
CHEMISTRY: MOLECULAR. W/ACCESS >IC<
16th Edition
ISBN: 9781323463840
Author: Tro
Publisher: PEARSON C
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Question
Chapter 16, Problem 81E
(a)
Interpretation Introduction
To determine: The
(b)
Interpretation Introduction
To determine: The
(c)
Interpretation Introduction
To determine: The
(d)
Interpretation Introduction
To determine: The
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Part I.
a)
Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone
b) Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone
(3,3-dimethyl-2-butanone) and 2, 3-dimethyl - 1,3-butadiene. Give reasonable mechanism
the formation of
the products
For
3. The explosive decomposition of 2 mole of TNT (2,4,6-trinitrotoluene) is shown below:
Assume the C(s) is soot-basically atomic carbon (although it isn't actually atomic carbon in real life).
2
CH3
H
NO2
NO2
3N2 (g)+7CO (g) + 5H₂O (g) + 7C (s)
H
a. Use bond dissociation energies to calculate how much AU is for this reaction in kJ/mol.
Part I.
Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff:
Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone
and
(3,3-dimethyl-2-butanone) 2,3-dimethyl-1,3-butadiene. Give reasonable mechanism
the formation of the products
For
Chapter 16 Solutions
CHEMISTRY: MOLECULAR. W/ACCESS >IC<
Ch. 16 - Prob. 1SAQCh. 16 - Q2. Which pair is a Brønsted–Lowry conjugate...Ch. 16 - Prob. 3SAQCh. 16 - Prob. 4SAQCh. 16 - Q5. An HNO3(aq) solution has a pH of 1.75. What is...Ch. 16 - Q6. Find the pH of a 0.350 M aqueous benzoic acid...Ch. 16 - Q7. Find the pH of a 0.155 M HClO2(aq) solution....Ch. 16 - Prob. 8SAQCh. 16 - Prob. 9SAQCh. 16 - Prob. 10SAQ
Ch. 16 - Prob. 11SAQCh. 16 - Prob. 12SAQCh. 16 - Prob. 13SAQCh. 16 - Prob. 14SAQCh. 16 - Q15. Which acid has the largest Ka: HClO2(aq),...Ch. 16 - 1. What causes heartburn? What are some possible...Ch. 16 - 2. What are the general physical and chemical...Ch. 16 - Prob. 3ECh. 16 - Prob. 4ECh. 16 - Prob. 5ECh. 16 - Prob. 6ECh. 16 - Prob. 7ECh. 16 - Prob. 8ECh. 16 - Prob. 9ECh. 16 - Prob. 10ECh. 16 - 11. What are diprotic and triprotic acids? List an...Ch. 16 - 12. Define the acid ionization constant and...Ch. 16 - 13. Write an equation for the autoionization of...Ch. 16 - 14. What happens to the [OH–] of a solution when...Ch. 16 - Prob. 15ECh. 16 - Prob. 16ECh. 16 - Prob. 17ECh. 16 - Prob. 18ECh. 16 - Prob. 19ECh. 16 - Prob. 20ECh. 16 - Prob. 21ECh. 16 - 22. How can you determine if an anion will act as...Ch. 16 - 23. What is the relationship between the acid...Ch. 16 - 24. What kinds of cations act as weak acids? List...Ch. 16 - 25. When calculating the [H3O+] for a polyprotic...Ch. 16 - Prob. 26ECh. 16 - Prob. 27ECh. 16 - Prob. 28ECh. 16 - Prob. 29ECh. 16 - Prob. 30ECh. 16 -
31. What is acid rain? What causes it, and where...Ch. 16 - Prob. 32ECh. 16 - 33. Identify each substance as an acid or a base...Ch. 16 - 34. Identify each substance as an acid or a base...Ch. 16 - 35. In each reaction, identify the Brønsted–Lowry...Ch. 16 - Prob. 36ECh. 16 - 37. Write the formula for the conjugate base of...Ch. 16 - 38. Write the formula for the conjugate acid of...Ch. 16 - 39. Both H2O and H2PO4– are amphoteric. Write an...Ch. 16 - 40. Both HCO3– and HS– are amphoteric. Write an...Ch. 16 - Prob. 41ECh. 16 - Prob. 42ECh. 16 - Prob. 43ECh. 16 - Prob. 44ECh. 16 - Prob. 45ECh. 16 - Prob. 46ECh. 16 - 47. Calculate [OH–] in each aqueous solution at 25...Ch. 16 - Prob. 48ECh. 16 - Prob. 49ECh. 16 - 50. Calculate [H3O+] and [OH–] for each solution...Ch. 16 - Prob. 51ECh. 16 - Prob. 52ECh. 16 - 53. Like all equilibrium constants, the value of...Ch. 16 - Prob. 54ECh. 16 - 55. Calculate the pH of each acid solution....Ch. 16 - Prob. 56ECh. 16 - Prob. 57ECh. 16 - 58. Determine the pH of each solution.
a. 0.048 M...Ch. 16 - Prob. 59ECh. 16 - Prob. 60ECh. 16 - 61. What is the pH of a solution in which 224 mL...Ch. 16 - Prob. 62ECh. 16 - Prob. 63ECh. 16 - 64. Determine the [H3O+] and pH of a 0.200 M...Ch. 16 - 65. Determine the pH of an HNO2 solution of each...Ch. 16 - 66. Determine the pH of an HF solution of each...Ch. 16 - Prob. 67ECh. 16 - Prob. 68ECh. 16 - Prob. 69ECh. 16 - Prob. 70ECh. 16 - 71. Determine the percent ionization of a 0.125 M...Ch. 16 - Prob. 72ECh. 16 - Prob. 73ECh. 16 - Prob. 74ECh. 16 - Prob. 75ECh. 16 - Prob. 76ECh. 16 - Prob. 77ECh. 16 - Prob. 78ECh. 16 - Prob. 79ECh. 16 - Prob. 80ECh. 16 - Prob. 81ECh. 16 - Prob. 82ECh. 16 - Prob. 83ECh. 16 - Prob. 84ECh. 16 - Prob. 85ECh. 16 - Prob. 86ECh. 16 - Prob. 87ECh. 16 - Prob. 88ECh. 16 - Prob. 89ECh. 16 - Prob. 90ECh. 16 - Prob. 91ECh. 16 - Prob. 92ECh. 16 - Prob. 93ECh. 16 - Prob. 94ECh. 16 - Prob. 95ECh. 16 - Prob. 96ECh. 16 - 97. Determine the [OH–] and pH of a solution that...Ch. 16 - Prob. 98ECh. 16 - Prob. 99ECh. 16 - Prob. 100ECh. 16 - Prob. 101ECh. 16 - 102. Determine if each salt will form a solution...Ch. 16 - Prob. 103ECh. 16 - Prob. 104ECh. 16 - 105. Determine the pH of each solution.
a. 0.10 M...Ch. 16 - 106. Determine the pH of each solution.
a. 0.20 M...Ch. 16 - Prob. 107ECh. 16 - Prob. 108ECh. 16 - Prob. 109ECh. 16 - Prob. 110ECh. 16 - Prob. 111ECh. 16 - 112. Calculate the [H3O+] and pH of each...Ch. 16 - 113. Calculate the concentration of all species in...Ch. 16 - 114. Calculate the concentration of all species in...Ch. 16 - 115. Calculate the [H3O+] and pH of each H2SO4...Ch. 16 - Prob. 116ECh. 16 - Prob. 117ECh. 16 - Prob. 118ECh. 16 - 119. Based on their molecular structure, pick the...Ch. 16 - Prob. 120ECh. 16 - Prob. 121ECh. 16 - 122. Which is a stronger base, PO43– or AsO43–?...Ch. 16 - 123. Classify each species as either a Lewis acid...Ch. 16 - 124. Classify each species as either a Lewis acid...Ch. 16 - Prob. 125ECh. 16 - Prob. 126ECh. 16 - Prob. 127ECh. 16 - Prob. 128ECh. 16 - Prob. 129ECh. 16 - Prob. 130ECh. 16 - Prob. 131ECh. 16 - Prob. 132ECh. 16 - 133. Acid rain over the Great Lakes has a pH of...Ch. 16 - 134. White wines tend to be more acidic than red...Ch. 16 - 135. Common aspirin is acetylsalicylic acid, which...Ch. 16 - Prob. 136ECh. 16 - Prob. 137ECh. 16 - Prob. 138ECh. 16 - Prob. 139ECh. 16 - 140. Determine the pH of each two-component...Ch. 16 - Prob. 141ECh. 16 - Prob. 142ECh. 16 - 143. The pH of a 1.00 M solution of urea, a weak...Ch. 16 - 144. A solution is prepared by dissolving 0.10 mol...Ch. 16 - 145. Lactic acid is a weak acid found in milk. Its...Ch. 16 - Prob. 146ECh. 16 - Prob. 147ECh. 16 - Prob. 148ECh. 16 - Prob. 149ECh. 16 - 150. To what volume should you dilute 1 L of a...Ch. 16 - Prob. 151ECh. 16 - Prob. 152ECh. 16 -
153. Calculate the pH of a solution prepared from...Ch. 16 - 154. To 1.0 L of a 0.30 M solution of HClO2 is...Ch. 16 - 155. A mixture of Na2CO3 and NaHCO3 has a mass of...Ch. 16 - 156. A mixture of NaCN and NaHSO4 consists of a...Ch. 16 - 157. Without doing any calculations, determine...Ch. 16 - 158. Without doing any calculations, determine...Ch. 16 - Prob. 159ECh. 16 - 160. Without using a calculator, determine the pH...Ch. 16 - Prob. 161QGWCh. 16 - Prob. 162QGWCh. 16 - Prob. 163QGWCh. 16 - Prob. 164QGWCh. 16 - Prob. 165QGWCh. 16 - 166. Sulfur dioxide protects wine from spoiling;...
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