Problem 1PE: What are the ion product expressions for the following salts: (a) lead(II) bromide, (b) aluminum... Problem 2PE: What are the ion product expressions for the following salts: (a) lead(II) bromide, (b) aluminum... Problem 3PE: The solubility of thallium(I) iodide, TlI, in water at 20Cis5.910-3gL-1. Using this fact, calculate... Problem 4PE: One liter of water will dissolve mol of . Calculate the value of .
Problem 5PE Problem 6PE: Calculate the molar solubility of
Problem 7PE: Calculate the molar solubility of AgI in a 0.20MCaI2 solution. Compare the answer to the calculated... Problem 8PE Problem 9PE: Calculate the ion product for the solution in which the concentration is 0.0025 M and the ... Problem 10PE: Calculate the ion product for a solution containing . Will a precipitate form?
Problem 11PE: What precipitate might be expected if we mix ? Will some precipitate form? Assume that the volumes... Problem 12PE: 50.0 mL of 0.10 M Pb(NO3)2 and 20.0 mL of 0.040 M NaCl ? Will some of that precipitate form? Assume... Problem 13PE: Determine whether adding an acid will increase the solubility of the following salts:... Problem 14PE: Determine the molar solubility of Ag2CrO4in1.0MH+ solution. Problem 15PE: What pH is needed to achieve a concentration of 0.022 M NiS? (Hint: Is NiS soluble in acid according... Problem 16PE: What pH is needed to dissolve 2.00 g PbS in 1.5106L of water? Problem 17PE: If a solution contains calcium ions (0.25 M) and barium ions (0.05 M), what concentration of would... Problem 18PE Problem 19PE: Suppose a solution contains and is saturated with . Would precipitate if the solution has a pH of... Problem 20PE: Consider a solution containing , both at molarities of 0.010 M. It is to be saturated with .... Problem 21PE: The Ksp for barium oxalate, BaC2O4,is1.210andforoxalicacid,H2C2O4,Ka1=5.910-2andKa2=6.410-5. If a... Problem 22PE: A solution contains calcium nitrate and nickel nitrate, each at a concentration of 0.10 M. Carbon... Problem 23PE: Calculate the solubility of silver chloride in and compare it with its solubility in pure water.... Problem 24PE: How many moles of have to be added to 1.0 L of water to dissolve ? The complex ion forms.
Problem 1RQ: Equilibria in Solutions of Slightly Soluble Salts What is the difference between an ion product and... Problem 2RQ: Equilibria in Solutions of Slightly Soluble Salts Use the following equilibrium to demonstrate why... Problem 3RQ: Equilibria in Solutions of Slightly Soluble Salts What is the common ion effect? How does Le... Problem 4RQ: Equilibria in Solutions of Slightly Soluble Salts
17.4. With respect to , what conditions must be... Problem 5RQ Problem 6RQ Problem 7RQ: Equilibria in Solutions of Slightly Soluble Salts Using Figure 12.10, how does the Ksp change with... Problem 8RQ: Solubility of Basic Salts Is Influenced by Acids
17.8. What makes the equilibrium for the solubility... Problem 9RQ Problem 10RQ: Solubility of Basic Salts Is Influenced by Acids
17.10. Water can provide ions to a solution. What... Problem 11RQ: Solubility of Basic Salts Is Influenced by Acids How does Le Chtelier's principle explain the... Problem 12RQ: Solubility of Basic Salts Is Influenced by Acids A solution of MgBr2 can be changed to a solution of... Problem 13RQ: Solubility of Basic Salts Is Influenced by Acids On the basis of Le Chateliers principle, explain... Problem 14RQ: Solubility of Basic Salts Is Influenced by Acids Which of the following will be more soluble if acid... Problem 15RQ: Equilibria in Solutions of Metal Oxides and Sulfides
17.15 Potassium oxide is readily soluble in... Problem 16RQ: Equilibria in Solutions of Metal Oxides and Sulfides
17.16 What chemical reaction takes place when... Problem 17RQ: Equilibria in Solutions of Metal Oxides and Sulfides Consider cobalt(II) sulfide, (a) Write its... Problem 18RQ: Selective Precipitation Use Le Chatelier's principle to explain how adjusting the pH makes it... Problem 19RQ Problem 20RQ: Selective Precipitation If you had a solution with Ag+,Co2+,andCu2+, how could you separate the... Problem 21RQ: Equilibria Involving Complex Ions Explain the interaction between a metal ion and ammonia in a metal... Problem 22RQ: Equilibria Involving Complex Ions What is a formation constant and what is an instability constant? Problem 23RQ: Complexation and Solubility
17.23 Using Le Châtclier’s principle, explain how the addition of... Problem 24RQ: Complexation and Solubility For PbCl3-,Kform=2.5101. If a solution containing this complex ion is... Problem 25RQ Problem 26RQ: Equilibria in Solutions of Slightly Soluble Salts
17.26 Write the , expressions for each of the... Problem 27RQ Problem 28RQ Problem 29RQ Problem 30RQ Problem 31RQ Problem 32RQ: Which compound is more soluble in water, BaSO4orSrCO3 ? Problem 33RQ: 17.33 In water, the solubility of lead(II) chloride is 0.016 M. Use this information to calculate... Problem 34RQ: The solubility of zinc oxalate is 7.9103M. Calculate the KspforZnC2O4. Problem 35RQ: 17.35 Barium sulfate is so insoluble that it can be swallowed without significant danger even though... Problem 36RQ: A student found that a maximum of 0.800 g silver acetate is able to dissolve in 100.0 mL of water.... Problem 37RQ Problem 38RQ: A student prepared a saturated solution of CaCrO4 and found that when 156 mL of the solution was... Problem 39RQ: At 25C, the molar solubility of silver phosphate is 1.810-5molL-1. Calculate Ksp for this salt. Problem 40RQ: 17.40 The molar solubility of barium phosphate in water at . What is the value of for this salt?
Problem 41RQ: What is the molar solubility of PbBr2 in water? Problem 42RQ: 17.42 What is the molar solubility of in water?
Problem 43RQ: Calculate the molar solubility of Zn(CN)2 in water. (Ignore the reaction of the CN- ion with water.) Problem 44RQ: Calculate the molar solubility of PbF2 in water. (Ignore the reaction of the F- ion with water.) Problem 45RQ: 17.45 At , the value of for , and that for . Which salt, , has the larger molar solubility in... Problem 46RQ: At 25C, the value of Ksp for AgCNis6.010-17 and that for Zn(CN)2is310-l6. In terms of grams per 100... Problem 47RQ: A salt whose formula is MX has a Ksp equal to 3.21010. Another sparingly soluble salt, MX3, must... Problem 48RQ: 17.48 A salt having a formula of the type has . Another salt. , has to have what value if has... Problem 49RQ: Calcium sulfate is found in plaster. At 25C the value of Ksp for CaSO4 is 4.9105. What is the... Problem 50RQ: Chalk is CaCO3, and at 25CitsKsp=3.410 What is the molar solubility of CaCO3 ? How many grams of... Problem 51RQ: It was found that the molar solubility of BaSO3 in 0.10MBaCl2is8.010-6M. What is the value of for... Problem 52RQ: 17.52 The molar solubility of . What is the value of ?
Problem 53RQ Problem 54RQ: Mercury(I) chloride has Ksp=1.41018. Calculate the molar solubility of mercury(l) chloride in (a)... Problem 55RQ: Calculate the molar solubility of Mg(OH)2 in a solution that is basic with a pH of 12.50. Problem 56RQ: 17.56 Calculate the molar solubility of in a solution that is slightly basic with a pH of 9.50.
Problem 57RQ: 17.57 What is the highest concentration of that can exist in a solution of 0.10 M HCl?
Problem 58RQ: 17.58 Will lead (II) bromide be less soluble in 0.10 M Pb or in 0.10 M NaBr?
Problem 59RQ: Calculate the molar solubility of... Problem 60RQ: 17.60 What is the molar solubility of in (a) 0.20 M NaOH and (b) ? For .
Problem 61RQ: 17.61 What is the molar solubility of in a buffer that has a pH of 9.50?
Problem 62RQ: What is the molar solubility of Ca(OH)2 in (a) 0.10MCaCl2 and (b) 0.10 M NaOH? Problem 63RQ: In an experiment, 2.20gofNaOH(s) is added to 250 mL of 0.10MFeCl2 solution. What mass of Fe(OH)2... Problem 64RQ: Suppose that 1.75 g of NaOH(s) is added to 250 mL of 0.10MNiCl2 solution. What mass, in grams, of... Problem 65RQ: 17.65 Docs a precipitate of form when are dissolved in 1.00 I. of solution?
Problem 66RQ Problem 67RQ: 17.67 Docs a precipitate of form if 50.0 ml. of is mixed with (a) 50.0 ml. of 0.0100 M KBr and (b)... Problem 68RQ Problem 69RQ: 17.69 Suppose that 50.0 mL each of 0.0100 M solutions of are poured together. Does a precipitate... Problem 70RQ: If a solution of 0.10 M Mn2+ and 0.10 M Cd2+ is gradually made basic, what will the concentration of... Problem 71RQ: In an aqueous suspension of Ca(OH)2, the only other component is water. Use Ksp to estimate the pH... Problem 72RQ: Suppose that 25.0 mL of 0.10MHCl is added to 1.000 L of saturated Mg(OH)2 in contact with more than... Problem 73RQ: *17.73 When solid is added to a suspension of (s), some of the dissolves. (a) Write equations for... Problem 74RQ: *17.74 After solid was added to a slightly basic solution, the pH was measured to be 8.50. What was... Problem 75RQ: *17.75 Will a precipitate form in a solution made by dissolving of solution? For
Problem 76RQ: 17.76 What is the molar solubility of in water? (Hint: You have to take into account the... Problem 77RQ: Solubility of Basic Salts Is Influenced by Acids
*17.77 Magnesium hydroxide, , found in milk of... Problem 78RQ: Solubility of Basic Salts Is Influenced by Acids
*17.78 What is the molar solubility of... Problem 79RQ: *17.79 What is the molar solubility of in pure water, and in ? (Hint: In this solution, assume the... Problem 80RQ: 17.80 What is the molar solubility of in pure water, and in ? (Hint: In this solution, the... Problem 81RQ: How many grams of solid sodium acetate must be added to 0.200 L of a solution containing 0.200 M... Problem 82RQ: How many grams of solid potassium fluoride must be added to 200 mL of a solution that contains 0.20... Problem 83RQ: What is the molar solubility of Mg(OH)2 in 0.1MNH3 solution? Remember that NH3 is a weak base. Problem 84RQ: *17.84 If 100 mL of is added to 0.400 L of a solution containing , what minimum number of grams of ... Problem 85RQ: Equilibria in Solutions of Metal Oxides and Sulfides Calculate the molar solubility of CoS in water... Problem 86RQ Problem 87RQ: *17.87 Does nickel(II) sulfide dissolve in 4 M HCl? Perform the calculations that prove your... Problem 88RQ: Does iron(II) sulfide dissolve in 8 M HCl? Perform the calculations that prove your answer. Problem 89RQ: Selective Precipitation Both AgCl and AgI are very sparingly soluble salts, but the solubility of... Problem 90RQ Problem 91RQ: 17.91 What value of and what pH permit the selective precipitation of the sulfide of just one of the... Problem 92RQ: What pH would yield the maximum separation of Mn2+ from Sn2+ in a solution that is 0.010 M in Mn2+,... Problem 93RQ Problem 94RQ: Kidney stones often contain insoluble calcium oxalate, CaC2O4, which has a Ksp=2.3109. Calcium... Problem 95RQ: 17.95 Solid is added to a solution of . After reaction, what will be the molar concentrations of ... Problem 96RQ: What value of [ H+ ] and what pH would allow the selective separation of the carbonate of just one... Problem 97RQ Problem 98RQ: *17.98 In the metal plating industry, the waste is often contaminated with . In order to save the... Problem 99RQ: Equilibria Involving Complex Ions
17.99 Write the chemical equilibria and equilibrium laws that... Problem 100RQ: Equilibria Involving Complex Ions
17.100 Write the chemical equilibria and equilibrium laws that... Problem 101RQ Problem 102RQ Problem 103RQ Problem 104RQ Problem 105RQ: For PbCl3, Kform=2.510 . Use this information plus the Ksp for PbCl2 to calculate Kc for the... Problem 106RQ: The overall formation constant for Ag(CN)2 equals 5.31018, and the Ksp for AgCN equals 6.01017.... Problem 107RQ: How many grams of solid NaCN have to be added to 1.2 L of water to dissolve 0.11molofFe(OH)3 in the... Problem 108RQ Problem 109RQ: Silver iodide is very insoluble and can be difficult to remove from glass apparatus, but it forms a... Problem 110RQ: 17.110 Silver forms a sparingly soluble iodide salt, AgI, and it also forms a soluble iodide... Problem 111RQ: The formation constant for Ag(CN)2-equals5.341018. Use the data in Table 17.1 to determine the molar... Problem 112RQ: 17.112 Suppose that some dipositive cation, , is able to form a complex ion with a ligand, L, by the... Problem 113RQ: (Calculate the molar solubility of Cu(OH)2in2.0MNH3. (For simplicity, ignore the reaction of NH3 as... Problem 114RQ: The molar solubility of Zn(OH)2in1.0MNH3 is 5.710-3molL-1. Determine the value of the instability... Problem 115RQ: What ratio of Ksp values will allow for the use of selective precipitation to separate two ionic... Problem 116RQ: A student had a solution that contained Ph2+,Ni2+,andCd2+ and wanted to separate the ions. The... Problem 117RQ: Suppose that 50.0 mL of 0.12 M AgNO3 is added to 50.0 mL of 0.048 M NaCl solution. (a) What mass of... Problem 118RQ Problem 119RQ Problem 120RQ: In Example 17.11 we say, there are relatively few uncomplexed Ag+ ions in the solution." Calculate... Problem 121RQ: *17.121 What is the molar solubility of ? What is the formula of the complex formed?
Problem 122RQ: *17.122 An old method for mining gold was to wash the ore with a cyanide solution and oxidizing... Problem 123RQ: What is the molar concentration of Cu2+ ion in a solution prepared by mixing... Problem 124RQ: On the basis of the KspofAl(OH)3, what would be the pH of a mixture consisting of solid Al(OH)3... Problem 125RQ: The compound EDTA is used to remove soap scum, as it was described in the Chemistry Outside the... Problem 126RQ: A chemist has a solution that contains a mixture of the following metal ions:... Problem 127RQ: You are given a sample containing , both with concentrations of 0.020 M. Some of the figures shown... Problem 128RQ Problem 129RQ: In modern construction, walls and ceilings are constructed of drywall, which consists of plaster... Problem 130RQ: *17.130 How many milliliters of would have to be added to 100 mL of a saturated solution of in... Problem 131RQ: Marble is composed primarily of CaCO3, a slightly soluble salt. Unfortunately, it is attacked by the... Problem 132RQ: *17.132 The pH of a saturated solution of is 9.8. Determine the for .
Problem 133RQ: The osmotic pressure of a saturated solution of NiCO3 is 13 torr at 25 C. From this information,... Problem 134RQ: A saturated solution of PbCl2 has a freezing point of -0.089 C. What is the Ksp of PbCl2 2 as... Problem 135RQ: 17.135 Consider mercury(II) sulfide, , which has a solubility product of . Suppose some solid was... Problem 136RQ: If aqueous ammonia is added gradually to a solution of copper sulfate, a pale blue precipitate forms... Problem 137RQ: From a practical standpoint, can you effectively separate Pb2+andSr2+ ions by selective... Problem 139RQ: 17.139 In older textbooks, the solubility equilibrium for lead(II) sulfide was written as .... Problem 140RQ: Suppose two silver wires, one coated with silver chloride and the other coated with silver bromide,... format_list_bulleted