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(a)
Interpretation:
The reason for the negative value of
Concept introduction:
Entropy is defined as degree of randomness in a system. It is due to the random motion of molecules in the reaction system. The entropy of a gaseous system is more than a liquid system as gaseous molecules are in constant motion. If number of gaseous molecules increases, entropy also increases.
(b)
Interpretation:
The reason for
Concept introduction:
Entropy is defined as degree of randomness in a system. It is due to the random motion of molecules in the reaction system. The entropy of a gaseous system is more than a liquid system as gaseous molecules are in constant motion. If temperature of a system is increased, the random movement of molecules of gases increases.
(c)
Interpretation:
The reason for a solid to have lower entropy than liquid needs to be explained.
Concept introduction:
Entropy is defined as degree of randomness in a system. It is due to the random motion of molecules in the reaction system. The entropy of a gaseous system is more than a liquid system as gaseous molecules are in constant motion.

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Chapter 16 Solutions
OWLv2 with Student Solutions Manual eBook for Masterton/Hurley's Chemistry: Principles and Reactions, 8th Edition, [Instant Access], 4 terms (24 months)
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- Could you crystallize one enantiomer of mandelic acid from a racemic mixture (using the typical achiral solvents found in our lab) without preparing a diastereomeric salt? Why or why not? No, because both enantiomers have the same solubility in achiral solvents. than the other. ооо Yes, because one enantiomer has a higher melting point No, because both enantiomers are liquids. Yes, because one enantiomer is more crystalline than the other.arrow_forwardIf the literature value of specific rotation for a chiral compound is -53.6°, what is the enantiomeric excess of a compound with a measured specific rotation of -40.5°?arrow_forwardThe process to determine the configuration, starts by placing the lowest priority substituent toward the back. If the substituents pointing forward decrease in priority in a clockwise order, the configuration is S. If the substituents decrease in priority in a counterclockwise order, the configuration is R. True Falsearrow_forward
- In the drawing area below, create a hemiacetal with 1 hydroxyl group, 1 methoxy group, and a total of 3 carbon atoms. Click and drag to start drawing a structure. Explanation Check Х PO 18 Ar B © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center | Accessibilityarrow_forwardPredict the product of the reaction below (3 pts). hydrazine Ph H₂NNH2 KOH Write the mechanism for the above reaction using curved arrows to show electron movements. show all intermediates in the process (7 pts).arrow_forward↓ Feedback (8/10) Draw the major product of this reaction. Ignore inorganic byproducts. Incorrect, 2 attempts remaining N H3O+ 0 × Select to Draw + V Retryarrow_forward
- 2. Calculate the branching ratio of the reaction of the methyl peroxy radical with either HO, NO 298K) (note: rate constant can be found in the tropospheric chemistry ppt CH,O,+NO-HCHO+HO, + NO, CH₂O+HO, CH₂00H +0₂ when the concentration of hydroperoxyl radical is DH01-1.5 x 10 molecules and the nitrogen oxide maxing ratio of 10 ppb when the concentration of hydroperoxyl radicalis [H0] +1.5x10 molecules cm" and the nitrogen oxide mixing ratio of 30 p Under which condition do you expect more formaldehyde to be produced and whyarrow_forwardIndicate the product of the reaction of benzene with 1-chloro-2,2-dimethylpropane in the presence of AlCl3.arrow_forwardIn what position will N-(4-methylphenyl)acetamide be nitrated and what will the compound be called.arrow_forward
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