Haworth projection of alpha-D-galactose and beta-D-galactose has to be drawn. Concept Introduction: A structure that is drawn in a cyclic form is known as Haworth projection. This is used to represent the substituent orientation around cyclic sugar molecule. When drawing Haworth projection, the groups that are bonded to left to the carbon chain in Fischer projection is placed above the cyclic ring and the groups that are bonded to the right to the carbon chain are placed below the cyclic ring. In beta-D-Glucose, the hydroxyl group is placed above the ring and in alpha-D-Glucose, the hydroxyl group is placed below the ring.

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Answer 1

Question

Chapter 16.4, Problem 16.5PP

(a)

Interpretation Introduction

Interpretation:

Haworth projection of alpha-D-galactose and beta-D-galactose has to be drawn.

Concept Introduction:

A structure that is drawn in a cyclic form is known as Haworth projection. This is used to represent the substituent orientation around cyclic sugar molecule. When drawing Haworth projection, the groups that are bonded to left to the carbon chain in Fischer projection is placed above the cyclic ring and the groups that are bonded to the right to the carbon chain are placed below the cyclic ring.

In beta-D-Glucose, the hydroxyl group is placed above the ring and in alpha-D-Glucose, the hydroxyl group is placed below the ring.

(b)

Interpretation Introduction

Interpretation:

Haworth projection of alpha-D-ribose and beta-D-ribose has to be drawn.

Concept Introduction:

Refer part (a).

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Part II. Given two isomers: 2-methylpentane (A) and 2,2-dimethyl butane (B) answer the following: (a) match structures of isomers given their mass spectra below (spectra A and spectra B) (b) Draw the fragments given the following prominent peaks from each spectrum: Spectra A m/2 =43 and 1/2-57 spectra B m/2 = 43 (c) why is 1/2=57 peak in spectrum A more intense compared to the same peak in spectrum B. Relative abundance Relative abundance 100 A 50 29 29 0 10 -0 -0 100 B 50 720 30 41 43 57 71 4-0 40 50 60 70 m/z 43 57 8-0 m/z = 86 M 90 100 71 m/z = 86 M -O 0 10 20 30 40 50 60 70 80 -88 m/z 90 100

Part IV. C6H5 CH2CH2OH is an aromatic compound which was subjected to Electron Ionization - mass spectrometry (El-MS) analysis. Prominent m/2 values: m/2 = 104 and m/2 = 9) was obtained. Draw the structures of these fragments.

For each reaction shown below follow the curved arrows to complete each equationby showing the structure of the products. Identify the acid, the base, the conjugated acid andconjugated base. Consutl the pKa table and choose the direciton theequilibrium goes. However show the curved arrows. Please explain if possible.

Answer 2

Question

Chapter 16.4, Problem 16.5PP

(a)

Interpretation Introduction

Interpretation:

Haworth projection of alpha-D-galactose and beta-D-galactose has to be drawn.

Concept Introduction:

A structure that is drawn in a cyclic form is known as Haworth projection. This is used to represent the substituent orientation around cyclic sugar molecule. When drawing Haworth projection, the groups that are bonded to left to the carbon chain in Fischer projection is placed above the cyclic ring and the groups that are bonded to the right to the carbon chain are placed below the cyclic ring.

In beta-D-Glucose, the hydroxyl group is placed above the ring and in alpha-D-Glucose, the hydroxyl group is placed below the ring.

(b)

Interpretation Introduction

Interpretation:

Haworth projection of alpha-D-ribose and beta-D-ribose has to be drawn.

Concept Introduction:

Refer part (a).

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Answer 3

Question

Chapter 16.4, Problem 16.5PP

(a)

Interpretation Introduction

Interpretation:

Haworth projection of alpha-D-galactose and beta-D-galactose has to be drawn.

Concept Introduction:

A structure that is drawn in a cyclic form is known as Haworth projection. This is used to represent the substituent orientation around cyclic sugar molecule. When drawing Haworth projection, the groups that are bonded to left to the carbon chain in Fischer projection is placed above the cyclic ring and the groups that are bonded to the right to the carbon chain are placed below the cyclic ring.

In beta-D-Glucose, the hydroxyl group is placed above the ring and in alpha-D-Glucose, the hydroxyl group is placed below the ring.

(b)

Interpretation Introduction

Interpretation:

Haworth projection of alpha-D-ribose and beta-D-ribose has to be drawn.

Concept Introduction:

Refer part (a).

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Answer 4

Question

Chapter 16.4, Problem 16.5PP

(a)

Interpretation Introduction

Interpretation:

Haworth projection of alpha-D-galactose and beta-D-galactose has to be drawn.

Concept Introduction:

A structure that is drawn in a cyclic form is known as Haworth projection. This is used to represent the substituent orientation around cyclic sugar molecule. When drawing Haworth projection, the groups that are bonded to left to the carbon chain in Fischer projection is placed above the cyclic ring and the groups that are bonded to the right to the carbon chain are placed below the cyclic ring.

In beta-D-Glucose, the hydroxyl group is placed above the ring and in alpha-D-Glucose, the hydroxyl group is placed below the ring.

(b)

Interpretation Introduction

Interpretation:

Haworth projection of alpha-D-ribose and beta-D-ribose has to be drawn.

Concept Introduction:

Refer part (a).

Expert Solution & Answer

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Answer 5

Chapter 16.4, Problem 16.5PP

(a)

Interpretation Introduction

Interpretation:

Haworth projection of alpha-D-galactose and beta-D-galactose has to be drawn.

Concept Introduction:

A structure that is drawn in a cyclic form is known as Haworth projection. This is used to represent the substituent orientation around cyclic sugar molecule. When drawing Haworth projection, the groups that are bonded to left to the carbon chain in Fischer projection is placed above the cyclic ring and the groups that are bonded to the right to the carbon chain are placed below the cyclic ring.

In beta-D-Glucose, the hydroxyl group is placed above the ring and in alpha-D-Glucose, the hydroxyl group is placed below the ring.

(b)

Interpretation Introduction

Interpretation:

Haworth projection of alpha-D-ribose and beta-D-ribose has to be drawn.

Concept Introduction:

Refer part (a).

Answer 6

Chapter 16.4, Problem 16.5PP

(a)

Interpretation Introduction

Interpretation:

Haworth projection of alpha-D-galactose and beta-D-galactose has to be drawn.

Concept Introduction:

A structure that is drawn in a cyclic form is known as Haworth projection. This is used to represent the substituent orientation around cyclic sugar molecule. When drawing Haworth projection, the groups that are bonded to left to the carbon chain in Fischer projection is placed above the cyclic ring and the groups that are bonded to the right to the carbon chain are placed below the cyclic ring.

In beta-D-Glucose, the hydroxyl group is placed above the ring and in alpha-D-Glucose, the hydroxyl group is placed below the ring.

Answer 7

Chapter 16.4, Problem 16.5PP

(a)

Interpretation Introduction

Interpretation:

Haworth projection of alpha-D-galactose and beta-D-galactose has to be drawn.

Concept Introduction:

A structure that is drawn in a cyclic form is known as Haworth projection. This is used to represent the substituent orientation around cyclic sugar molecule. When drawing Haworth projection, the groups that are bonded to left to the carbon chain in Fischer projection is placed above the cyclic ring and the groups that are bonded to the right to the carbon chain are placed below the cyclic ring.

In beta-D-Glucose, the hydroxyl group is placed above the ring and in alpha-D-Glucose, the hydroxyl group is placed below the ring.

Answer 8

(b)

Interpretation Introduction

Interpretation:

Haworth projection of alpha-D-ribose and beta-D-ribose has to be drawn.

Concept Introduction:

Refer part (a).

Answer 9

(b)

Interpretation Introduction

Interpretation:

Haworth projection of alpha-D-ribose and beta-D-ribose has to be drawn.

Concept Introduction:

Refer part (a).

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 16.1 - What is the current recommendation for the amount...Ch. 16.1 - Prob. 16.2Q Ch. 16.2 - Prob. 16.3Q Ch. 16.2 - Prob. 16.4Q Ch. 16.3 - Prob. 16.1PP Ch. 16.3 - Prob. 16.2PP Ch. 16.3 - Prob. 16.3PP Ch. 16.3 - Prob. 16.5Q Ch. 16.3 - Prob. 16.6Q Ch. 16.3 - Prob. 16.7Q

Concept explainers

Interpretation:

Haworth projection of alpha-D-ribose and beta-D-ribose has to be drawn.

Concept Introduction:

Refer part (a).

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Chapter 16 Solutions

Concept explainers

Interpretation: Haworth projection of alpha-D-ribose and beta-D-ribose has to be drawn. Concept Introduction: Refer part (a).

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Chapter 16 Solutions

Interpretation:

Haworth projection of alpha-D-ribose and beta-D-ribose has to be drawn.

Concept Introduction:

Refer part (a).