Atkins' Physical chemistry
Atkins' Physical chemistry
11th Edition
ISBN: 9780198814740
Author: ATKINS, P. W. (peter William), 1940- (author.)
Publisher: Oxford University Press,
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Chapter 18, Problem 18C.2AE
Interpretation Introduction

Interpretation:

Gibbs energy for activation at 30°C has to be evaluated for the reaction A-+ H+P with rate constant empirical expression as kr= Ae(9134K)/T with A= 7.78x1014dm3mol-1s-1.

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Which of the following compounds can be synthesized using one reaction from any alkene, as a major product? If it can be synthesized, propose a route, and you may use any other starting materials, reagents and solvents as needed. If you do not think that it can be synthesized as a major product from an alkene, explain in detail why.
Draw the stepwise mechanism (with arrow pushing)
a) Explain why product 1 is the kinetic product and product 2 is the thermodynamic product. b) Draw the reaction coordinate diagram for the reaction pathway generating each product. c) State the Arrhenius Equation and explain the terms with their physical significance. d) State and explain which reaction pathway has a higher rate constant. What happens to the rate constant if the temperature has increased?

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Atkins' Physical chemistry

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