General Chemistry
7th Edition
ISBN: 9780073402758
Author: Chang, Raymond/ Goldsby
Publisher: McGraw-Hill College
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Question
Chapter 17, Problem 17.56QP
(a)
Interpretation Introduction
Interpretation:
Dissolving of
(b)
Interpretation Introduction
Interpretation:
Dissolving of
(c)
Interpretation Introduction
Interpretation:
Dissolving of
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A
J
то
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+0
Also calculate the amount of starting materials chlorobenzaldehyde and p-chloroacetophenone
required to prepare 400 mg of the given chalcone product 1, 3-bis(4-chlorophenyl)prop-2-en-1-one
molar mass ok 1,3-bis(4-Chlorophenyl) prop-2-en-1-one = 277.1591m01
number of moles= 0.400/277.15 = 0.00144 moles
2 x 0.00 144=0.00288 moves
arams of acetophenone = 0.00144 X 120.16 = 0.1739
0.1739x2=0.3469
grams of benzaldehyde = 0.00144X106.12=0.1539
0.1539x2 = 0.3069
Starting materials:
0.3469 Ox acetophenone,
0.3069 of benzaldehyde
3
1.
Answer the questions about the following reaction:
(a) Draw in the arrows that can be used make this reaction occur and draw in the product of substitution in this
reaction. Be sure to include any relevant stereochemistry in the product structure.
+
SK
F
Br
+
(b) In which solvent would this reaction proceed the fastest (Circle one)
Methanol
Acetone
(c) Imagine that you are working for a chemical company and it was your job to perform a similar reaction to the
one above, with the exception of the S atom in this reaction being replaced by an O atom. During the reaction, you
observe the formation of three separate molecules instead of the single molecule obtained above. What is the likeliest
other products that are formed? Draw them in the box provided.
3. For the reactions below, draw the arrows corresponding to the transformations and draw in the boxes the reactants
or products as indicated. Note: Part A should have arrows drawn going from the reactants to the middle structure
and the arrows on the middle structure that would yield the final structure. For part B, you will need to draw in
the reactant before being able to draw the arrows corresponding to product formation.
A.
B.
Rearrangement
ΘΗ
Chapter 17 Solutions
General Chemistry
Ch. 17.2 - Prob. 1PECh. 17.2 - Prob. 2PECh. 17.2 - Prob. 1RCCh. 17.2 - Prob. 3PECh. 17.3 - Prob. 1PECh. 17.3 - Prob. 1RCCh. 17.4 - Practice Exercise Referring to Table 17.1, specify...Ch. 17.4 - Prob. 1RCCh. 17.5 - Prob. 1RCCh. 17.5 - Prob. 1PE
Ch. 17.5 - Prob. 2PECh. 17.5 - Prob. 3PECh. 17.6 - Prob. 1PECh. 17.6 - Prob. 1RCCh. 17.7 - Prob. 1PECh. 17.7 - Prob. 1RCCh. 17 - Prob. 17.1QPCh. 17 - Prob. 17.2QPCh. 17 - Prob. 17.3QPCh. 17 - 17.4 The pKbs for the bases X−, Y−, and Z− are...Ch. 17 - 17.5 Specify which of these systems can be...Ch. 17 - 17.6 Specify which of these systems can be...Ch. 17 - 17.7 The pH of a bicarbonate–carbonic acid buffer...Ch. 17 - Prob. 17.8QPCh. 17 - 17.9 Calculate the pH of the buffer system 0.15 M...Ch. 17 - 17.10 What is the pH of the buffer 0.10 M...Ch. 17 - 17.11 The pH of a sodium acetate–acetic acid...Ch. 17 - 17.12 The pH of blood plasma is 7.40. Assuming the...Ch. 17 - Prob. 17.13QPCh. 17 - Prob. 17.14QPCh. 17 - 17.16 A student wishes to prepare a buffer...Ch. 17 - Prob. 17.17QPCh. 17 - Prob. 17.18QPCh. 17 - Prob. 17.19QPCh. 17 - 17.20 A 5.00-g quantity of a diprotic acid is...Ch. 17 - Prob. 17.21QPCh. 17 - Prob. 17.22QPCh. 17 - 17.23 The diagrams shown here represent solutions...Ch. 17 - 16.38 The diagrams shown here represent solutions...Ch. 17 - 17.25 Explain how an acid-base indicator works in...Ch. 17 - 17.26 What are the criteria for choosing an...Ch. 17 - 17.27 The amount of indicator used in an acid-base...Ch. 17 - 17.28 A student carried out an acid-base titration...Ch. 17 - 17.29 Referring to Table 17.1, specify which...Ch. 17 - 17.30 The ionization constant Ka of an indicator...Ch. 17 - 17.31 Define solubility, molar solubility, and...Ch. 17 - 17.32 Why do we usually not quote the Ksp values...Ch. 17 - 17.33 Write balanced equations and solubility...Ch. 17 - Prob. 17.34QPCh. 17 - Prob. 17.35QPCh. 17 - 17.36 Silver chloride has a larger Ksp than silver...Ch. 17 - Prob. 17.38QPCh. 17 - 17.39 The molar solubility of MnCO3 is 4.2 × 10−6...Ch. 17 - Prob. 17.40QPCh. 17 - Prob. 17.41QPCh. 17 - 17.42 Using data from Table 17.2, calculate the...Ch. 17 - 17.43 What is the pH of a saturated zinc hydroxide...Ch. 17 - 17.44 The pH of a saturated solution of a metal...Ch. 17 - Prob. 17.45QPCh. 17 - 17.46 A volume of 75 mL of 0.060 M NaF is mixed...Ch. 17 - 17.47 How does a common ion affect solubility? Use...Ch. 17 - Prob. 17.48QPCh. 17 - Prob. 17.49QPCh. 17 - Prob. 17.50QPCh. 17 - Prob. 17.51QPCh. 17 - 17.52 Calculate the molar solubility of BaSO4 (a)...Ch. 17 - Prob. 17.55QPCh. 17 - Prob. 17.56QPCh. 17 - 17.57 If 2.50 g of CuSO4 are dissolved in 9.0 ×...Ch. 17 - 17.58 Calculate the concentrations of Cd2+, , and...Ch. 17 - Prob. 17.59QPCh. 17 - Prob. 17.60QPCh. 17 - Prob. 17.61QPCh. 17 - Prob. 17.62QPCh. 17 - Prob. 17.63QPCh. 17 - 16.88 In a group 1 analysis, a student adds HCl...Ch. 17 - 17.65 Both KCl and NH4Cl are white solids. Suggest...Ch. 17 - 17.66 Describe a simple test that would enable you...Ch. 17 - Prob. 17.67QPCh. 17 - Prob. 17.68QPCh. 17 - Prob. 17.69QPCh. 17 - 17.70 The pKa of the indicator methyl orange is...Ch. 17 - Prob. 17.71QPCh. 17 - Prob. 17.72QPCh. 17 - 17.73 The two curves shown here represent the...Ch. 17 - 17.74 The two curves shown here represent the...Ch. 17 - Prob. 17.75QPCh. 17 - 17.76 A solution is made by mixing exactly 500 mL...Ch. 17 - Prob. 17.77QPCh. 17 - Prob. 17.78QPCh. 17 - 17.79 For which of these reactions is the...Ch. 17 - Prob. 17.80QPCh. 17 - Prob. 17.81QPCh. 17 - Prob. 17.82QPCh. 17 - Prob. 17.83QPCh. 17 - 17.84 Find the approximate pH range suitable for...Ch. 17 - Prob. 17.85QPCh. 17 - 17.86 Which of these substances will be more...Ch. 17 - Prob. 17.87QPCh. 17 - Prob. 17.88QPCh. 17 - Prob. 17.89QPCh. 17 - Prob. 17.90QPCh. 17 - Prob. 17.91QPCh. 17 - 17.92 When a KI solution was added to a solution...Ch. 17 - Prob. 17.93QPCh. 17 - Prob. 17.94QPCh. 17 - Prob. 17.95QPCh. 17 - 17.96 Solid NaI is slowly added to a solution that...Ch. 17 - Prob. 17.97QPCh. 17 - 17.98 (a) Assuming complete dissociation and no...Ch. 17 - 17.99 Acid-base reactions usually go to...Ch. 17 - 17.100 Calculate x, the number of molecules of...Ch. 17 - Prob. 17.101QPCh. 17 - 17.102 What reagents would you employ to separate...Ch. 17 - 17.103 CaSO4 (Ksp = 2.4 × 10−5) has a larger Ksp...Ch. 17 - 17.104 How many milliliters of 1.0 M NaOH must be...Ch. 17 - Prob. 17.105QPCh. 17 - Prob. 17.106QPCh. 17 - Prob. 17.107QPCh. 17 - Prob. 17.108QPCh. 17 - Prob. 17.109QPCh. 17 - Prob. 17.111SPCh. 17 - Prob. 17.112SPCh. 17 - Prob. 17.113SPCh. 17 - Prob. 17.114SPCh. 17 - Prob. 17.115SPCh. 17 - Prob. 17.116SPCh. 17 - 17.117 The titration curve shown here represents...Ch. 17 - Prob. 17.118SP
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