Atkins' Physical Chemistry 11e
Atkins' Physical Chemistry 11e
11th Edition
ISBN: 9780192575135
Author: Peter Atkins; Julio de Paula; James Keeler
Publisher: Oxford University Press Academic UK
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Chapter 17, Problem 17D.1P
Interpretation Introduction

Interpretation:

From the following data the activation energy has to be estimated.

    kr/(10-3s-1)2.4645.1576θ/oC020.040.0

Concept Introduction:

Arrhenius Equation:

The temperature dependence characteristics of reaction is normally expressed mathematically by introducing two parameters, one representing the intercept and the other the slop of the straight line of a so-called ‘Arrhenius plot’ of ln k, against 1/T and writing the Arrhenius equation.

    lnk = lnA - EaRT

A is the parameter obtained from the intercept of the line at 1/T = 0 is called the frequency factor.  The parameter Ea is called the activation energy.  The two quantities are collectively known as Arrhenius parameters.

Atkins' Physical Chemistry 11e, Chapter 17, Problem 17D.1P

Figure.1

If the activation energy of a reaction is known, the value of a rate constant k2 at a temperature T2 can be predicted from its value k1 at another temperature T1

That is:

    ln(k2k1)=EaR[1T1-1T2]

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Chapter 17 Solutions

Atkins' Physical Chemistry 11e

Ch. 17 - Prob. 17A.2DQCh. 17 - Prob. 17A.3DQCh. 17 - Prob. 17A.4DQCh. 17 - Prob. 17A.1AECh. 17 - Prob. 17A.1BECh. 17 - Prob. 17A.2AECh. 17 - Prob. 17A.2BECh. 17 - Prob. 17A.3AECh. 17 - Prob. 17A.3BECh. 17 - Prob. 17A.4AECh. 17 - Prob. 17A.4BECh. 17 - Prob. 17A.5AECh. 17 - Prob. 17A.5BECh. 17 - Prob. 17A.6AECh. 17 - Prob. 17A.6BECh. 17 - Prob. 17A.7AECh. 17 - Prob. 17A.7BECh. 17 - Prob. 17A.9AECh. 17 - Prob. 17A.9BECh. 17 - Prob. 17A.1PCh. 17 - Prob. 17A.2PCh. 17 - Prob. 17A.3PCh. 17 - Prob. 17B.1DQCh. 17 - Prob. 17B.2DQCh. 17 - Prob. 17B.3DQCh. 17 - Prob. 17B.1BECh. 17 - Prob. 17B.2AECh. 17 - Prob. 17B.2BECh. 17 - Prob. 17B.3AECh. 17 - Prob. 17B.3BECh. 17 - Prob. 17B.4AECh. 17 - Prob. 17B.4BECh. 17 - Prob. 17B.5AECh. 17 - Prob. 17B.5BECh. 17 - Prob. 17B.6BECh. 17 - Prob. 17B.3PCh. 17 - Prob. 17B.4PCh. 17 - Prob. 17B.5PCh. 17 - Prob. 17B.6PCh. 17 - Prob. 17B.7PCh. 17 - Prob. 17B.8PCh. 17 - Prob. 17B.9PCh. 17 - Prob. 17B.10PCh. 17 - Prob. 17B.11PCh. 17 - Prob. 17B.12PCh. 17 - Prob. 17B.14PCh. 17 - Prob. 17B.15PCh. 17 - Prob. 17B.16PCh. 17 - Prob. 17B.17PCh. 17 - Prob. 17B.18PCh. 17 - Prob. 17C.1DQCh. 17 - Prob. 17C.2DQCh. 17 - Prob. 17C.1BECh. 17 - Prob. 17C.2AECh. 17 - Prob. 17C.2BECh. 17 - Prob. 17C.6PCh. 17 - Prob. 17D.1DQCh. 17 - Prob. 17D.1AECh. 17 - Prob. 17D.1BECh. 17 - Prob. 17D.2AECh. 17 - Prob. 17D.2BECh. 17 - Prob. 17D.3AECh. 17 - Prob. 17D.3BECh. 17 - Prob. 17D.4AECh. 17 - Prob. 17D.4BECh. 17 - Prob. 17D.5BECh. 17 - Prob. 17D.1PCh. 17 - Prob. 17D.3PCh. 17 - Prob. 17D.4PCh. 17 - Prob. 17D.5PCh. 17 - Prob. 17D.6PCh. 17 - Prob. 17E.1DQCh. 17 - Prob. 17E.2DQCh. 17 - Prob. 17E.3DQCh. 17 - Prob. 17E.4DQCh. 17 - Prob. 17E.5DQCh. 17 - Prob. 17E.6DQCh. 17 - Prob. 17E.1AECh. 17 - Prob. 17E.1BECh. 17 - Prob. 17E.2AECh. 17 - Prob. 17E.2BECh. 17 - Prob. 17E.3AECh. 17 - Prob. 17E.3BECh. 17 - Prob. 17E.4PCh. 17 - Prob. 17F.1DQCh. 17 - Prob. 17F.3DQCh. 17 - Prob. 17F.4DQCh. 17 - Prob. 17F.1AECh. 17 - Prob. 17F.1BECh. 17 - Prob. 17F.2AECh. 17 - Prob. 17F.2BECh. 17 - Prob. 17F.3AECh. 17 - Prob. 17F.3BECh. 17 - Prob. 17F.4AECh. 17 - Prob. 17F.4BECh. 17 - Prob. 17F.2PCh. 17 - Prob. 17F.3PCh. 17 - Prob. 17F.4PCh. 17 - Prob. 17F.6PCh. 17 - Prob. 17F.7PCh. 17 - Prob. 17G.1AECh. 17 - Prob. 17G.1BECh. 17 - Prob. 17G.2AECh. 17 - Prob. 17G.2BECh. 17 - Prob. 17G.3AECh. 17 - Prob. 17G.3BECh. 17 - Prob. 17G.1PCh. 17 - Prob. 17G.2PCh. 17 - Prob. 17G.7PCh. 17 - Prob. 17.3IACh. 17 - Prob. 17.6IACh. 17 - Prob. 17.7IA
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