Laboratory Experiments for Chemistry: The Central Science (14th Edition)
14th Edition
ISBN: 9780134566207
Author: Theodore E. Brown, H. Eugene LeMay, Bruce E. Bursten, Catherine Murphy, Patrick Woodward, Matthew E. Stoltzfus, John H. Nelson, Kenneth C. Kemp
Publisher: PEARSON
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Chapter 18, Problem 91IE
(a)
Interpretation Introduction
To determine: The process that is greener from the given reactions.
(b)
Interpretation Introduction
To determine: The hybridization and geometry of the carbon atoms in each
(c)
Interpretation Introduction
To determine: The method to promote the formation of isocynate intermediate in each reaction, using Le Chatelier’s principle.
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5. A solution of sucrose is fermented in a vessel until the evolution of CO2 ceases. Then, the
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If the original charge is 500 kg, evaluate;
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h. Conversion efficiency.
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Reactions:
Inversion reaction: C12H22O11 + H2O →2C6H12O6
Fermentation reaction: C6H12O6 →→2C2H5OH + 2CO2
Formation of acetic acid and glycerin: C6H12O6 + C2H5OH + H₂O→ CH3COOH + 2C3H8O3
Show work. don't give Ai generated solution. How many carbons and hydrogens are in the structure?
13. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the
molecule depicted below.
Bond B
2°C. +2°C. cleavage
Bond A
•CH3 + 26.← Cleavage
2°C. +
Bond C
+3°C•
CH3 2C
Cleavage
E
2°C. 26.
weakest bond
Intact molecule
Strongest 3°C 20.
Gund
Largest
argest
a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in
appropriate boxes.
C
Weakest
bond
A
Produces
Most
Bond
Strongest
Bond
Strongest Gund
produces least stable
radicals
Weakest
Stable radical
b. (4pts) Consider the relative stability of all cleavage products that form when bonds A,
B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B,
and C are all carbon radicals.
i. Which ONE cleavage product is the most stable? A condensed or bond line
representation is fine.
13°C. formed in
bound C
cleavage
ii. Which ONE cleavage product is the least stable? A condensed or bond line
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• CH3
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c.…
Chapter 18 Solutions
Laboratory Experiments for Chemistry: The Central Science (14th Edition)
Ch. 18.1 - Prob. 18.1.1PECh. 18.1 - Prob. 18.1.2PECh. 18.1 - Prob. 18.2.1PECh. 18.1 - Practice Exercise 2 The bond energy in N2 is 941...Ch. 18.2 - Prob. 18.3.1PECh. 18.2 - Prob. 18.3.2PECh. 18 - Prob. 1DECh. 18 - Prob. 1ECh. 18 - Prob. 2ECh. 18 - The figure shows the three lowest regions of...
Ch. 18 - Prob. 4ECh. 18 - Where does the energy come from to evaporate the...Ch. 18 - Prob. 6ECh. 18 - Prob. 7ECh. 18 - The first stage of treatment at the reverse...Ch. 18 - Prob. 9ECh. 18 - Prob. 10ECh. 18 - Prob. 11ECh. 18 - How are the boundaries between the regions of the...Ch. 18 - Air pollution in the Mexico City metropolitan area...Ch. 18 - Prob. 14ECh. 18 - Prob. 15ECh. 18 - Prob. 16ECh. 18 - Prob. 17ECh. 18 - Prob. 18ECh. 18 - Distinguish between photodissociation and...Ch. 18 - Prob. 20ECh. 18 - Prob. 21ECh. 18 - Prob. 22ECh. 18 - Do the reactions involved in ozone depletion...Ch. 18 - Prob. 24ECh. 18 - Prob. 25ECh. 18 - Prob. 26ECh. 18 - Prob. 27ECh. 18 - Prob. 28ECh. 18 - Prob. 29ECh. 18 - Prob. 30ECh. 18 - Prob. 31ECh. 18 - Prob. 32ECh. 18 - Alcohol-based fuels for automobiles lead to the...Ch. 18 - Prob. 34ECh. 18 - Prob. 35ECh. 18 - Prob. 36ECh. 18 - Prob. 37ECh. 18 - Prob. 38ECh. 18 - Prob. 39ECh. 18 - Prob. 40ECh. 18 - Prob. 41ECh. 18 - Prob. 42ECh. 18 - Although there are many ions in seawater, the...Ch. 18 - The Ogallala aquifer described in the Close Look...Ch. 18 - Prob. 45ECh. 18 - Prob. 46ECh. 18 - List the common products formed when an organic...Ch. 18 - Prob. 48ECh. 18 - Prob. 49ECh. 18 - Prob. 50ECh. 18 - Prob. 51ECh. 18 - Prob. 52ECh. 18 - Prob. 53ECh. 18 - Prob. 54ECh. 18 - Prob. 55ECh. 18 - Prob. 56ECh. 18 - Prob. 57ECh. 18 - Prob. 58ECh. 18 - Prob. 59ECh. 18 - Prob. 60ECh. 18 - Prob. 61AECh. 18 - Prob. 62AECh. 18 - Prob. 63AECh. 18 - Prob. 64AECh. 18 - Prob. 65AECh. 18 - Prob. 66AECh. 18 - Prob. 67AECh. 18 - Explain, using Le Châtelier’s principle, why the...Ch. 18 - Prob. 69AECh. 18 - Prob. 70AECh. 18 - Prob. 71AECh. 18 - Prob. 72AECh. 18 - Prob. 73AECh. 18 - Prob. 74AECh. 18 - Prob. 75AECh. 18 - Prob. 76AECh. 18 - Prob. 77AECh. 18 - Prob. 78IECh. 18 - Prob. 79IECh. 18 - Prob. 80IECh. 18 - Prob. 81IECh. 18 - Prob. 82IECh. 18 - Prob. 83IECh. 18 - Prob. 84IECh. 18 - 18.85 The main reason that distillation is a...Ch. 18 - Prob. 86IECh. 18 - Prob. 87IECh. 18 - Prob. 88IECh. 18 - Prob. 89IECh. 18 - Prob. 90IECh. 18 - Prob. 91IECh. 18 - Prob. 92IE
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