
Organic Chemistry
2nd Edition
ISBN: 9781118452288
Author: David R. Klein
Publisher: WILEY
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Question
Chapter 16.5, Problem 3LTS
Interpretation Introduction
Interpretation: For the given compounds the chemical shift of the signals to be predicted.
Concept Introduction:
Chemical shift: The frequency of the proton signal in the spectrum with reference to the standard compound which may be TMS(Tetramethylsilane) shows signal at 0 ppm(parts per million).
Bench mark values: The chemical shift values to remember for the protons below.
Methyl |
|
Methylene |
|
Methine |
|
Inductive effect: The presence of
FUNCTIONAL GROUP | EFFECT ON THE ALPHA PROTONS | EFFECT ON THE BETA PROTONS |
Oxygen of an alcohol or ether |
|
|
Oxygen of ester |
|
|
Carbonyl groups |
|
|
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Chapter 16 Solutions
Organic Chemistry
Ch. 16.4 - Prob. 1LTSCh. 16.4 - Prob. 1PTSCh. 16.4 - Prob. 2ATSCh. 16.4 - Prob. 3ATSCh. 16.4 - Prob. 2LTSCh. 16.4 - Prob. 4PTSCh. 16.4 - Prob. 5ATSCh. 16.4 - Prob. 6ATSCh. 16.5 - Prob. 3LTSCh. 16.5 - Prob. 7PTS
Ch. 16.5 - Prob. 8ATSCh. 16.5 - Prob. 9ATSCh. 16.5 - Prob. 10CCCh. 16.6 - Prob. 4LTSCh. 16.6 - Prob. 11PTSCh. 16.6 - Prob. 12PTSCh. 16.6 - Prob. 13PTSCh. 16.6 - Prob. 14ATSCh. 16.7 - Prob. 5LTSCh. 16.7 - Prob. 15PTSCh. 16.7 - Prob. 16ATSCh. 16.7 - Prob. 17CCCh. 16.7 - Prob. 18CCCh. 16.8 - Prob. 6LTSCh. 16.8 - Prob. 19PTSCh. 16.8 - Prob. 20ATSCh. 16.9 - Prob. 7LTSCh. 16.9 - Prob. 21PTSCh. 16.9 - Prob. 22ATSCh. 16.10 - Prob. 8LTSCh. 16.10 - Prob. 23PTSCh. 16.10 - Prob. 24ATSCh. 16.12 - Prob. 9LTSCh. 16.12 - Prob. 25PTSCh. 16.12 - Prob. 26ATSCh. 16.12 - Prob. 27ATSCh. 16.13 - Prob. 10LTSCh. 16.13 - Prob. 28PTSCh. 16.13 - Prob. 29PTSCh. 16.13 - Prob. 30ATSCh. 16 - Prob. 31PPCh. 16 - Prob. 32PPCh. 16 - Prob. 33PPCh. 16 - Prob. 34PPCh. 16 - Prob. 35PPCh. 16 - Prob. 36PPCh. 16 - Prob. 37PPCh. 16 - Prob. 38PPCh. 16 - Prob. 39PPCh. 16 - Prob. 40PPCh. 16 - Prob. 41PPCh. 16 - Prob. 42PPCh. 16 - Prob. 43PPCh. 16 - Prob. 44PPCh. 16 - Prob. 45PPCh. 16 - Prob. 46PPCh. 16 - Prob. 47PPCh. 16 - Prob. 48PPCh. 16 - Prob. 49PPCh. 16 - Prob. 50PPCh. 16 - Prob. 51PPCh. 16 - Prob. 52PPCh. 16 - Prob. 53PPCh. 16 - Prob. 54PPCh. 16 - Prob. 55PPCh. 16 - Prob. 56PPCh. 16 - Prob. 57PPCh. 16 - Prob. 58PPCh. 16 - Prob. 59PPCh. 16 - Prob. 60PPCh. 16 - Prob. 61PPCh. 16 - Prob. 62IPCh. 16 - Prob. 63IPCh. 16 - Prob. 64IPCh. 16 - Prob. 65IPCh. 16 - Prob. 66IPCh. 16 - Prob. 67IPCh. 16 - Prob. 68IPCh. 16 - Prob. 69IPCh. 16 - Prob. 70IPCh. 16 - Prob. 71IP
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