CHEM:ATOM FOC 2E CL (TEXT)
2nd Edition
ISBN: 9780393284218
Author: Stacey Lowery Bretz, Natalie Foster, Thomas R. Gilbert, Rein V. Kirss
Publisher: WW Norton & Co
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PQ-10. What is the major product of this reaction?
(A)
(C)
930
Me
HO
O=S=O
O-8-CF,
C
어
Me
H+
OH
270
O
0-5-0
O=S=O
O-S-CF
CF3
2
Predict the major organic product(s) of the following reactions. Include stereochemistry when necessary. Write NR if no reaction, try to explain.
Q2: Explain why epoxides that react in an SN1 manner will not show any stereochemical
inversion in the product.
Q3: Rationalize why Alcohol B will react under the indicated reaction conditions, but Alcohol A
will not.
A
☑
OH
B
OH
PBr3
R-Br
Chapter 17 Solutions
CHEM:ATOM FOC 2E CL (TEXT)
Ch. 17 - Prob. 17.1VPCh. 17 - Prob. 17.2VPCh. 17 - Prob. 17.3VPCh. 17 - Prob. 17.4VPCh. 17 - Prob. 17.5VPCh. 17 - Prob. 17.6VPCh. 17 - Prob. 17.7VPCh. 17 - Prob. 17.8VPCh. 17 - Prob. 17.9VPCh. 17 - Prob. 17.10VP
Ch. 17 - Prob. 17.11QACh. 17 - Prob. 17.12QACh. 17 - Prob. 17.13QACh. 17 - Prob. 17.14QACh. 17 - Prob. 17.15QACh. 17 - Prob. 17.16QACh. 17 - Prob. 17.17QACh. 17 - Prob. 17.18QACh. 17 - Prob. 17.19QACh. 17 - Prob. 17.20QACh. 17 - Prob. 17.21QACh. 17 - Prob. 17.22QACh. 17 - Prob. 17.23QACh. 17 - Prob. 17.24QACh. 17 - Prob. 17.25QACh. 17 - Prob. 17.26QACh. 17 - Prob. 17.27QACh. 17 - Prob. 17.28QACh. 17 - Prob. 17.29QACh. 17 - Prob. 17.30QACh. 17 - Prob. 17.31QACh. 17 - Prob. 17.32QACh. 17 - Prob. 17.33QACh. 17 - Prob. 17.34QACh. 17 - Prob. 17.35QACh. 17 - Prob. 17.36QACh. 17 - Prob. 17.37QACh. 17 - Prob. 17.38QACh. 17 - Prob. 17.39QACh. 17 - Prob. 17.40QACh. 17 - Prob. 17.41QACh. 17 - Prob. 17.42QACh. 17 - Prob. 17.43QACh. 17 - Prob. 17.44QACh. 17 - Prob. 17.45QACh. 17 - Prob. 17.46QACh. 17 - Prob. 17.47QACh. 17 - Prob. 17.48QACh. 17 - Prob. 17.49QACh. 17 - Prob. 17.50QACh. 17 - Prob. 17.51QACh. 17 - Prob. 17.52QACh. 17 - Prob. 17.53QACh. 17 - Prob. 17.54QACh. 17 - Prob. 17.55QACh. 17 - Prob. 17.56QACh. 17 - Prob. 17.57QACh. 17 - Prob. 17.58QACh. 17 - Prob. 17.59QACh. 17 - Prob. 17.60QACh. 17 - Prob. 17.61QACh. 17 - Prob. 17.62QACh. 17 - Prob. 17.63QACh. 17 - Prob. 17.64QACh. 17 - Prob. 17.65QACh. 17 - Prob. 17.66QACh. 17 - Prob. 17.67QACh. 17 - Prob. 17.68QACh. 17 - Prob. 17.69QACh. 17 - Prob. 17.70QACh. 17 - Prob. 17.71QACh. 17 - Prob. 17.72QACh. 17 - Prob. 17.73QACh. 17 - Prob. 17.74QACh. 17 - Prob. 17.75QACh. 17 - Prob. 17.76QACh. 17 - Prob. 17.77QACh. 17 - Prob. 17.78QACh. 17 - Prob. 17.79QACh. 17 - Prob. 17.80QACh. 17 - Prob. 17.81QACh. 17 - Prob. 17.82QACh. 17 - Prob. 17.83QACh. 17 - Prob. 17.84QACh. 17 - Prob. 17.85QACh. 17 - Prob. 17.86QACh. 17 - Prob. 17.87QACh. 17 - Prob. 17.88QACh. 17 - Prob. 17.89QACh. 17 - Prob. 17.90QACh. 17 - Prob. 17.91QACh. 17 - Prob. 17.92QACh. 17 - Prob. 17.93QACh. 17 - Prob. 17.94QACh. 17 - Prob. 17.95QACh. 17 - Prob. 17.96QACh. 17 - Prob. 17.97QACh. 17 - Prob. 17.98QACh. 17 - Prob. 17.99QACh. 17 - Prob. 17.100QACh. 17 - Prob. 17.101QACh. 17 - Prob. 17.102QA
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- Q1: Predict the major organic product(s) of the following reactions. Include stereochemistry when necessary. Write NR if no reaction, try to explain. 1.) LDA, THF 2.) СОН CI OH H2SO4, heat OH m...... OH 1.) PCC, CH2Cl2 2.) CH3CH2MgBr, THF 3.) H3O+ 4.) TsCl, pyr 5.) tBuOK, tBuOH 1.) SOCI 2, CHCI 3 2.) CH3CH2ONA, DMF OH 1.) HBr 2.) Mg, THF 3.) H₂CO, THE 4.) H3O+ OH NaH, THFarrow_forwardWhat is the stepwise mechanism for this reaction?arrow_forwardDraw the major product of this reactionarrow_forward
- Please provide the IUPAC name for the compound shown herearrow_forwardProblem 6-29 Identify the functional groups in the following molecules, and show the polarity of each: (a) CH3CH2C=N CH, CH, COCH (c) CH3CCH2COCH3 NH2 (e) OCH3 (b) (d) O Problem 6-30 Identify the following reactions as additions, eliminations, substitutions, or rearrangements: (a) CH3CH2Br + NaCN CH3CH2CN ( + NaBr) Acid -OH (+ H2O) catalyst (b) + (c) Heat NO2 Light + 02N-NO2 (+ HNO2) (d)arrow_forwardPredict the organic product of Y that is formed in the reaction below, and draw the skeletal ("line") structures of the missing organic product. Please include all steps & drawings & explanations.arrow_forward
- Please choose the best reagents to complete the following reactionarrow_forwardProblem 6-17 Look at the following energy diagram: Energy Reaction progress (a) Is AG for the reaction positive or negative? Label it on the diagram. (b) How many steps are involved in the reaction? (c) How many transition states are there? Label them on the diagram. Problem 6-19 What is the difference between a transition state and an intermediate? Problem 6-21 Draw an energy diagram for a two-step reaction with Keq > 1. Label the overall AG°, transition states, and intermediate. Is AG° positive or negative? Problem 6-23 Draw an energy diagram for a reaction with Keq = 1. What is the value of AG° in this reaction?arrow_forwardProblem 6-37 Draw the different monochlorinated constitutional isomers you would obtain by the radical chlorination of the following compounds. (b) (c) Problem 6-39 Show the structure of the carbocation that would result when each of the following alkenes reacts with an acid, H+. (a) (b) (c)arrow_forward
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