10th Edition

ISBN: 9781260028355

Author: Carey

Publisher: MCG CUSTOM

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Textbook Question

Chapter 17, Problem 24P

The name of the parent six-membered sulfur-containing heterocycle is thiane. It is

numbered beginning at sulfur. Multiple incorporation of sulfur in the ring is indicated by the prefixes di-, tri-, and so on.

How many methyl-substituted thianes are there? Which ones are chiral?

Write structural formulas for 1,4-dithiane and 1,3,5-trithiane.

Which dithiane isomer (1,2-, 1,3-, or 1,4-) is a disulfide?

Draw the two most stable conformations of the sulfoxide derived from thiane.

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Chapter 17, Problem 23P

Chapter 17, Problem 25P

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Chapter 17 Solutions

ORGANIC CHEMISTRY-PACKAGE >CUSTOM<

Ch. 17.1 - Prob. 1P Ch. 17.2 - The heats of combustion of 1, 2-epoxybutane...Ch. 17.3 - Prob. 3P Ch. 17.4 - Prob. 4P Ch. 17.5 - Prob. 5P Ch. 17.6 - Problem 17.6 (a) Write equations describing two...Ch. 17.6 - Problem 17.7 Only one combination of alkyl halide...Ch. 17.6 - Prob. 8P Ch. 17.8 - Prob. 9P Ch. 17.8 - Prob. 10P

Ch. 17.9 - Prob. 11P Ch. 17.10 - Problem 17.12 Classify the bromohydrins formed...Ch. 17.11 - Prob. 13P Ch. 17.11 - Prob. 14P Ch. 17.12 - Prob. 15P Ch. 17.12 - Prob. 16P Ch. 17.14 - Prob. 17P Ch. 17.15 - Prob. 18P Ch. 17.16 - Prob. 19P Ch. 17.17 - Problem 17.20 There is another oxygen-stabilized...Ch. 17 - Prob. 21P Ch. 17 - Many ethers, including diethyl ether, are...Ch. 17 - Although epoxides are always considered to have...Ch. 17 - The name of the parent six-membered...Ch. 17 - Prob. 25P Ch. 17 - Prob. 26P Ch. 17 - Prob. 27P Ch. 17 - Prob. 28P Ch. 17 - Prob. 29P Ch. 17 - Given that: does the product of the analogous...Ch. 17 - Prob. 31P Ch. 17 - Prob. 32P Ch. 17 - Prob. 33P Ch. 17 - Prob. 34P Ch. 17 - Prob. 35P Ch. 17 - Prob. 36P Ch. 17 - When (R)-(+)-2-phenyl-2-butanol is allowed to...Ch. 17 - Prob. 38P Ch. 17 - Prob. 39P Ch. 17 - Write a mechanism for the following reaction.Ch. 17 - Prob. 41P Ch. 17 - Prob. 42P Ch. 17 - Prob. 43P Ch. 17 - Prob. 44P Ch. 17 - Prob. 45P Ch. 17 - Prob. 46DSP Ch. 17 - Prob. 47DSP Ch. 17 - Prob. 48DSP Ch. 17 - Prob. 49DSP Ch. 17 - Epoxide Rearrangements and the NIH Shift This...Ch. 17 - Epoxide Rearrangements and the NIH Shift This...

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Solution Summary: The author explains the number of methyl-substituted thianes and those chiral, and the structural formulas for the sulfoxide derived from thiane.

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