Chemistry: The Science in Context (Fifth Edition)
Chemistry: The Science in Context (Fifth Edition)
5th Edition
ISBN: 9780393615159
Author: Stacey Lowery Bretz, Geoffrey Davies, Natalie Foster, Thomas R. Gilbert, Rein V. Kirss
Publisher: W. W. Norton & Company
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Chapter 17, Problem 17.20QP

(a)

Interpretation Introduction

Interpretation: The given processes that would not result in entropy increase for the indicated system are to be identified.

Concept introduction: Entropy is a thermodynamic property which shows the randomness or disorder of the atoms within the system.

ΔSsys is known as the entropy change for a system

The entropy is maximum in the gas phase and minimum in the solid phase.

To determine: The process of melting of an ice cube that would not result in an entropy increase for the indicated system.

(b)

Interpretation Introduction

To determine: The process of evaporation of a sample of an alcohol that would not result in an entropy increase for the indicated system.

(c)

Interpretation Introduction

To determine: The process of sublimation of a mothball would not result in an entropy increase for the indicated system.

(d)

Interpretation Introduction

To determine: The process of cooling hot water to room temperature would not result in an entropy increase for the indicated system.

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LTS Solid: AT=Te-Ti Trial 1 Trial 2 Trial 3 Average ΔΗ Mass water, g 24.096 23.976 23.975 Moles of solid, mol 0.01763 001767 0101781 Temp. change, °C 2.9°C 11700 2.0°C Heat of reaction, J -292.37J -170.473 -193.26J AH, kJ/mole 16.58K 9.647 kJ 10.85 kr 16.58K59.64701 KJ mol 12.35k Minimum AS, J/mol K 41.582 mol-k Remember: q = mCsAT (m = mass of water, Cs=4.184J/g°C) & qsin =-qrxn & Show your calculations for: AH in J and then in kJ/mole for Trial 1: qa (24.0969)(4.1845/g) (-2.9°C)=-292.37J qsin = qrxn = 292.35 292.37J AH in J = 292.375 0.2923kJ 0.01763m01 =1.65×107 AH in kJ/mol = = 16.58K 0.01763mol mol qrx Minimum AS in J/mol K (Hint: use the average initial temperature of the three trials, con Kelvin.) AS=AHIT (1.65×10(9.64×103) + (1.0 Jimai
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Chapter 17 Solutions

Chemistry: The Science in Context (Fifth Edition)

Ch. 17 - Prob. 17.3VPCh. 17 - Prob. 17.4VPCh. 17 - Prob. 17.5VPCh. 17 - Prob. 17.6VPCh. 17 - Prob. 17.7VPCh. 17 - Prob. 17.8VPCh. 17 - Prob. 17.9QPCh. 17 - Prob. 17.10QPCh. 17 - Prob. 17.11QPCh. 17 - Prob. 17.12QPCh. 17 - Prob. 17.13QPCh. 17 - Prob. 17.14QPCh. 17 - Prob. 17.15QPCh. 17 - Prob. 17.16QPCh. 17 - Prob. 17.17QPCh. 17 - Prob. 17.18QPCh. 17 - Prob. 17.19QPCh. 17 - Prob. 17.20QPCh. 17 - Prob. 17.21QPCh. 17 - Prob. 17.22QPCh. 17 - Prob. 17.23QPCh. 17 - Prob. 17.24QPCh. 17 - Prob. 17.25QPCh. 17 - Prob. 17.26QPCh. 17 - Prob. 17.27QPCh. 17 - Prob. 17.28QPCh. 17 - Prob. 17.29QPCh. 17 - Prob. 17.30QPCh. 17 - Prob. 17.31QPCh. 17 - Prob. 17.32QPCh. 17 - Prob. 17.33QPCh. 17 - Prob. 17.34QPCh. 17 - Prob. 17.35QPCh. 17 - Prob. 17.36QPCh. 17 - Prob. 17.37QPCh. 17 - Prob. 17.38QPCh. 17 - Prob. 17.39QPCh. 17 - Prob. 17.40QPCh. 17 - Prob. 17.41QPCh. 17 - Prob. 17.42QPCh. 17 - Prob. 17.43QPCh. 17 - Prob. 17.44QPCh. 17 - Prob. 17.45QPCh. 17 - Prob. 17.46QPCh. 17 - Prob. 17.47QPCh. 17 - Prob. 17.48QPCh. 17 - Prob. 17.49QPCh. 17 - Prob. 17.50QPCh. 17 - Prob. 17.51QPCh. 17 - Prob. 17.52QPCh. 17 - Prob. 17.53QPCh. 17 - Prob. 17.54QPCh. 17 - Prob. 17.55QPCh. 17 - Prob. 17.56QPCh. 17 - Prob. 17.57QPCh. 17 - Prob. 17.58QPCh. 17 - Prob. 17.59QPCh. 17 - Prob. 17.60QPCh. 17 - Prob. 17.61QPCh. 17 - Prob. 17.62QPCh. 17 - Prob. 17.63QPCh. 17 - Prob. 17.64QPCh. 17 - Prob. 17.65QPCh. 17 - Prob. 17.66QPCh. 17 - Prob. 17.67QPCh. 17 - Prob. 17.68QPCh. 17 - Prob. 17.69QPCh. 17 - Prob. 17.70QPCh. 17 - Prob. 17.71QPCh. 17 - Prob. 17.72QPCh. 17 - Prob. 17.73QPCh. 17 - Prob. 17.74QPCh. 17 - Prob. 17.75QPCh. 17 - Prob. 17.76QPCh. 17 - Prob. 17.77QPCh. 17 - Prob. 17.78QPCh. 17 - Prob. 17.79QPCh. 17 - Prob. 17.80QPCh. 17 - Prob. 17.81QPCh. 17 - Prob. 17.82QPCh. 17 - Prob. 17.83QPCh. 17 - Prob. 17.84QPCh. 17 - Prob. 17.85QPCh. 17 - Prob. 17.86QPCh. 17 - Prob. 17.87QPCh. 17 - Prob. 17.88APCh. 17 - Prob. 17.89APCh. 17 - Prob. 17.90APCh. 17 - Prob. 17.91APCh. 17 - Prob. 17.92APCh. 17 - Prob. 17.93APCh. 17 - Prob. 17.94APCh. 17 - Prob. 17.95APCh. 17 - Prob. 17.96APCh. 17 - Prob. 17.97APCh. 17 - Prob. 17.98APCh. 17 - Prob. 17.99APCh. 17 - Prob. 17.100APCh. 17 - Prob. 17.101APCh. 17 - Prob. 17.102APCh. 17 - Prob. 17.103APCh. 17 - Prob. 17.104APCh. 17 - Prob. 17.105AP
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