(a) Interpretation: The net ionic equation needs to be determined and balanced in the acidic medium. Concept introduction: The rules to balance redox reactions in basic medium are as follows: Determine the oxidation numbers of the elements and write the oxidation and reduction half equation. Balance the atoms of elements other than H and O atoms. Use H 2 O to balance the number of O atoms, H+ to balance the number of H atoms and the electrons for charge balance. Equalize the number of electrons on both the half reactions and then add the half reactions.

Question

Which compound(s) will be fully deprotonated (>99%) by reaction with one molar equivalent of sodium hydroxide? I, II, III I, || I, III I only II, III SH | H3C-C=C-H || III NH2

Answer 1

Question

Chapter 17, Problem 10QAP

Interpretation Introduction

(a)

Interpretation:

The net ionic equation needs to be determined and balanced in the acidic medium.

Concept introduction:

The rules to balance redox reactions in basic medium are as follows:

Determine the oxidation numbers of the elements and write the oxidation and reduction half equation.

Balance the atoms of elements other than H and O atoms. Use H₂ O to balance the number of O atoms, H+ to balance the number of H atoms and the electrons for charge balance. Equalize the number of electrons on both the half reactions and then add the half reactions.

Interpretation Introduction

(b)

Interpretation:

The net ionic equation needs to be determined and balanced in the acidic medium.

Concept introduction:

The rules to balance redox reactions in basic medium are as follows:

Determine the oxidation numbers of the elements and write the oxidation and reduction half equation.

Balance the atoms of elements other than H and O atoms. Use H₂ O to balance the number of O atoms, H+ to balance the number of H atoms and the electrons for charge balance. Equalize the number of electrons on both the half reactions and then add the half reactions.

Interpretation Introduction

(c)

Interpretation:

The net ionic equation needs to be determined and balanced in the acidic medium.

Concept introduction:

The rules to balance redox reactions in basic medium are as follows:

Determine the oxidation numbers of the elements and write the oxidation and reduction half equation.

Balance the atoms of elements other than H and O atoms. Use H₂ O to balance the number of O atoms, H+ to balance the number of H atoms and the electrons for charge balance. Equalize the number of electrons on both the half reactions and then add the half reactions.

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Which compound(s) will be fully deprotonated (>99%) by reaction with one molar equivalent of sodium hydroxide? I, II, III I, || I, III I only II, III SH | H3C-C=C-H || III NH2

Will NBS (and heat or light) work for this reaction, or do we have to use Br2?

HAND DRAW

Answer 2

Question

Chapter 17, Problem 10QAP

Interpretation Introduction

(a)

Interpretation:

The net ionic equation needs to be determined and balanced in the acidic medium.

Concept introduction:

The rules to balance redox reactions in basic medium are as follows:

Determine the oxidation numbers of the elements and write the oxidation and reduction half equation.

Balance the atoms of elements other than H and O atoms. Use H₂ O to balance the number of O atoms, H+ to balance the number of H atoms and the electrons for charge balance. Equalize the number of electrons on both the half reactions and then add the half reactions.

Interpretation Introduction

(b)

Interpretation:

The net ionic equation needs to be determined and balanced in the acidic medium.

Concept introduction:

The rules to balance redox reactions in basic medium are as follows:

Determine the oxidation numbers of the elements and write the oxidation and reduction half equation.

Balance the atoms of elements other than H and O atoms. Use H₂ O to balance the number of O atoms, H+ to balance the number of H atoms and the electrons for charge balance. Equalize the number of electrons on both the half reactions and then add the half reactions.

Interpretation Introduction

(c)

Interpretation:

The net ionic equation needs to be determined and balanced in the acidic medium.

Concept introduction:

The rules to balance redox reactions in basic medium are as follows:

Determine the oxidation numbers of the elements and write the oxidation and reduction half equation.

Balance the atoms of elements other than H and O atoms. Use H₂ O to balance the number of O atoms, H+ to balance the number of H atoms and the electrons for charge balance. Equalize the number of electrons on both the half reactions and then add the half reactions.

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Answer 3

Question

Chapter 17, Problem 10QAP

Interpretation Introduction

(a)

Interpretation:

The net ionic equation needs to be determined and balanced in the acidic medium.

Concept introduction:

The rules to balance redox reactions in basic medium are as follows:

Determine the oxidation numbers of the elements and write the oxidation and reduction half equation.

Balance the atoms of elements other than H and O atoms. Use H₂ O to balance the number of O atoms, H+ to balance the number of H atoms and the electrons for charge balance. Equalize the number of electrons on both the half reactions and then add the half reactions.

Interpretation Introduction

(b)

Interpretation:

The net ionic equation needs to be determined and balanced in the acidic medium.

Concept introduction:

The rules to balance redox reactions in basic medium are as follows:

Determine the oxidation numbers of the elements and write the oxidation and reduction half equation.

Balance the atoms of elements other than H and O atoms. Use H₂ O to balance the number of O atoms, H+ to balance the number of H atoms and the electrons for charge balance. Equalize the number of electrons on both the half reactions and then add the half reactions.

Interpretation Introduction

(c)

Interpretation:

The net ionic equation needs to be determined and balanced in the acidic medium.

Concept introduction:

The rules to balance redox reactions in basic medium are as follows:

Determine the oxidation numbers of the elements and write the oxidation and reduction half equation.

Balance the atoms of elements other than H and O atoms. Use H₂ O to balance the number of O atoms, H+ to balance the number of H atoms and the electrons for charge balance. Equalize the number of electrons on both the half reactions and then add the half reactions.

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Answer 4

Question

Chapter 17, Problem 10QAP

Interpretation Introduction

(a)

Interpretation:

The net ionic equation needs to be determined and balanced in the acidic medium.

Concept introduction:

The rules to balance redox reactions in basic medium are as follows:

Determine the oxidation numbers of the elements and write the oxidation and reduction half equation.

Balance the atoms of elements other than H and O atoms. Use H₂ O to balance the number of O atoms, H+ to balance the number of H atoms and the electrons for charge balance. Equalize the number of electrons on both the half reactions and then add the half reactions.

Interpretation Introduction

(b)

Interpretation:

The net ionic equation needs to be determined and balanced in the acidic medium.

Concept introduction:

The rules to balance redox reactions in basic medium are as follows:

Determine the oxidation numbers of the elements and write the oxidation and reduction half equation.

Balance the atoms of elements other than H and O atoms. Use H₂ O to balance the number of O atoms, H+ to balance the number of H atoms and the electrons for charge balance. Equalize the number of electrons on both the half reactions and then add the half reactions.

Interpretation Introduction

(c)

Interpretation:

The net ionic equation needs to be determined and balanced in the acidic medium.

Concept introduction:

The rules to balance redox reactions in basic medium are as follows:

Determine the oxidation numbers of the elements and write the oxidation and reduction half equation.

Balance the atoms of elements other than H and O atoms. Use H₂ O to balance the number of O atoms, H+ to balance the number of H atoms and the electrons for charge balance. Equalize the number of electrons on both the half reactions and then add the half reactions.

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Answer 5

Chapter 17, Problem 10QAP

Interpretation Introduction

(a)

Interpretation:

The net ionic equation needs to be determined and balanced in the acidic medium.

Concept introduction:

The rules to balance redox reactions in basic medium are as follows:

Determine the oxidation numbers of the elements and write the oxidation and reduction half equation.

Balance the atoms of elements other than H and O atoms. Use H₂ O to balance the number of O atoms, H+ to balance the number of H atoms and the electrons for charge balance. Equalize the number of electrons on both the half reactions and then add the half reactions.

Interpretation Introduction

(b)

Interpretation:

The net ionic equation needs to be determined and balanced in the acidic medium.

Concept introduction:

The rules to balance redox reactions in basic medium are as follows:

Determine the oxidation numbers of the elements and write the oxidation and reduction half equation.

Balance the atoms of elements other than H and O atoms. Use H₂ O to balance the number of O atoms, H+ to balance the number of H atoms and the electrons for charge balance. Equalize the number of electrons on both the half reactions and then add the half reactions.

Interpretation Introduction

(c)

Interpretation:

The net ionic equation needs to be determined and balanced in the acidic medium.

Concept introduction:

The rules to balance redox reactions in basic medium are as follows:

Determine the oxidation numbers of the elements and write the oxidation and reduction half equation.

Balance the atoms of elements other than H and O atoms. Use H₂ O to balance the number of O atoms, H+ to balance the number of H atoms and the electrons for charge balance. Equalize the number of electrons on both the half reactions and then add the half reactions.

Answer 6

Chapter 17, Problem 10QAP

Interpretation Introduction

(a)

Interpretation:

The net ionic equation needs to be determined and balanced in the acidic medium.

Concept introduction:

The rules to balance redox reactions in basic medium are as follows:

Determine the oxidation numbers of the elements and write the oxidation and reduction half equation.

Balance the atoms of elements other than H and O atoms. Use H₂ O to balance the number of O atoms, H+ to balance the number of H atoms and the electrons for charge balance. Equalize the number of electrons on both the half reactions and then add the half reactions.

Answer 7

Chapter 17, Problem 10QAP

Interpretation Introduction

(a)

Interpretation:

The net ionic equation needs to be determined and balanced in the acidic medium.

Concept introduction:

The rules to balance redox reactions in basic medium are as follows:

Determine the oxidation numbers of the elements and write the oxidation and reduction half equation.

Balance the atoms of elements other than H and O atoms. Use H₂ O to balance the number of O atoms, H+ to balance the number of H atoms and the electrons for charge balance. Equalize the number of electrons on both the half reactions and then add the half reactions.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The net ionic equation needs to be determined and balanced in the acidic medium.

Concept introduction:

The rules to balance redox reactions in basic medium are as follows:

Determine the oxidation numbers of the elements and write the oxidation and reduction half equation.

Balance the atoms of elements other than H and O atoms. Use H₂ O to balance the number of O atoms, H+ to balance the number of H atoms and the electrons for charge balance. Equalize the number of electrons on both the half reactions and then add the half reactions.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The net ionic equation needs to be determined and balanced in the acidic medium.

Concept introduction:

The rules to balance redox reactions in basic medium are as follows:

Determine the oxidation numbers of the elements and write the oxidation and reduction half equation.

Balance the atoms of elements other than H and O atoms. Use H₂ O to balance the number of O atoms, H+ to balance the number of H atoms and the electrons for charge balance. Equalize the number of electrons on both the half reactions and then add the half reactions.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The net ionic equation needs to be determined and balanced in the acidic medium.

Concept introduction:

The rules to balance redox reactions in basic medium are as follows:

Determine the oxidation numbers of the elements and write the oxidation and reduction half equation.

Balance the atoms of elements other than H and O atoms. Use H₂ O to balance the number of O atoms, H+ to balance the number of H atoms and the electrons for charge balance. Equalize the number of electrons on both the half reactions and then add the half reactions.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The net ionic equation needs to be determined and balanced in the acidic medium.

Concept introduction:

The rules to balance redox reactions in basic medium are as follows:

Determine the oxidation numbers of the elements and write the oxidation and reduction half equation.

Balance the atoms of elements other than H and O atoms. Use H₂ O to balance the number of O atoms, H+ to balance the number of H atoms and the electrons for charge balance. Equalize the number of electrons on both the half reactions and then add the half reactions.

Answer 12

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Answer 23

Ch. 17 - Balance the following half-equations. Balance (a)...Ch. 17 - Balance the following half-equations. Balance (a)...Ch. 17 - Prob. 3QAP Ch. 17 - Balance the following reactions in acid: (a)...Ch. 17 - Write balanced equations for the following...Ch. 17 - Write balanced equations for the following...Ch. 17 - Prob. 7QAP Ch. 17 - Write balanced net ionic equations for the...Ch. 17 - Write balanced net ionic equations for the...Ch. 17 - Prob. 10QAP

Solution Summary: The author explains how the net ionic equation must be determined and balanced in the acidic medium.

Chapter 17 Solutions