CHEMISTRY:PRIN.+REACTIONS-OWLV2 ACCESS
8th Edition
ISBN: 9781305079298
Author: Masterton
Publisher: Cengage Learning
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Chapter 18, Problem 73QAP
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1. For each of the reaction "railroads" below, you are either asked to give the structure(s) of the starting
material(s) or product(s), or provide reagents/conditions to accomplish the transformation, as
indicated by the boxes.
a.
NaOMe
H+
.CO,H
HO₂C
MeOH (excess)
MeOH
H3C
Br
يع
CH3
1. LiAlH4
2. H3O+
3. PBг3
H3C
1. Et-Li
2. H3O+
-CO₂Me
-CO₂Me
OH
CH3
CH3
ল
CH3
Predict the intermediate 1 and final product 2 of this organic reaction:
NaOMe
ག1, ད།་, -
+
H
You can draw 1 and 2 in any arrangement you like.
2
work up
Note: if either 1 or 2 consists of a pair of enantiomers, just draw one structure using line bonds instead of 3D (dash and wedge)
bonds at the chiral center.
Explanation
Check
Click and drag to start drawing a structure.
Х
© 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | P
What is the total energy cost associated with the compound below adopting the shown conformation?
CH3
HH
DH
CH3
Chapter 18 Solutions
CHEMISTRY:PRIN.+REACTIONS-OWLV2 ACCESS
Ch. 18 - Which isotope in each of the following pairs...Ch. 18 - Which isotope in each of the following pairs...Ch. 18 - For each pair of elements listed, predict which...Ch. 18 - For each pair of elements listed, predict which...Ch. 18 - Prob. 5QAPCh. 18 - Prob. 6QAPCh. 18 - Prob. 7QAPCh. 18 - Prob. 8QAPCh. 18 - Prob. 9QAPCh. 18 - Prob. 10QAP
Ch. 18 - Prob. 11QAPCh. 18 - Prob. 12QAPCh. 18 - Prob. 13QAPCh. 18 - Prob. 14QAPCh. 18 - Prob. 15QAPCh. 18 - Prob. 16QAPCh. 18 - Prob. 17QAPCh. 18 - Prob. 18QAPCh. 18 - Balance the following equations by filling in the...Ch. 18 - Prob. 20QAPCh. 18 - Prob. 21QAPCh. 18 - Prob. 22QAPCh. 18 - Prob. 23QAPCh. 18 - Prob. 24QAPCh. 18 - Prob. 25QAPCh. 18 - Prob. 26QAPCh. 18 - Prob. 27QAPCh. 18 - Prob. 28QAPCh. 18 - Prob. 29QAPCh. 18 - Prob. 30QAPCh. 18 - Prob. 31QAPCh. 18 - Prob. 32QAPCh. 18 - Prob. 33QAPCh. 18 - Prob. 34QAPCh. 18 - Prob. 35QAPCh. 18 - Prob. 36QAPCh. 18 - Prob. 37QAPCh. 18 - Prob. 38QAPCh. 18 - Prob. 39QAPCh. 18 - Prob. 40QAPCh. 18 - Prob. 41QAPCh. 18 - Prob. 42QAPCh. 18 - Prob. 43QAPCh. 18 - Prob. 44QAPCh. 18 - Prob. 45QAPCh. 18 - Prob. 46QAPCh. 18 - Prob. 47QAPCh. 18 - Prob. 48QAPCh. 18 - Prob. 49QAPCh. 18 - Prob. 50QAPCh. 18 - Prob. 51QAPCh. 18 - Prob. 52QAPCh. 18 - Prob. 53QAPCh. 18 - Prob. 54QAPCh. 18 - Prob. 55QAPCh. 18 - Prob. 56QAPCh. 18 - Prob. 57QAPCh. 18 - Prob. 58QAPCh. 18 - Prob. 59QAPCh. 18 - Prob. 60QAPCh. 18 - Prob. 61QAPCh. 18 - Prob. 62QAPCh. 18 - Prob. 63QAPCh. 18 - Prob. 64QAPCh. 18 - Prob. 65QAPCh. 18 - Prob. 66QAPCh. 18 - Prob. 67QAPCh. 18 - Prob. 68QAPCh. 18 - Prob. 69QAPCh. 18 - Prob. 70QAPCh. 18 - Prob. 71QAPCh. 18 - Prob. 72QAPCh. 18 - Fill in the following table:Ch. 18 - Prob. 74QAPCh. 18 - Prob. 75QAPCh. 18 - Prob. 76QAPCh. 18 - Prob. 77QAPCh. 18 - Prob. 78QAPCh. 18 - Prob. 79QAPCh. 18 - Carbon-14 (C-14) with a half-life of 5730 years...Ch. 18 - Prob. 81QAPCh. 18 - Prob. 82QAP
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- ΗΝ, Draw Final Product C cyclohexanone pH 4-5 Edit Enamine H3O+ CH3CH2Br THF, reflux H Edit Iminium Ionarrow_forwardHow many hydrogen atoms are connected to the indicated carbon atom?arrow_forwardIdentify the compound with the longest carbon - nitrogen bond. O CH3CH2CH=NH O CH3CH2NH2 CH3CH2C=N CH3CH=NCH 3 The length of all the carbon-nitrogen bonds are the samearrow_forward
- Identify any polar covalent bonds in epichlorohydrin with S+ and 8- symbols in the appropriate locations. Choose the correct answer below. Η H's+ 6Η Η Η Η Η Ηδ Η Ο Ο HH +Η Η +Η Η Η -8+ CIarrow_forwardH H:O::::H H H HH H::O:D:D:H HH HH H:O:D:D:H .. HH H:O:D:D:H H H Select the correct Lewis dot structure for the following compound: CH3CH2OHarrow_forwardRank the following compounds in order of decreasing boiling point. ннннн -С-С-Н . н-с- ННННН H ΗΤΗ НННН TTTĪ н-с-с-с-с-о-н НННН НН C' Н н-с-с-с-с-н НН || Ш НННН H-C-C-C-C-N-H ННННН IVarrow_forward
- Rank the following compounds in order of decreasing dipole moment. |>||>||| ||>|||>| |>|||>|| |||>||>| O ||>>||| H F H F H c=c || H c=c F F IIIarrow_forwardchoose the description that best describes the geometry for the following charged species ch3-arrow_forwardWhy isn't the ketone in this compound converted to an acetal or hemiacetal by the alcohol and acid?arrow_forward
- What is the approximate bond angle around the nitrogen atom? HNH H Harrow_forwardOH 1. NaOCH2CH3 Q 2. CH3CH2Br (1 equiv) H3O+ Select to Draw 1. NaOCH2 CH3 2. CH3Br (1 equiv) heat Select to Edit Select to Drawarrow_forwardComplete and balance the following half-reaction in acidic solution. Be sure to include the proper phases for all species within the reaction. S₂O₃²⁻(aq) → S₄O₆²⁻(aq)arrow_forward
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