ORGANIC CHEMISTRY-PRINT COMPANION (LL)
ORGANIC CHEMISTRY-PRINT COMPANION (LL)
3rd Edition
ISBN: 9781119444251
Author: Klein
Publisher: WILEY
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Chapter 17, Problem 31PP
Interpretation Introduction

Interpretation: For the given terms, it should be identified whether it is used in reference to benzene or to cyclohexane

Concept introduction:

Cyclohexane and benzene have different properties, different energy, and different reactivity. Each of these compounds also has a unique set of terminology.

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. Provide IUPAC names for each of the following structures OR draw structures corresponding to each of the following names: [Three only]kk a. H₂N- 0 COCH2CH3 benzocaine b. What is the correct structure for phenylbenzoate? C a. 0 C-O O b. H3C-C-O 0 0 C-O-CH3 d. CH₂O C-CHZ c. Acetyl chloride d. 3,4,5-trimethoxybenzoyl chloride
. Draw structures corresponding to each of the following names or Provide IUPAC names for each of the ollowing structures [for 4 ONLY]. A. 2-propylpentanoic acid. B. m-chlorobenzoic acid. C. 0 0 HOC(CH2) COH glutaricadd D. E. F. 0 OH HO OH HO INCO salicylicadd H3C CH3 C=C tgicadd H COOH CH₂C=N 4
The reaction of a carboxylic acid with an alcohol in the presence of acid is termed Fischer esterification. 0 0 C .C. OH + CH3OH OCH3 + H₂O HCI A B C A. The nucleophile in this reaction is B. Compound C functions as a. a base scavenger b. a solvent C. a catalyst in this reaction. d. a neutralizer C. Fischer esterification is an example of: ........ a. nucleophilic acyl addition b. nucleophilic acyl substitution c. nucleophilic acyl elimination d. nucleophilic acyl rearrangement

Chapter 17 Solutions

ORGANIC CHEMISTRY-PRINT COMPANION (LL)

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