Chemical Principles in the Laboratory
11th Edition
ISBN: 9781305264434
Author: Emil Slowinski, Wayne C. Wolsey, Robert Rossi
Publisher: Brooks Cole
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Chapter 17, Problem 4ASA
Interpretation Introduction
Interpretation:
The substance that is gray-white solid, melts at
Concept introduction:
Substances are classified on the basis of the kinds of bonding present in it. There are three types of substances.
- Ionic substances
- Molecular substances
- Metallic substances
Molecular substances have covalent bonds between the atoms, ionic substances have electrostatic forces between the ions, and metallic substances have metallic bonds.
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Draw the anti-Markovnikov product of the hydration of this alkene.
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3. Before proceeding with this problem you may want to glance at p. 466 of your textbook
where various oxo-phosphorus derivatives and their oxidation states are summarized.
Shown below are Latimer diagrams for phosphorus at pH values at 0 and 14:
-0.93
+0.38
-0.50
-0.51 -0.06
H3PO4 →H4P206 →H3PO3 →→H3PO₂ → P → PH3
Acidic solution
Basic solution
-0.28
-0.50
3--1.12
-1.57
-2.05 -0.89
PO HPO H₂PO₂ →P → PH3
-1.73
a) Under acidic conditions, H3PO4 can be reduced into H3PO3 directly (-0.28V), or via the
formation and reduction of H4P206 (-0.93/+0.38V). Calculate the values of AG's for both
processes; comment.
(3 points)
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P
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-3 -2
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b) Frost diagram for phosphorus under acidic
conditions is shown. Identify possible
disproportionation and comproportionation processes;
write out chemical equations describing them. (2 points)
H,PO
4
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Oxidation stale, N
Chapter 17 Solutions
Chemical Principles in the Laboratory
Knowledge Booster
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