Chemistry: Atoms First
3rd Edition
ISBN: 9781259638138
Author: Julia Burdge, Jason Overby Professor
Publisher: McGraw-Hill Education
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Chapter 17.2, Problem 17.2WE
Starting with 1.00 L of a buffer that is 1.00 M in acetic acid and 1.00 M in sodium acetate, calculate the pH after the addition of 0.100 mole of NaOH. (Assume that the addition does not change the volume of the solution.)
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Also calculate the amount of starting materials chlorobenzaldehyde and p-chloroacetophenone
required to prepare 400 mg of the given chalcone product 1, 3-bis(4-chlorophenyl)prop-2-en-1-one
molar mass ok 1,3-bis(4-Chlorophenyl) prop-2-en-1-one = 277.1591m01
number of moles= 0.400/277.15 = 0.00144 moles
2 x 0.00 144=0.00288 moves
arams of acetophenone = 0.00144 X 120.16 = 0.1739
0.1739x2=0.3469
grams of benzaldehyde = 0.00144X106.12=0.1539
0.1539x2 = 0.3069
Starting materials:
0.3469 Ox acetophenone,
0.3069 of benzaldehyde
3
1.
Answer the questions about the following reaction:
(a) Draw in the arrows that can be used make this reaction occur and draw in the product of substitution in this
reaction. Be sure to include any relevant stereochemistry in the product structure.
+
SK
F
Br
+
(b) In which solvent would this reaction proceed the fastest (Circle one)
Methanol
Acetone
(c) Imagine that you are working for a chemical company and it was your job to perform a similar reaction to the
one above, with the exception of the S atom in this reaction being replaced by an O atom. During the reaction, you
observe the formation of three separate molecules instead of the single molecule obtained above. What is the likeliest
other products that are formed? Draw them in the box provided.
3. For the reactions below, draw the arrows corresponding to the transformations and draw in the boxes the reactants
or products as indicated. Note: Part A should have arrows drawn going from the reactants to the middle structure
and the arrows on the middle structure that would yield the final structure. For part B, you will need to draw in
the reactant before being able to draw the arrows corresponding to product formation.
A.
B.
Rearrangement
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Chapter 17 Solutions
Chemistry: Atoms First
Ch. 17.1 - Determine the pH at 25C of a solution prepared by...Ch. 17.1 - Determine the pH at 25C of a solution prepared by...Ch. 17.1 - Determine the pH at 25C of a solution prepared by...Ch. 17.1 - Prob. 17.1.1SRCh. 17.1 - Prob. 17.1.2SRCh. 17.2 - Starting with 1.00 L of a buffer that is 1.00 M in...Ch. 17.2 - Prob. 2PPACh. 17.2 - Prob. 2PPBCh. 17.2 - Prob. 17.3WECh. 17.2 - Prob. 3PPA
Ch. 17.2 - Prob. 3PPBCh. 17.2 - Prob. 17.2.1SRCh. 17.2 - Consider 1 L of a buffer that is 0.85 M in formic...Ch. 17.2 - Prob. 17.2.3SRCh. 17.2 - Prob. 17.2.4SRCh. 17.3 - Calculate the pH in the titration of 50.0 mL of...Ch. 17.3 - For the titration of 10.0 mL of 0.15 M acetic acid...Ch. 17.3 - Prob. 4PPBCh. 17.3 - Prob. 4PPCCh. 17.3 - Prob. 17.5WECh. 17.3 - Prob. 5PPACh. 17.3 - Prob. 5PPBCh. 17.3 - Which of the graphs [(i)(iv)] best represents the...Ch. 17.3 - Prob. 17.6WECh. 17.3 - Prob. 6PPACh. 17.3 - Prob. 6PPBCh. 17.3 - Calculate the pH at the equivalence point in the...Ch. 17.3 - Prob. 17.3.2SRCh. 17.3 - Prob. 17.3.3SRCh. 17.4 - Calculate the solubility of copper(II) hydroxide...Ch. 17.4 - Calculate the molar solubility and the solubility...Ch. 17.4 - Calculate the molar solubility and the solubility...Ch. 17.4 - Prob. 17.8WECh. 17.4 - Prob. 8PPACh. 17.4 - Prob. 8PPBCh. 17.4 - Prob. 8PPCCh. 17.4 - Prob. 17.9WECh. 17.4 - Predict whether a precipitate will form from each...Ch. 17.4 - Prob. 9PPBCh. 17.4 - Prob. 17.4.1SRCh. 17.4 - Prob. 17.4.2SRCh. 17.4 - Prob. 17.4.3SRCh. 17.5 - Prob. 17.10WECh. 17.5 - Calculate the molar solubility of AgI in (a) pure...Ch. 17.5 - Arrange the following salts in order of increasing...Ch. 17.5 - Prob. 17.11WECh. 17.5 - Determine if the following compounds are more...Ch. 17.5 - Prob. 11PPBCh. 17.5 - Prob. 11PPCCh. 17.5 - Prob. 17.12WECh. 17.5 - Prob. 12PPACh. 17.5 - Prob. 12PPBCh. 17.5 - Beginning with a saturated solution of AgCl, which...Ch. 17.5 - Prob. 17.5.1SRCh. 17.6 - Prob. 17.13WECh. 17.6 - Prob. 13PPACh. 17.6 - Prob. 13PPBCh. 17.6 - Prob. 17.6.1SRCh. 17.6 - Prob. 17.6.2SRCh. 17 - Which of the acids in Table 16.5 (page 732) can be...Ch. 17 - Prob. 17.3KSPCh. 17 - How much sodium fluoride must be dissolved in 250...Ch. 17 - Use Le Chteliers principle to explain how the...Ch. 17 - Describe the effect on pH (increase, decrease, or...Ch. 17 - Prob. 17.3QPCh. 17 - Prob. 17.4QPCh. 17 - Determine the pH of (a) a 0.40 M CH3COOH solution,...Ch. 17 - Determine the pH of (a) a 0.20 M NH3 solution, and...Ch. 17 - Which pair of substances can be dissolved together...Ch. 17 - Prob. 17.2VCCh. 17 - Prob. 17.3VCCh. 17 - Prob. 17.4VCCh. 17 - Prob. 17.7QPCh. 17 - Prob. 17.8QPCh. 17 - Calculate the pH of the buffer system made up of...Ch. 17 - Calculate the pH of the following two buffer...Ch. 17 - Prob. 17.11QPCh. 17 - Prob. 17.12QPCh. 17 - Prob. 17.13QPCh. 17 - The pH of blood plasma is 7.40. Assuming the...Ch. 17 - Calculate the pH of the 0.20 M NH3/0.20 M NH4Cl...Ch. 17 - Calculate the pH of 1.00 L of the buffer 1.00 M...Ch. 17 - Prob. 17.17QPCh. 17 - Prob. 17.18QPCh. 17 - Prob. 17.19QPCh. 17 - Prob. 17.20QPCh. 17 - The diagrams [(a)(d)] contain one or more of the...Ch. 17 - Prob. 17.22QPCh. 17 - Prob. 17.23QPCh. 17 - Prob. 17.24QPCh. 17 - Prob. 17.25QPCh. 17 - The amount of indicator used in an acid-base...Ch. 17 - Prob. 17.27QPCh. 17 - Prob. 17.28QPCh. 17 - Prob. 17.29QPCh. 17 - Prob. 17.30QPCh. 17 - Prob. 17.31QPCh. 17 - Prob. 17.32QPCh. 17 - Prob. 17.33QPCh. 17 - Prob. 17.34QPCh. 17 - A 25.0-,L solution of 0n100 M CH3COOH is titrated...Ch. 17 - A 10.0-mL solution of 0.300 M NH3 is titratee with...Ch. 17 - Prob. 17.37QPCh. 17 - Prob. 17.38QPCh. 17 - Prob. 17.39QPCh. 17 - Prob. 17.40QPCh. 17 - Diagrams (a) through (d) represent solutions at...Ch. 17 - Prob. 17.42QPCh. 17 - Prob. 17.43QPCh. 17 - Prob. 17.44QPCh. 17 - Write balanced equations and solubility product...Ch. 17 - Prob. 17.46QPCh. 17 - Prob. 17.47QPCh. 17 - Prob. 17.48QPCh. 17 - Prob. 17.49QPCh. 17 - Prob. 17.50QPCh. 17 - Prob. 17.51QPCh. 17 - The solubility of an ionic compound MX (molar mass...Ch. 17 - Prob. 17.53QPCh. 17 - Prob. 17.54QPCh. 17 - Prob. 17.55QPCh. 17 - Prob. 17.56QPCh. 17 - Prob. 17.57QPCh. 17 - A volume of 75 mL of 0.060 M NaF is mixed with 25...Ch. 17 - Prob. 17.59QPCh. 17 - Prob. 17.60QPCh. 17 - Prob. 17.5VCCh. 17 - Prob. 17.6VCCh. 17 - Prob. 17.7VCCh. 17 - How would the concentration of silver ion in the...Ch. 17 - Prob. 17.61QPCh. 17 - Prob. 17.62QPCh. 17 - Prob. 17.63QPCh. 17 - Prob. 17.64QPCh. 17 - The solubility product of PbBr2 is 8.9 106....Ch. 17 - Prob. 17.66QPCh. 17 - Calculate the molar solubility of BaSO4 in (a)...Ch. 17 - Prob. 17.68QPCh. 17 - Prob. 17.69QPCh. 17 - Prob. 17.70QPCh. 17 - Prob. 17.71QPCh. 17 - Prob. 17.72QPCh. 17 - Calculate the concentrations of Cd2+, Cd(CN)42 ,...Ch. 17 - Prob. 17.74QPCh. 17 - Prob. 17.75QPCh. 17 - (a) Calculate the molar solubility of...Ch. 17 - Prob. 17.77QPCh. 17 - Prob. 17.78QPCh. 17 - Prob. 17.79QPCh. 17 - Prob. 17.80QPCh. 17 - Prob. 17.81QPCh. 17 - Prob. 17.82QPCh. 17 - Prob. 17.83QPCh. 17 - Prob. 17.84QPCh. 17 - In a group 1 analysis, a student adds HCl acid to...Ch. 17 - Prob. 17.86QPCh. 17 - Prob. 17.87QPCh. 17 - Sketch the titration curve of a weak acid with a...Ch. 17 - Prob. 17.89QPCh. 17 - Prob. 17.90QPCh. 17 - Prob. 17.91QPCh. 17 - Tris [tris(hydroxymethyl)aminomethane] is a common...Ch. 17 - Prob. 17.93QPCh. 17 - Prob. 17.94QPCh. 17 - Prob. 17.95QPCh. 17 - Prob. 17.96QPCh. 17 - Prob. 17.97QPCh. 17 - Find the approximate pH range suitable for...Ch. 17 - Prob. 17.99QPCh. 17 - Prob. 17.100QPCh. 17 - Prob. 17.101QPCh. 17 - Prob. 17.102QPCh. 17 - Barium is a toxic substance that can seriously...Ch. 17 - The pKa of phenolphthalein is 9.10. Over what pH...Ch. 17 - Prob. 17.105QPCh. 17 - Prob. 17.106QPCh. 17 - Prob. 17.107QPCh. 17 - The molar mass of a certain metal carbonate, MCO3,...Ch. 17 - Prob. 17.109QPCh. 17 - Prob. 17.110QPCh. 17 - Describe how you would prepare a 1 -L 0.20 M...Ch. 17 - Phenolphthalein is the common indicator for the...Ch. 17 - Prob. 17.113QPCh. 17 - Prob. 17.114QPCh. 17 - Prob. 17.115QPCh. 17 - Prob. 17.116QPCh. 17 - Prob. 17.117QPCh. 17 - Prob. 17.118QPCh. 17 - When lemon juice is added to tea, the color...Ch. 17 - How many milliliters of 1.0 M NaOH must be added...Ch. 17 - Prob. 17.121QPCh. 17 - Prob. 17.122QPCh. 17 - Prob. 17.123QPCh. 17 - Prob. 17.124QPCh. 17 - Calcium oxalate is a major component of kidney...Ch. 17 - Water containing Ca2+ and Mg2+ ions is called hard...Ch. 17 - Prob. 17.127QPCh. 17 - Prob. 17.128QPCh. 17 - Prob. 17.129QPCh. 17 - (a) Referring to Figure 17.4, describe how you...Ch. 17 - Prob. 17.131QPCh. 17 - Prob. 17.132QPCh. 17 - Prob. 17.133QPCh. 17 - Prob. 17.134QPCh. 17 - Prob. 17.135QPCh. 17 - Prob. 17.136QPCh. 17 - A sample of 0.96 L of HCl gas at 372 mmHg and 22C...Ch. 17 - Prob. 17.138QPCh. 17 - The solutions (a) through (f) represent various...Ch. 17 - Prob. 17.140QPCh. 17 - Prob. 17.141QP
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