
EBK INTRODUCTORY CHEMISTRY: AN ACTIVE L
6th Edition
ISBN: 8220100547508
Author: CRACOLICE
Publisher: Cengage Learning US
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Chapter 17, Problem 35E
Interpretation Introduction
Interpretation:
The reason as to how strong acid and strong reducing agent is similar is to be stated. The reason as to how strong base compares with a strong oxidizing agent is to be stated.
Concept introduction:
The acid that has a very high capacity to lose a proton is known as strong acid. They completely dissociates into the water.
The base that has a very high capacity to lose hydroxide ion is known as strong base. They completely dissociates into the aqueous solution.
The species that has the tendency to gain an electron and get reduced is known as an oxidizing agent.
The species that reduces other substances by donating an electron is known as a reducing agent.
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-AG|F=2E|V
3. Before proceeding with this problem you may want to glance at p. 466 of your textbook
where various oxo-phosphorus derivatives and their oxidation states are summarized.
Shown below are Latimer diagrams for phosphorus at pH values at 0 and 14:
Acidic solution
-0.93
+0.38
-0.51 -0.06
H3PO4 →H4P206 H3PO3 H3PO2 → P→ PH3
-0.28
-0.50
→
-0.50
Basic solution
3-1.12
-1.57
-2.05 -0.89
PO HPO →→H2PO2 P PH3
-1.73
a) Under acidic conditions, H3PO4 can be reduced into H3PO3 directly (-0.28V), or via the
formation and reduction of H4P2O6 (-0.93/+0.38V). Calculate the values of AG's for both
processes; comment.
(3 points)
0.5 PH,
0.0
-0.5-
2 3 9 3
-1.5
-2.0
Pa
H,PO
H,PO
H,PO
-3
-1 0
2
4
Oxidation state, N
2
b) Frost diagram for phosphorus under acidic
conditions is shown. Identify possible
disproportionation and comproportionation processes;
write out chemical equations describing them. (2 points)
c) Elemental phosphorus tends to disproportionate under basic conditions. Use data in…
These two reactions appear to start with the same starting materials but result in different products. How do the chemicals know which product to form? Are both products formed, or is there some information missing that will direct them a particular way?
What would be the best choices for the missing reagents 1 and 3 in this synthesis?
1. PPh3
3
1
2
2. n-BuLi
• Draw the missing reagents in the drawing area below. You can draw them in any arrangement you like.
• Do not draw the missing reagent 2. If you draw 1 correctly, we'll know what it is.
• Note: if one of your reagents needs to contain a halogen, use bromine.
Explanation
Check
Click and drag to start drawing a structure.
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Chapter 17 Solutions
EBK INTRODUCTORY CHEMISTRY: AN ACTIVE L
Ch. 17 - Prob. 1ECh. 17 - Prob. 2ECh. 17 - Prob. 3ECh. 17 - a Write a net ionic equation to show that...Ch. 17 - Prob. 5ECh. 17 - Classify each of the following substances into the...Ch. 17 - Prob. 7ECh. 17 - Aluminum chloride, AlCl3, behaves more as a...Ch. 17 - Prob. 9ECh. 17 - Prob. 10E
Ch. 17 - Prob. 11ECh. 17 - Prob. 12ECh. 17 - Prob. 13ECh. 17 - In the following net ionic reaction, identify each...Ch. 17 - Prob. 15ECh. 17 - Prob. 16ECh. 17 - Prob. 17ECh. 17 - Prob. 18ECh. 17 - Prob. 19ECh. 17 - Prob. 20ECh. 17 - Prob. 21ECh. 17 - Prob. 22ECh. 17 - List the following bases in order of their...Ch. 17 - Prob. 24ECh. 17 - Prob. 25ECh. 17 - Prob. 26ECh. 17 - Prob. 27ECh. 17 - Prob. 28ECh. 17 - Prob. 29ECh. 17 - Prob. 30ECh. 17 - Prob. 31ECh. 17 - Prob. 32ECh. 17 - Prob. 33ECh. 17 - Prob. 34ECh. 17 - Prob. 35ECh. 17 - Prob. 36ECh. 17 - Prob. 37ECh. 17 - Prob. 38ECh. 17 - Prob. 39ECh. 17 - Prob. 40ECh. 17 - Prob. 41ECh. 17 - Prob. 42ECh. 17 - Prob. 43ECh. 17 - Prob. 44ECh. 17 - If the pH of a solution is 8.6, is the solution...Ch. 17 - Prob. 46ECh. 17 - Prob. 47ECh. 17 - Prob. 48ECh. 17 - Prob. 49ECh. 17 - Prob. 50ECh. 17 - Prob. 51ECh. 17 - Prob. 52ECh. 17 - Prob. 53ECh. 17 - Prob. 54ECh. 17 - Prob. 55ECh. 17 - Prob. 56ECh. 17 - Prob. 57ECh. 17 - Prob. 58ECh. 17 - Prob. 59ECh. 17 - Prob. 60ECh. 17 - Prob. 61ECh. 17 - Prob. 62ECh. 17 - Prob. 63ECh. 17 - Classify each of the following statements as true...Ch. 17 - Prob. 65ECh. 17 - Explain what amphoteric means. Give an example of...Ch. 17 - Prob. 67ECh. 17 - Prob. 68ECh. 17 - Prob. 69ECh. 17 - Prob. 70ECh. 17 - Prob. 71ECh. 17 - Prob. 72ECh. 17 - Prob. 73ECh. 17 - Prob. 74ECh. 17 - Prob. 75ECh. 17 - Prob. 76ECh. 17 - According to the Arrhenius theory of acids and...Ch. 17 - Prob. 17.2TCCh. 17 - Prob. 17.3TCCh. 17 - Prob. 17.4TCCh. 17 - Write a brief description of the relationships...Ch. 17 - Prob. 2CLECh. 17 - Prob. 3CLECh. 17 - Prob. 4CLECh. 17 - Write a brief description of the relationships...Ch. 17 - Prob. 6CLECh. 17 - Prob. 7CLECh. 17 - Prob. 8CLECh. 17 - Prob. 9CLECh. 17 - Prob. 10CLECh. 17 - Prob. 11CLECh. 17 - Prob. 1PECh. 17 - Prob. 2PECh. 17 - Prob. 3PECh. 17 - Prob. 4PECh. 17 - Write the net ionic equation for the reaction...Ch. 17 - Prob. 6PECh. 17 - Prob. 7PECh. 17 - Prob. 8PECh. 17 - Prob. 9PECh. 17 - Prob. 10PECh. 17 - Prob. 11PECh. 17 - Prob. 12PECh. 17 - Prob. 13PECh. 17 - Prob. 14PECh. 17 - What are the pOH, hydroxide ion concentration, and...
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