draw the condensed structural formula for...Ch. 18.8 - 18.67 Why does the body convert NH4+ to urea?
Ch. 18.8 - Prob. 18.68PPCh. 18.8 - Prob. 18.69PPCh. 18.8 - Prob. 18.70PPCh. 18.8 - Draw the condensed structural formulas for the...Ch. 18.8 - Prob. 18.72PPCh. 18 - Prob. 18.73UTCCh. 18 - Prob. 18.74UTCCh. 18 - Prob. 18.75UTCCh. 18 - Prob. 18.76UTCCh. 18 - Prob. 18.77APPCh. 18 - Prob. 18.78APPCh. 18 - Prob. 18.79APPCh. 18 - Prob. 18.80APPCh. 18 - Prob. 18.81APPCh. 18 - Prob. 18.82APPCh. 18 - Prob. 18.83APPCh. 18 - Prob. 18.84APPCh. 18 - Prob. 18.85APPCh. 18 - Prob. 18.86APPCh. 18 - Prob. 18.87APPCh. 18 - Prob. 18.88APPCh. 18 - Prob. 18.89APPCh. 18 - Prob. 18.90APPCh. 18 - Prob. 18.91APPCh. 18 - Prob. 18.92APPCh. 18 - Prob. 18.93CPCh. 18 - Prob. 18.94CPCh. 18 - Prob. 18.95CPCh. 18 - Prob. 18.96CPCh. 18 - Prob. 18.97CPCh. 18 - Prob. 18.98CPCh. 18 - Prob. 33CICh. 18 - CI.34 In response to signals from the nervous...Ch. 18 - Prob. 35CICh. 18 - Prob. 36CICh. 18 - Prob. 37CICh. 18 - Prob. 38CICh. 18 - Prob. 39CICh. 18 - Thalassemia is an inherited genetic mutation that...
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