Introductory Chemistry: An Active Learning Approach
6th Edition
ISBN: 9781305545014
Author: CRACOLICE
Publisher: Cengage
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Chapter 17, Problem 17.1TC
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Draw the stepwise mechanism for the reactions
Part I.
a)
Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone
b) Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone
(3,3-dimethyl-2-butanone) and 2, 3-dimethyl - 1,3-butadiene. Give reasonable mechanism
the formation of
the products
For
3. The explosive decomposition of 2 mole of TNT (2,4,6-trinitrotoluene) is shown below:
Assume the C(s) is soot-basically atomic carbon (although it isn't actually atomic carbon in real life).
2
CH3
H
NO2
NO2
3N2 (g)+7CO (g) + 5H₂O (g) + 7C (s)
H
a. Use bond dissociation energies to calculate how much AU is for this reaction in kJ/mol.
Chapter 17 Solutions
Introductory Chemistry: An Active Learning Approach
Ch. 17 - Prob. 1ECh. 17 - Prob. 2ECh. 17 - Prob. 3ECh. 17 - a Write a net ionic equation to show that...Ch. 17 - Prob. 5ECh. 17 - Classify each of the following substances into the...Ch. 17 - Prob. 7ECh. 17 - Aluminum chloride, AlCl3, behaves more as a...Ch. 17 - Prob. 9ECh. 17 - Prob. 10E
Ch. 17 - Prob. 11ECh. 17 - Prob. 12ECh. 17 - Prob. 13ECh. 17 - In the following net ionic reaction, identify each...Ch. 17 - Prob. 15ECh. 17 - Prob. 16ECh. 17 - Prob. 17ECh. 17 - Prob. 18ECh. 17 - Prob. 19ECh. 17 - Prob. 20ECh. 17 - Prob. 21ECh. 17 - Prob. 22ECh. 17 - List the following bases in order of their...Ch. 17 - Prob. 24ECh. 17 - Prob. 25ECh. 17 - Prob. 26ECh. 17 - Prob. 27ECh. 17 - Prob. 28ECh. 17 - Prob. 29ECh. 17 - Prob. 30ECh. 17 - Prob. 31ECh. 17 - Prob. 32ECh. 17 - Prob. 33ECh. 17 - Prob. 34ECh. 17 - Prob. 35ECh. 17 - Prob. 36ECh. 17 - Prob. 37ECh. 17 - Prob. 38ECh. 17 - Prob. 39ECh. 17 - Prob. 40ECh. 17 - Prob. 41ECh. 17 - Prob. 42ECh. 17 - Prob. 43ECh. 17 - Prob. 44ECh. 17 - If the pH of a solution is 8.6, is the solution...Ch. 17 - Prob. 46ECh. 17 - Prob. 47ECh. 17 - Prob. 48ECh. 17 - Prob. 49ECh. 17 - Prob. 50ECh. 17 - Prob. 51ECh. 17 - Prob. 52ECh. 17 - Prob. 53ECh. 17 - Prob. 54ECh. 17 - Prob. 55ECh. 17 - Prob. 56ECh. 17 - Prob. 57ECh. 17 - Prob. 58ECh. 17 - Prob. 59ECh. 17 - Prob. 60ECh. 17 - Prob. 61ECh. 17 - Prob. 62ECh. 17 - Prob. 63ECh. 17 - Classify each of the following statements as true...Ch. 17 - Prob. 65ECh. 17 - Explain what amphoteric means. Give an example of...Ch. 17 - Prob. 67ECh. 17 - Prob. 68ECh. 17 - Prob. 69ECh. 17 - Prob. 70ECh. 17 - Prob. 71ECh. 17 - Prob. 72ECh. 17 - Prob. 73ECh. 17 - Prob. 74ECh. 17 - Prob. 75ECh. 17 - Prob. 76ECh. 17 - According to the Arrhenius theory of acids and...Ch. 17 - Prob. 17.2TCCh. 17 - Prob. 17.3TCCh. 17 - Prob. 17.4TCCh. 17 - Write a brief description of the relationships...Ch. 17 - Prob. 2CLECh. 17 - Prob. 3CLECh. 17 - Prob. 4CLECh. 17 - Write a brief description of the relationships...Ch. 17 - Prob. 6CLECh. 17 - Prob. 7CLECh. 17 - Prob. 8CLECh. 17 - Prob. 9CLECh. 17 - Prob. 10CLECh. 17 - Prob. 11CLECh. 17 - Prob. 1PECh. 17 - Prob. 2PECh. 17 - Prob. 3PECh. 17 - Prob. 4PECh. 17 - Write the net ionic equation for the reaction...Ch. 17 - Prob. 6PECh. 17 - Prob. 7PECh. 17 - Prob. 8PECh. 17 - Prob. 9PECh. 17 - Prob. 10PECh. 17 - Prob. 11PECh. 17 - Prob. 12PECh. 17 - Prob. 13PECh. 17 - Prob. 14PECh. 17 - What are the pOH, hydroxide ion concentration, and...
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- Part I. Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff: Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone and (3,3-dimethyl-2-butanone) 2,3-dimethyl-1,3-butadiene. Give reasonable mechanism the formation of the products Forarrow_forwardShow the mechanism for these reactionsarrow_forwardDraw the stepwise mechanismarrow_forward
- Draw a structural formula of the principal product formed when benzonitrile is treated with each reagent. (a) H₂O (one equivalent), H₂SO₄, heat (b) H₂O (excess), H₂SO₄, heat (c) NaOH, H₂O, heat (d) LiAlH4, then H₂Oarrow_forwardDraw the stepwise mechanism for the reactionsarrow_forwardDraw stepwise mechanismarrow_forward
- Part I. Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff: a) Give the major reason for the exposure of benzophenone al isopropyl alcohol (w/acid) to direct sunlight of pina colone Mechanism For b) Pinacol (2,3-dimethy 1, 1-3-butanediol) on treatment w/ acid gives a mixture (3,3-dimethyl-2-butanone) and 2, 3-dimethyl-1,3-butadiene. Give reasonable the formation of the productsarrow_forwardwhat are the Iupac names for each structurearrow_forwardWhat are the IUPAC Names of all the compounds in the picture?arrow_forward
- 1) a) Give the dominant Intermolecular Force (IMF) in a sample of each of the following compounds. Please show your work. (8) SF2, CH,OH, C₂H₂ b) Based on your answers given above, list the compounds in order of their Boiling Point from low to high. (8)arrow_forward19.78 Write the products of the following sequences of reactions. Refer to your reaction road- maps to see how the combined reactions allow you to "navigate" between the different functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18 roadmaps along with your new Chapter 19 roadmap for these. (a) 1. BHS 2. H₂O₂ 3. H₂CrO4 4. SOCI₂ (b) 1. Cl₂/hv 2. KOLBU 3. H₂O, catalytic H₂SO4 4. H₂CrO4 Reaction Roadmap An alkene 5. EtOH 6.0.5 Equiv. NaOEt/EtOH 7. Mild H₂O An alkane 1.0 2. (CH3)₂S 3. H₂CrO (d) (c) 4. Excess EtOH, catalytic H₂SO OH 4. Mild H₂O* 5.0.5 Equiv. NaOEt/EtOH An alkene 6. Mild H₂O* A carboxylic acid 7. Mild H₂O* 1. SOC₁₂ 2. EtOH 3.0.5 Equiv. NaOEt/E:OH 5.1.0 Equiv. NaOEt 6. NH₂ (e) 1. 0.5 Equiv. NaOEt/EtOH 2. Mild H₂O* Br (f) i H An aldehyde 1. Catalytic NaOE/EtOH 2. H₂O*, heat 3. (CH,CH₂)₂Culi 4. Mild H₂O* 5.1.0 Equiv. LDA Br An ester 4. NaOH, H₂O 5. Mild H₂O* 6. Heat 7. MgBr 8. Mild H₂O* 7. Mild H₂O+arrow_forwardLi+ is a hard acid. With this in mind, which if the following compounds should be most soluble in water? Group of answer choices LiBr LiI LiF LiClarrow_forward
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