Products of given reactions has to be predicted. Concept introduction: Given set of conditions gives a final product of reaction through a series of steps. Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction. Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction. A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product. Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction. Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product. A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

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Answer 1

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 17, Problem 49P

(a)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(b)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(c)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(d)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(e)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(f)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

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On the next page is an LC separation of the parabens found in baby wash. Parabens are suspected in a link to breast cancer therefore an accurate way to quantitate them is desired. a. In the chromatogram, estimate k' for ethyl paraben. Clearly indicate what values you used for all the terms in your calculation. b. Is this a "good" value for a capacity factor? Explain. c. What is the resolution between n-Propyl paraben and n-Butyl paraben? Again, indicate clearly what values you used in your calculation. MAU | Methyl paraben 40 20 0 -2 Ethyl paraben n-Propyl paraben n-Butyl paraben App ID 22925 6 8 min

d. In Figure 4, each stationary phase shows some negative correlation between plate count and retention factor. In other words, as k' increases, N decreases. Explain this relationship between k' and N. Plate Count (N) 4000 3500 2500 2000 1500 1000 Figure 4. Column efficiency (N) vs retention factor (k') for 22 nonionizable solutes on FMS (red), PGC (black), and COZ (green). 3000 Eluent compositions (acetonitrile/water, A/W) were adjusted to obtain k' less than 15, which was achieved for most solutes as follows: FMS (30/70 A/W), PGC (60/40), COZ (80/20). Slightly different compositions were used for the most highly retained solutes. All columns were 50 mm × 4.6 mm id and packed with 5 um particles, except for COZ, which was packed with 3 um particles. All other chromatographic conditions were constant: column length 5 cm, column j.§. 4.6 mm, flow rate 2 mL/min, column temperature 40 °C, and injection volume 0.5 μL Log(k'x/K'ethylbenzene) FMS 1.5 1.0 0.5 0.0 ཐྭ ཋ ཤྩ བྷྲ ; 500 0 5 10…

f. Predict how the van Deemter curve in Figure 7 would change if the temperature were raised from 40 °C to 55 °C. Figure 7. van Desmter curves in reduced coordinates for four nitroalkane homologues (nitropropane, black; nitrobutane, red; nitropentane, blue; and nitrohexane, green) separated on the FMS phase. Chromatographic conditions: column dimensions 50 mm × 4.6 mm id, eluent 30/70 ACN/water, flow rates 0.2-5.0 mL/min, injection volume 0.5 and column temperature 40 °C. No corrections to the plate heights have been made to account for extracolumn dispersion. Reduced Plate Height (h) ° 20 40 60 Reduced Velocity (v) 8. (2) A water sample is analyzed for traces of benzene using headspace analysis. The sample and standard are spiked with a fixed amount of toluene as an internal standard. The following data are obtained: Ppb benzene Peak area benzene Peak area toluene 10.0 252 376 Sample 533 368 What is the concentration of benzene in the sample?

Answer 2

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 17, Problem 49P

(a)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(b)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(c)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(d)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(e)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(f)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

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Answer 3

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 17, Problem 49P

(a)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(b)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(c)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(d)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(e)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(f)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

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Check out a sample textbook solution

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Answer 4

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 17, Problem 49P

(a)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(b)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(c)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(d)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(e)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(f)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Expert Solution & Answer

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Check out a sample textbook solution

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Answer 5

Chapter 17, Problem 49P

(a)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(b)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(c)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(d)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(e)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(f)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Answer 6

Chapter 17, Problem 49P

(a)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Answer 7

Chapter 17, Problem 49P

(a)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Answer 8

(b)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Answer 9

(b)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Answer 10

(c)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Answer 11

(c)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Answer 12

(d)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Answer 13

(d)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Answer 14

(e)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Answer 15

(e)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Answer 16

(f)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Answer 17

(f)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Answer 18

Expert Solution & Answer

Answer 19

Expert Solution & Answer

Answer 20

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Answer 21

Ch. 17.1 - Prob. 1P Ch. 17.1 - Prob. 2P Ch. 17.1 - Prob. 3P Ch. 17.1 - Prob. 4P Ch. 17.1 - Rank the compounds in each of the following groups...Ch. 17.2 - Explain why 92% of 2,4-pemtanedione exists as the...Ch. 17.3 - Draw the enol tautomers for each of the following...Ch. 17.3 - Prob. 8P Ch. 17.4 - Prob. 9P Ch. 17.4 - Prob. 10P

Solution Summary: The author explains that Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

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Chapter 17 Solutions