For the given compounds, major products should be predicted when each of them are treated with Birch condition. Concept introduction: Birch reduction converts aromatic compound having benzoid ring in to a product 1, 4-cyclohexa diene. The product having hydrogen atoms attached on opposite end of the molecule Birch reduction is the reduction of aromatic rings with sodium , potassium or lithium and an alcohol in liquid ammonia Birch reduction is unlike catalytic hydrogenation When the benzene with an electron donating group such as alkyl group is treated with Birch reduction, the carbon atom connected to the alkyl group is not reduced. Electron donating effect destabilizes the radical anion. When an electron withdrawing groups are used, different regiochemical outcome is observed. Electron withdrawing effect stabilizes the intermediate.

Question

Want to see the full answer?

Answer 1

Question

Chapter 17.7, Problem 20PTS

(a)

Interpretation Introduction

Interpretation: For the given compounds, major products should be predicted when each of them are treated with Birch condition.

Concept introduction:

Birch reduction converts aromatic compound having benzoid ring in to a product 1, 4-cyclohexa diene.

The product having hydrogen atoms attached on opposite end of the molecule

Birch reduction is the reduction of aromatic rings with sodium , potassium or lithium and an alcohol in liquid ammonia

Birch reduction is unlike catalytic hydrogenation

When the benzene with an electron donating group such as alkyl group is treated with Birch reduction, the carbon atom connected to the alkyl group is not reduced. Electron donating effect destabilizes the radical anion.

When an electron withdrawing groups are used, different regiochemical outcome is observed. Electron withdrawing effect stabilizes the intermediate.

(b)

Interpretation Introduction

Interpretation: For the given compounds, major products should be predicted when each of them are treated with Birch condition.

Concept introduction:

Birch reduction converts aromatic compound having benzoid ring in to a product 1, 4-cyclohexa diene.

The product having hydrogen atoms attached on opposite end of the molecule

Birch reduction is the reduction of aromatic rings with sodium , potassium or lithium and an alcohol in liquid ammonia

Birch reduction is unlike catalytic hydrogenation

When the benzene with an electron donating group such as alkyl group is treated with Birch reduction, the carbon atom connected to the alkyl group is not reduced. Electron donating effect destabilizes the radical anion.

When an electron withdrawing groups are used, different regiochemical outcome is observed. Electron withdrawing effect stabilizes the intermediate.

(c)

Interpretation Introduction

Interpretation: For the given compounds, major products should be predicted when each of them are treated with Birch condition.

Concept introduction:

Birch reduction converts aromatic compound having benzoid ring in to a product 1, 4-cyclohexa diene.

The product having hydrogen atoms attached on opposite end of the molecule

Birch reduction is the reduction of aromatic rings with sodium , potassium or lithium and an alcohol in liquid ammonia

Birch reduction is unlike catalytic hydrogenation

When the benzene with an electron donating group such as alkyl group is treated with Birch reduction, the carbon atom connected to the alkyl group is not reduced. Electron donating effect destabilizes the radical anion.

When an electron withdrawing groups are used, different regiochemical outcome is observed. Electron withdrawing effect stabilizes the intermediate.

(d)

Interpretation Introduction

Interpretation: For the given compounds, major products should be predicted when each of them are treated with Birch condition.

Concept introduction:

Birch reduction converts aromatic compound having benzoid ring in to a product 1, 4-cyclohexa diene.

The product having hydrogen atoms attached on opposite end of the molecule

Birch reduction is the reduction of aromatic rings with sodium , potassium or lithium and an alcohol in liquid ammonia

Birch reduction is unlike catalytic hydrogenation

When the benzene with an electron donating group such as alkyl group is treated with Birch reduction, the carbon atom connected to the alkyl group is not reduced. Electron donating effect destabilizes the radical anion.

When an electron withdrawing groups are used, different regiochemical outcome is observed. Electron withdrawing effect stabilizes the intermediate.

(e)

Interpretation Introduction

Interpretation: For the given compounds, major products should be predicted when each of them are treated with Birch condition.

Concept introduction:

Birch reduction converts aromatic compound having benzoid ring in to a product 1, 4-cyclohexa diene.

The product having hydrogen atoms attached on opposite end of the molecule

Birch reduction is the reduction of aromatic rings with sodium , potassium or lithium and an alcohol in liquid ammonia

Birch reduction is unlike catalytic hydrogenation

When the benzene with an electron donating group such as alkyl group is treated with Birch reduction, the carbon atom connected to the alkyl group is not reduced. Electron donating effect destabilizes the radical anion.

When an electron withdrawing groups are used, different regiochemical outcome is observed. Electron withdrawing effect stabilizes the intermediate.

(f)

Interpretation Introduction

Interpretation: For the given compounds, major products should be predicted when each of them are treated with Birch condition.

Concept introduction:

Birch reduction converts aromatic compound having benzoid ring in to a product 1, 4-cyclohexa diene.

The product having hydrogen atoms attached on opposite end of the molecule

Birch reduction is the reduction of aromatic rings with sodium , potassium or lithium and an alcohol in liquid ammonia

Birch reduction is unlike catalytic hydrogenation

When the benzene with an electron donating group such as alkyl group is treated with Birch reduction, the carbon atom connected to the alkyl group is not reduced. Electron donating effect destabilizes the radical anion.

When an electron withdrawing groups are used, different regiochemical outcome is observed. Electron withdrawing effect stabilizes the intermediate.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

Identify the starting material in the following reaction. Click the "draw structure" button to launch the drawing utility. draw structure ... [1] 0 3 C10H18 [2] CH3SCH3 H

In an equilibrium mixture of the formation of ammonia from nitrogen and hydrogen, it is found that PNH3 = 0.147 atm, PN2 = 1.41 atm and Pн2 = 6.00 atm. Evaluate Kp and Kc at 500 °C. 2 NH3 (g) N2 (g) + 3 H₂ (g) K₂ = (PN2)(PH2)³ = (1.41) (6.00)³ = 1.41 x 104

What alkene or alkyne yields the following products after oxidative cleavage with ozone? Click the "draw structure" button to launch the drawing utility. and two equivalents of CH2=O draw structure ...

Answer 2

Question

Chapter 17.7, Problem 20PTS

(a)

Interpretation Introduction

Interpretation: For the given compounds, major products should be predicted when each of them are treated with Birch condition.

Concept introduction:

Birch reduction converts aromatic compound having benzoid ring in to a product 1, 4-cyclohexa diene.

The product having hydrogen atoms attached on opposite end of the molecule

Birch reduction is the reduction of aromatic rings with sodium , potassium or lithium and an alcohol in liquid ammonia

Birch reduction is unlike catalytic hydrogenation

When the benzene with an electron donating group such as alkyl group is treated with Birch reduction, the carbon atom connected to the alkyl group is not reduced. Electron donating effect destabilizes the radical anion.

When an electron withdrawing groups are used, different regiochemical outcome is observed. Electron withdrawing effect stabilizes the intermediate.

(b)

Interpretation Introduction

Interpretation: For the given compounds, major products should be predicted when each of them are treated with Birch condition.

Concept introduction:

Birch reduction converts aromatic compound having benzoid ring in to a product 1, 4-cyclohexa diene.

The product having hydrogen atoms attached on opposite end of the molecule

Birch reduction is the reduction of aromatic rings with sodium , potassium or lithium and an alcohol in liquid ammonia

Birch reduction is unlike catalytic hydrogenation

When the benzene with an electron donating group such as alkyl group is treated with Birch reduction, the carbon atom connected to the alkyl group is not reduced. Electron donating effect destabilizes the radical anion.

When an electron withdrawing groups are used, different regiochemical outcome is observed. Electron withdrawing effect stabilizes the intermediate.

(c)

Interpretation Introduction

Interpretation: For the given compounds, major products should be predicted when each of them are treated with Birch condition.

Concept introduction:

Birch reduction converts aromatic compound having benzoid ring in to a product 1, 4-cyclohexa diene.

The product having hydrogen atoms attached on opposite end of the molecule

Birch reduction is the reduction of aromatic rings with sodium , potassium or lithium and an alcohol in liquid ammonia

Birch reduction is unlike catalytic hydrogenation

When the benzene with an electron donating group such as alkyl group is treated with Birch reduction, the carbon atom connected to the alkyl group is not reduced. Electron donating effect destabilizes the radical anion.

When an electron withdrawing groups are used, different regiochemical outcome is observed. Electron withdrawing effect stabilizes the intermediate.

(d)

Interpretation Introduction

Interpretation: For the given compounds, major products should be predicted when each of them are treated with Birch condition.

Concept introduction:

Birch reduction converts aromatic compound having benzoid ring in to a product 1, 4-cyclohexa diene.

The product having hydrogen atoms attached on opposite end of the molecule

Birch reduction is the reduction of aromatic rings with sodium , potassium or lithium and an alcohol in liquid ammonia

Birch reduction is unlike catalytic hydrogenation

When the benzene with an electron donating group such as alkyl group is treated with Birch reduction, the carbon atom connected to the alkyl group is not reduced. Electron donating effect destabilizes the radical anion.

When an electron withdrawing groups are used, different regiochemical outcome is observed. Electron withdrawing effect stabilizes the intermediate.

(e)

Interpretation Introduction

Interpretation: For the given compounds, major products should be predicted when each of them are treated with Birch condition.

Concept introduction:

Birch reduction converts aromatic compound having benzoid ring in to a product 1, 4-cyclohexa diene.

The product having hydrogen atoms attached on opposite end of the molecule

Birch reduction is the reduction of aromatic rings with sodium , potassium or lithium and an alcohol in liquid ammonia

Birch reduction is unlike catalytic hydrogenation

When the benzene with an electron donating group such as alkyl group is treated with Birch reduction, the carbon atom connected to the alkyl group is not reduced. Electron donating effect destabilizes the radical anion.

When an electron withdrawing groups are used, different regiochemical outcome is observed. Electron withdrawing effect stabilizes the intermediate.

(f)

Interpretation Introduction

Interpretation: For the given compounds, major products should be predicted when each of them are treated with Birch condition.

Concept introduction:

Birch reduction converts aromatic compound having benzoid ring in to a product 1, 4-cyclohexa diene.

The product having hydrogen atoms attached on opposite end of the molecule

Birch reduction is the reduction of aromatic rings with sodium , potassium or lithium and an alcohol in liquid ammonia

Birch reduction is unlike catalytic hydrogenation

When the benzene with an electron donating group such as alkyl group is treated with Birch reduction, the carbon atom connected to the alkyl group is not reduced. Electron donating effect destabilizes the radical anion.

When an electron withdrawing groups are used, different regiochemical outcome is observed. Electron withdrawing effect stabilizes the intermediate.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Chapter 17.7, Problem 20PTS

(a)

Interpretation Introduction

Interpretation: For the given compounds, major products should be predicted when each of them are treated with Birch condition.

Concept introduction:

Birch reduction converts aromatic compound having benzoid ring in to a product 1, 4-cyclohexa diene.

The product having hydrogen atoms attached on opposite end of the molecule

Birch reduction is the reduction of aromatic rings with sodium , potassium or lithium and an alcohol in liquid ammonia

Birch reduction is unlike catalytic hydrogenation

When the benzene with an electron donating group such as alkyl group is treated with Birch reduction, the carbon atom connected to the alkyl group is not reduced. Electron donating effect destabilizes the radical anion.

When an electron withdrawing groups are used, different regiochemical outcome is observed. Electron withdrawing effect stabilizes the intermediate.

(b)

Interpretation Introduction

Interpretation: For the given compounds, major products should be predicted when each of them are treated with Birch condition.

Concept introduction:

Birch reduction converts aromatic compound having benzoid ring in to a product 1, 4-cyclohexa diene.

The product having hydrogen atoms attached on opposite end of the molecule

Birch reduction is the reduction of aromatic rings with sodium , potassium or lithium and an alcohol in liquid ammonia

Birch reduction is unlike catalytic hydrogenation

When the benzene with an electron donating group such as alkyl group is treated with Birch reduction, the carbon atom connected to the alkyl group is not reduced. Electron donating effect destabilizes the radical anion.

When an electron withdrawing groups are used, different regiochemical outcome is observed. Electron withdrawing effect stabilizes the intermediate.

(c)

Interpretation Introduction

Interpretation: For the given compounds, major products should be predicted when each of them are treated with Birch condition.

Concept introduction:

Birch reduction converts aromatic compound having benzoid ring in to a product 1, 4-cyclohexa diene.

The product having hydrogen atoms attached on opposite end of the molecule

Birch reduction is the reduction of aromatic rings with sodium , potassium or lithium and an alcohol in liquid ammonia

Birch reduction is unlike catalytic hydrogenation

When the benzene with an electron donating group such as alkyl group is treated with Birch reduction, the carbon atom connected to the alkyl group is not reduced. Electron donating effect destabilizes the radical anion.

When an electron withdrawing groups are used, different regiochemical outcome is observed. Electron withdrawing effect stabilizes the intermediate.

(d)

Interpretation Introduction

Interpretation: For the given compounds, major products should be predicted when each of them are treated with Birch condition.

Concept introduction:

Birch reduction converts aromatic compound having benzoid ring in to a product 1, 4-cyclohexa diene.

The product having hydrogen atoms attached on opposite end of the molecule

Birch reduction is the reduction of aromatic rings with sodium , potassium or lithium and an alcohol in liquid ammonia

Birch reduction is unlike catalytic hydrogenation

When the benzene with an electron donating group such as alkyl group is treated with Birch reduction, the carbon atom connected to the alkyl group is not reduced. Electron donating effect destabilizes the radical anion.

When an electron withdrawing groups are used, different regiochemical outcome is observed. Electron withdrawing effect stabilizes the intermediate.

(e)

Interpretation Introduction

Interpretation: For the given compounds, major products should be predicted when each of them are treated with Birch condition.

Concept introduction:

Birch reduction converts aromatic compound having benzoid ring in to a product 1, 4-cyclohexa diene.

The product having hydrogen atoms attached on opposite end of the molecule

Birch reduction is the reduction of aromatic rings with sodium , potassium or lithium and an alcohol in liquid ammonia

Birch reduction is unlike catalytic hydrogenation

When the benzene with an electron donating group such as alkyl group is treated with Birch reduction, the carbon atom connected to the alkyl group is not reduced. Electron donating effect destabilizes the radical anion.

When an electron withdrawing groups are used, different regiochemical outcome is observed. Electron withdrawing effect stabilizes the intermediate.

(f)

Interpretation Introduction

Interpretation: For the given compounds, major products should be predicted when each of them are treated with Birch condition.

Concept introduction:

Birch reduction converts aromatic compound having benzoid ring in to a product 1, 4-cyclohexa diene.

The product having hydrogen atoms attached on opposite end of the molecule

Birch reduction is the reduction of aromatic rings with sodium , potassium or lithium and an alcohol in liquid ammonia

Birch reduction is unlike catalytic hydrogenation

When the benzene with an electron donating group such as alkyl group is treated with Birch reduction, the carbon atom connected to the alkyl group is not reduced. Electron donating effect destabilizes the radical anion.

When an electron withdrawing groups are used, different regiochemical outcome is observed. Electron withdrawing effect stabilizes the intermediate.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Chapter 17.7, Problem 20PTS

(a)

Interpretation Introduction

Interpretation: For the given compounds, major products should be predicted when each of them are treated with Birch condition.

Concept introduction:

Birch reduction converts aromatic compound having benzoid ring in to a product 1, 4-cyclohexa diene.

The product having hydrogen atoms attached on opposite end of the molecule

Birch reduction is the reduction of aromatic rings with sodium , potassium or lithium and an alcohol in liquid ammonia

Birch reduction is unlike catalytic hydrogenation

When the benzene with an electron donating group such as alkyl group is treated with Birch reduction, the carbon atom connected to the alkyl group is not reduced. Electron donating effect destabilizes the radical anion.

When an electron withdrawing groups are used, different regiochemical outcome is observed. Electron withdrawing effect stabilizes the intermediate.

(b)

Interpretation Introduction

Interpretation: For the given compounds, major products should be predicted when each of them are treated with Birch condition.

Concept introduction:

Birch reduction converts aromatic compound having benzoid ring in to a product 1, 4-cyclohexa diene.

The product having hydrogen atoms attached on opposite end of the molecule

Birch reduction is the reduction of aromatic rings with sodium , potassium or lithium and an alcohol in liquid ammonia

Birch reduction is unlike catalytic hydrogenation

When the benzene with an electron donating group such as alkyl group is treated with Birch reduction, the carbon atom connected to the alkyl group is not reduced. Electron donating effect destabilizes the radical anion.

When an electron withdrawing groups are used, different regiochemical outcome is observed. Electron withdrawing effect stabilizes the intermediate.

(c)

Interpretation Introduction

Interpretation: For the given compounds, major products should be predicted when each of them are treated with Birch condition.

Concept introduction:

Birch reduction converts aromatic compound having benzoid ring in to a product 1, 4-cyclohexa diene.

The product having hydrogen atoms attached on opposite end of the molecule

Birch reduction is the reduction of aromatic rings with sodium , potassium or lithium and an alcohol in liquid ammonia

Birch reduction is unlike catalytic hydrogenation

When the benzene with an electron donating group such as alkyl group is treated with Birch reduction, the carbon atom connected to the alkyl group is not reduced. Electron donating effect destabilizes the radical anion.

When an electron withdrawing groups are used, different regiochemical outcome is observed. Electron withdrawing effect stabilizes the intermediate.

(d)

Interpretation Introduction

Interpretation: For the given compounds, major products should be predicted when each of them are treated with Birch condition.

Concept introduction:

Birch reduction converts aromatic compound having benzoid ring in to a product 1, 4-cyclohexa diene.

The product having hydrogen atoms attached on opposite end of the molecule

Birch reduction is the reduction of aromatic rings with sodium , potassium or lithium and an alcohol in liquid ammonia

Birch reduction is unlike catalytic hydrogenation

When the benzene with an electron donating group such as alkyl group is treated with Birch reduction, the carbon atom connected to the alkyl group is not reduced. Electron donating effect destabilizes the radical anion.

When an electron withdrawing groups are used, different regiochemical outcome is observed. Electron withdrawing effect stabilizes the intermediate.

(e)

Interpretation Introduction

Interpretation: For the given compounds, major products should be predicted when each of them are treated with Birch condition.

Concept introduction:

Birch reduction converts aromatic compound having benzoid ring in to a product 1, 4-cyclohexa diene.

The product having hydrogen atoms attached on opposite end of the molecule

Birch reduction is the reduction of aromatic rings with sodium , potassium or lithium and an alcohol in liquid ammonia

Birch reduction is unlike catalytic hydrogenation

When the benzene with an electron donating group such as alkyl group is treated with Birch reduction, the carbon atom connected to the alkyl group is not reduced. Electron donating effect destabilizes the radical anion.

When an electron withdrawing groups are used, different regiochemical outcome is observed. Electron withdrawing effect stabilizes the intermediate.

(f)

Interpretation Introduction

Interpretation: For the given compounds, major products should be predicted when each of them are treated with Birch condition.

Concept introduction:

Birch reduction converts aromatic compound having benzoid ring in to a product 1, 4-cyclohexa diene.

The product having hydrogen atoms attached on opposite end of the molecule

Birch reduction is the reduction of aromatic rings with sodium , potassium or lithium and an alcohol in liquid ammonia

Birch reduction is unlike catalytic hydrogenation

When the benzene with an electron donating group such as alkyl group is treated with Birch reduction, the carbon atom connected to the alkyl group is not reduced. Electron donating effect destabilizes the radical anion.

When an electron withdrawing groups are used, different regiochemical outcome is observed. Electron withdrawing effect stabilizes the intermediate.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 5

Chapter 17.7, Problem 20PTS

(a)

Interpretation Introduction

Interpretation: For the given compounds, major products should be predicted when each of them are treated with Birch condition.

Concept introduction:

Birch reduction converts aromatic compound having benzoid ring in to a product 1, 4-cyclohexa diene.

The product having hydrogen atoms attached on opposite end of the molecule

Birch reduction is the reduction of aromatic rings with sodium , potassium or lithium and an alcohol in liquid ammonia

Birch reduction is unlike catalytic hydrogenation

When the benzene with an electron donating group such as alkyl group is treated with Birch reduction, the carbon atom connected to the alkyl group is not reduced. Electron donating effect destabilizes the radical anion.

When an electron withdrawing groups are used, different regiochemical outcome is observed. Electron withdrawing effect stabilizes the intermediate.

(b)

Interpretation Introduction

Interpretation: For the given compounds, major products should be predicted when each of them are treated with Birch condition.

Concept introduction:

Birch reduction converts aromatic compound having benzoid ring in to a product 1, 4-cyclohexa diene.

The product having hydrogen atoms attached on opposite end of the molecule

Birch reduction is the reduction of aromatic rings with sodium , potassium or lithium and an alcohol in liquid ammonia

Birch reduction is unlike catalytic hydrogenation

When the benzene with an electron donating group such as alkyl group is treated with Birch reduction, the carbon atom connected to the alkyl group is not reduced. Electron donating effect destabilizes the radical anion.

When an electron withdrawing groups are used, different regiochemical outcome is observed. Electron withdrawing effect stabilizes the intermediate.

(c)

Interpretation Introduction

Interpretation: For the given compounds, major products should be predicted when each of them are treated with Birch condition.

Concept introduction:

Birch reduction converts aromatic compound having benzoid ring in to a product 1, 4-cyclohexa diene.

The product having hydrogen atoms attached on opposite end of the molecule

Birch reduction is the reduction of aromatic rings with sodium , potassium or lithium and an alcohol in liquid ammonia

Birch reduction is unlike catalytic hydrogenation

When the benzene with an electron donating group such as alkyl group is treated with Birch reduction, the carbon atom connected to the alkyl group is not reduced. Electron donating effect destabilizes the radical anion.

When an electron withdrawing groups are used, different regiochemical outcome is observed. Electron withdrawing effect stabilizes the intermediate.

(d)

Interpretation Introduction

Interpretation: For the given compounds, major products should be predicted when each of them are treated with Birch condition.

Concept introduction:

Birch reduction converts aromatic compound having benzoid ring in to a product 1, 4-cyclohexa diene.

The product having hydrogen atoms attached on opposite end of the molecule

Birch reduction is the reduction of aromatic rings with sodium , potassium or lithium and an alcohol in liquid ammonia

Birch reduction is unlike catalytic hydrogenation

When the benzene with an electron donating group such as alkyl group is treated with Birch reduction, the carbon atom connected to the alkyl group is not reduced. Electron donating effect destabilizes the radical anion.

When an electron withdrawing groups are used, different regiochemical outcome is observed. Electron withdrawing effect stabilizes the intermediate.

(e)

Interpretation Introduction

Interpretation: For the given compounds, major products should be predicted when each of them are treated with Birch condition.

Concept introduction:

Birch reduction converts aromatic compound having benzoid ring in to a product 1, 4-cyclohexa diene.

The product having hydrogen atoms attached on opposite end of the molecule

Birch reduction is the reduction of aromatic rings with sodium , potassium or lithium and an alcohol in liquid ammonia

Birch reduction is unlike catalytic hydrogenation

When the benzene with an electron donating group such as alkyl group is treated with Birch reduction, the carbon atom connected to the alkyl group is not reduced. Electron donating effect destabilizes the radical anion.

When an electron withdrawing groups are used, different regiochemical outcome is observed. Electron withdrawing effect stabilizes the intermediate.

(f)

Interpretation Introduction

Interpretation: For the given compounds, major products should be predicted when each of them are treated with Birch condition.

Concept introduction:

Birch reduction converts aromatic compound having benzoid ring in to a product 1, 4-cyclohexa diene.

The product having hydrogen atoms attached on opposite end of the molecule

Birch reduction is the reduction of aromatic rings with sodium , potassium or lithium and an alcohol in liquid ammonia

Birch reduction is unlike catalytic hydrogenation

When the benzene with an electron donating group such as alkyl group is treated with Birch reduction, the carbon atom connected to the alkyl group is not reduced. Electron donating effect destabilizes the radical anion.

When an electron withdrawing groups are used, different regiochemical outcome is observed. Electron withdrawing effect stabilizes the intermediate.

Answer 6

Chapter 17.7, Problem 20PTS

(a)

Interpretation Introduction

Interpretation: For the given compounds, major products should be predicted when each of them are treated with Birch condition.

Concept introduction:

Birch reduction converts aromatic compound having benzoid ring in to a product 1, 4-cyclohexa diene.

The product having hydrogen atoms attached on opposite end of the molecule

Birch reduction is the reduction of aromatic rings with sodium , potassium or lithium and an alcohol in liquid ammonia

Birch reduction is unlike catalytic hydrogenation

When the benzene with an electron donating group such as alkyl group is treated with Birch reduction, the carbon atom connected to the alkyl group is not reduced. Electron donating effect destabilizes the radical anion.

When an electron withdrawing groups are used, different regiochemical outcome is observed. Electron withdrawing effect stabilizes the intermediate.

Answer 7

Chapter 17.7, Problem 20PTS

(a)

Interpretation Introduction

Interpretation: For the given compounds, major products should be predicted when each of them are treated with Birch condition.

Concept introduction:

Birch reduction converts aromatic compound having benzoid ring in to a product 1, 4-cyclohexa diene.

The product having hydrogen atoms attached on opposite end of the molecule

Birch reduction is the reduction of aromatic rings with sodium , potassium or lithium and an alcohol in liquid ammonia

Birch reduction is unlike catalytic hydrogenation

When the benzene with an electron donating group such as alkyl group is treated with Birch reduction, the carbon atom connected to the alkyl group is not reduced. Electron donating effect destabilizes the radical anion.

When an electron withdrawing groups are used, different regiochemical outcome is observed. Electron withdrawing effect stabilizes the intermediate.

Answer 8

(b)

Interpretation Introduction

Interpretation: For the given compounds, major products should be predicted when each of them are treated with Birch condition.

Concept introduction:

Birch reduction converts aromatic compound having benzoid ring in to a product 1, 4-cyclohexa diene.

The product having hydrogen atoms attached on opposite end of the molecule

Birch reduction is the reduction of aromatic rings with sodium , potassium or lithium and an alcohol in liquid ammonia

Birch reduction is unlike catalytic hydrogenation

When the benzene with an electron donating group such as alkyl group is treated with Birch reduction, the carbon atom connected to the alkyl group is not reduced. Electron donating effect destabilizes the radical anion.

When an electron withdrawing groups are used, different regiochemical outcome is observed. Electron withdrawing effect stabilizes the intermediate.

Answer 9

(b)

Interpretation Introduction

Interpretation: For the given compounds, major products should be predicted when each of them are treated with Birch condition.

Concept introduction:

Birch reduction converts aromatic compound having benzoid ring in to a product 1, 4-cyclohexa diene.

The product having hydrogen atoms attached on opposite end of the molecule

Birch reduction is the reduction of aromatic rings with sodium , potassium or lithium and an alcohol in liquid ammonia

Birch reduction is unlike catalytic hydrogenation

When the benzene with an electron donating group such as alkyl group is treated with Birch reduction, the carbon atom connected to the alkyl group is not reduced. Electron donating effect destabilizes the radical anion.

When an electron withdrawing groups are used, different regiochemical outcome is observed. Electron withdrawing effect stabilizes the intermediate.

Answer 10

(c)

Interpretation Introduction

Interpretation: For the given compounds, major products should be predicted when each of them are treated with Birch condition.

Concept introduction:

Birch reduction converts aromatic compound having benzoid ring in to a product 1, 4-cyclohexa diene.

The product having hydrogen atoms attached on opposite end of the molecule

Birch reduction is the reduction of aromatic rings with sodium , potassium or lithium and an alcohol in liquid ammonia

Birch reduction is unlike catalytic hydrogenation

When the benzene with an electron donating group such as alkyl group is treated with Birch reduction, the carbon atom connected to the alkyl group is not reduced. Electron donating effect destabilizes the radical anion.

When an electron withdrawing groups are used, different regiochemical outcome is observed. Electron withdrawing effect stabilizes the intermediate.

Answer 11

(c)

Interpretation Introduction

Interpretation: For the given compounds, major products should be predicted when each of them are treated with Birch condition.

Concept introduction:

Birch reduction converts aromatic compound having benzoid ring in to a product 1, 4-cyclohexa diene.

The product having hydrogen atoms attached on opposite end of the molecule

Birch reduction is the reduction of aromatic rings with sodium , potassium or lithium and an alcohol in liquid ammonia

Birch reduction is unlike catalytic hydrogenation

When the benzene with an electron donating group such as alkyl group is treated with Birch reduction, the carbon atom connected to the alkyl group is not reduced. Electron donating effect destabilizes the radical anion.

When an electron withdrawing groups are used, different regiochemical outcome is observed. Electron withdrawing effect stabilizes the intermediate.

Answer 12

(d)

Interpretation Introduction

Interpretation: For the given compounds, major products should be predicted when each of them are treated with Birch condition.

Concept introduction:

Birch reduction converts aromatic compound having benzoid ring in to a product 1, 4-cyclohexa diene.

The product having hydrogen atoms attached on opposite end of the molecule

Birch reduction is the reduction of aromatic rings with sodium , potassium or lithium and an alcohol in liquid ammonia

Birch reduction is unlike catalytic hydrogenation

When the benzene with an electron donating group such as alkyl group is treated with Birch reduction, the carbon atom connected to the alkyl group is not reduced. Electron donating effect destabilizes the radical anion.

When an electron withdrawing groups are used, different regiochemical outcome is observed. Electron withdrawing effect stabilizes the intermediate.

Answer 13

(d)

Interpretation Introduction

Interpretation: For the given compounds, major products should be predicted when each of them are treated with Birch condition.

Concept introduction:

Birch reduction converts aromatic compound having benzoid ring in to a product 1, 4-cyclohexa diene.

The product having hydrogen atoms attached on opposite end of the molecule

Birch reduction is the reduction of aromatic rings with sodium , potassium or lithium and an alcohol in liquid ammonia

Birch reduction is unlike catalytic hydrogenation

When the benzene with an electron donating group such as alkyl group is treated with Birch reduction, the carbon atom connected to the alkyl group is not reduced. Electron donating effect destabilizes the radical anion.

When an electron withdrawing groups are used, different regiochemical outcome is observed. Electron withdrawing effect stabilizes the intermediate.

Answer 14

(e)

Interpretation Introduction

Interpretation: For the given compounds, major products should be predicted when each of them are treated with Birch condition.

Concept introduction:

Birch reduction converts aromatic compound having benzoid ring in to a product 1, 4-cyclohexa diene.

The product having hydrogen atoms attached on opposite end of the molecule

Birch reduction is the reduction of aromatic rings with sodium , potassium or lithium and an alcohol in liquid ammonia

Birch reduction is unlike catalytic hydrogenation

When the benzene with an electron donating group such as alkyl group is treated with Birch reduction, the carbon atom connected to the alkyl group is not reduced. Electron donating effect destabilizes the radical anion.

When an electron withdrawing groups are used, different regiochemical outcome is observed. Electron withdrawing effect stabilizes the intermediate.

Answer 15

(e)

Interpretation Introduction

Interpretation: For the given compounds, major products should be predicted when each of them are treated with Birch condition.

Concept introduction:

Birch reduction converts aromatic compound having benzoid ring in to a product 1, 4-cyclohexa diene.

The product having hydrogen atoms attached on opposite end of the molecule

Birch reduction is the reduction of aromatic rings with sodium , potassium or lithium and an alcohol in liquid ammonia

Birch reduction is unlike catalytic hydrogenation

When the benzene with an electron donating group such as alkyl group is treated with Birch reduction, the carbon atom connected to the alkyl group is not reduced. Electron donating effect destabilizes the radical anion.

When an electron withdrawing groups are used, different regiochemical outcome is observed. Electron withdrawing effect stabilizes the intermediate.

Answer 16

(f)

Interpretation Introduction

Interpretation: For the given compounds, major products should be predicted when each of them are treated with Birch condition.

Concept introduction:

Birch reduction converts aromatic compound having benzoid ring in to a product 1, 4-cyclohexa diene.

The product having hydrogen atoms attached on opposite end of the molecule

Birch reduction is the reduction of aromatic rings with sodium , potassium or lithium and an alcohol in liquid ammonia

Birch reduction is unlike catalytic hydrogenation

When the benzene with an electron donating group such as alkyl group is treated with Birch reduction, the carbon atom connected to the alkyl group is not reduced. Electron donating effect destabilizes the radical anion.

When an electron withdrawing groups are used, different regiochemical outcome is observed. Electron withdrawing effect stabilizes the intermediate.

Answer 17

(f)

Interpretation Introduction

Interpretation: For the given compounds, major products should be predicted when each of them are treated with Birch condition.

Concept introduction:

Birch reduction converts aromatic compound having benzoid ring in to a product 1, 4-cyclohexa diene.

The product having hydrogen atoms attached on opposite end of the molecule

Birch reduction is the reduction of aromatic rings with sodium , potassium or lithium and an alcohol in liquid ammonia

Birch reduction is unlike catalytic hydrogenation

When the benzene with an electron donating group such as alkyl group is treated with Birch reduction, the carbon atom connected to the alkyl group is not reduced. Electron donating effect destabilizes the radical anion.

When an electron withdrawing groups are used, different regiochemical outcome is observed. Electron withdrawing effect stabilizes the intermediate.

Answer 18

Expert Solution & Answer

Answer 19

Expert Solution & Answer

Answer 20

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 21

Ch. 17.2 - Prob. 1LTS Ch. 17.2 - Prob. 1PTS Ch. 17.2 - Prob. 2PTS Ch. 17.2 - Prob. 3PTS Ch. 17.2 - Prob. 4PTS Ch. 17.2 - Prob. 5ATS Ch. 17.4 - Prob. 6CC Ch. 17.4 - Prob. 7CC Ch. 17.4 - Prob. 8CC Ch. 17.4 - Prob. 9CC

Want to see the full answer?

Chapter 17 Solutions