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Concept explainers
Interpretation: At least four other resonance structures of the given compound have to be drawn and identify the reason for why the given structure is the greatest contributor to overall resonance hybrid.
Concept Introduction:
Resonance is an electron displacement effect for stabilizing a molecule through delocalization of bonding electrons in the pi orbital.
Delocalized electrons stabilize a compound. The extra stability gains from having delocalized electrons are called resonance stabilization or resonance energy.
Bond length: Bond distance or bond length is the average distance between nuclei of two bonded atoms in a molecule. It is a transferable property of a bond between atoms of fixed types
Double bonds: One sigma bond and one pi bond are together known as a double bond.
Bond length is inversely proportional to the bond order.
A higher bond order results in a shorter bond for a given pair of atoms.
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Chapter 17 Solutions
Organic Chemistry
- Calculate the reaction quotient for the reaction:NaOH (s) ⇌ Na+ (aq)+ OH- (aq) + 44.4 kJ [Na+] = 4.22 M [OH-] = 6.41 Marrow_forwardGiven the following concentrations for a system, calculate the value for the reaction quotient: Cl2(g)+ CS2(g) ⇌ CCl4(g)+ S2Cl2(g) Cl2 = 31.1 atm CS2 = 91.2 atm CCl4 = 2.12 atm S2Cl2 = 10.4 atmarrow_forwardMatch each chemical or item with the proper disposal or cleanup mwthod, Not all disposal and cleanup methods will be labeled. Metal sheets C, calcium, choroide solutions part A, damp metal pieces Part B, volumetric flask part A. a.Return to correct lables”drying out breaker. Place used items in the drawer.: Rinse with deionized water, dry as best you can, return to instructor. Return used material to the instructor.: Pour down the sink with planty of running water.: f.Pour into aqueous waste container. g.Places used items in garbage.arrow_forward
- Write the equilibrium constant expression for the following reaction: HNO2(aq) + H2O(l) ⇌ H3O+(aq) + NO2-(aq)arrow_forwardWrite the reaction quotient for: Pb2+(aq) + 2 Cl- (aq) ⇌ PbCl2(s)arrow_forwardWrite the equilibrium constant expression for the following system at equilibrium: I2 (g) ⇌ 2 I (g)arrow_forward
- Don't used hand raiting and don't used Ai solutionarrow_forwardWe learned four factors (ARIO) for comparing the relative acidity of compounds. When two of these factors are in competition, the order of priority is the order in which these factors were covered ("atom" being the most important factor and "orbital" being the least important). However, we also mentioned that there are exceptions to this order of priority. Compare the two compounds and identify the exception. OH PK-4.75 SH PK-10.6 5. "Resonance" is more important than "atom" because the conjugate base of first compound is more stable than the second. "Atom" is more important than "resonance" because the conjugate base of first compound is more stable than the second. "Resonance" is more important than "atom" because the conjugate base of second compound is more stable than the first. "Atom" is more important than "resonance" because the conjugate base of second compound is more stable than the first.arrow_forwardThe relative fitnesses of three genotypes are WA/A= 1.0, WA/a = 0.7, and Wa/a = 0.3. If the population starts at the allele frequency p = 0.5, what is the value of p in the next generation? (3 pts) 12pt v Paragraph V BIU ALarrow_forward
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