The plausible mechanism for the formation of the product B has to be proposed. Concept introduction: There are mainly three types of pericyclic reactions, 1) Electrocyclic reactions 2) Cycloaddition reactions 3) Sigmatropic reactions In a cycloaddition reaction “ two new sigma-bonds are formed or brocken” Click reaction: Azide reaction with alkyne in the presence of CuSO 4 and provides trazole as a product.

Question

Want to see the full answer?

Answer 1

Question

Chapter 16, Problem 78CP

(a)

Interpretation Introduction

Interpretation:

The plausible mechanism for the formation of the product B has to be proposed.

Concept introduction:

There are mainly three types of pericyclic reactions,

1) Electrocyclic reactions

2) Cycloaddition reactions

3) Sigmatropic reactions

In a cycloaddition reaction “ two new sigma-bonds are formed or brocken”

Click reaction:

Azide reaction with alkyne in the presence of CuSO4 and provides trazole as a product.

(b)

Interpretation Introduction

Interpretation:

The structure of compound C has to be drawn.

Concept introduction:

There are mainly three types of pericyclic reactions,

1) Electrocyclic reactions

2) Cycloaddition reactions

3) Sigmatropic reactions

In a cycloaddition reaction “ two new sigma-bonds are formed or brocken”

Click reaction:

Azide reaction with alkyne in the presence of CuSO4 and provides trazole as a product.

(c)

Interpretation Introduction

Interpretation:

The reason for decrease in rate if the alkyne A is replaced by alkynes from D-F has to be determined.

Concept introduction:

Angle strain: The strain experienced because of existence of the non-bonded interactions of the atoms which are placed spatially close to each other is called the angle strain.

The angle strain will be very much low for sp-hybridised carbon in linear alkyne but is more in cyclic alkyne.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

2. Calculate the branching ratio of the reaction of the methyl peroxy radical with either HO, NO 298K) (note: rate constant can be found in the tropospheric chemistry ppt CH,O,+NO-HCHO+HO, + NO, CH₂O+HO, CH₂00H +0₂ when the concentration of hydroperoxyl radical is DH01-1.5 x 10 molecules and the nitrogen oxide maxing ratio of 10 ppb when the concentration of hydroperoxyl radicalis [H0] +1.5x10 molecules cm" and the nitrogen oxide mixing ratio of 30 p Under which condition do you expect more formaldehyde to be produced and why

Indicate the product of the reaction of benzene with 1-chloro-2,2-dimethylpropane in the presence of AlCl3.

In what position will N-(4-methylphenyl)acetamide be nitrated and what will the compound be called.

Answer 2

Question

Chapter 16, Problem 78CP

(a)

Interpretation Introduction

Interpretation:

The plausible mechanism for the formation of the product B has to be proposed.

Concept introduction:

There are mainly three types of pericyclic reactions,

1) Electrocyclic reactions

2) Cycloaddition reactions

3) Sigmatropic reactions

In a cycloaddition reaction “ two new sigma-bonds are formed or brocken”

Click reaction:

Azide reaction with alkyne in the presence of CuSO4 and provides trazole as a product.

(b)

Interpretation Introduction

Interpretation:

The structure of compound C has to be drawn.

Concept introduction:

There are mainly three types of pericyclic reactions,

1) Electrocyclic reactions

2) Cycloaddition reactions

3) Sigmatropic reactions

In a cycloaddition reaction “ two new sigma-bonds are formed or brocken”

Click reaction:

Azide reaction with alkyne in the presence of CuSO4 and provides trazole as a product.

(c)

Interpretation Introduction

Interpretation:

The reason for decrease in rate if the alkyne A is replaced by alkynes from D-F has to be determined.

Concept introduction:

Angle strain: The strain experienced because of existence of the non-bonded interactions of the atoms which are placed spatially close to each other is called the angle strain.

The angle strain will be very much low for sp-hybridised carbon in linear alkyne but is more in cyclic alkyne.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Chapter 16, Problem 78CP

(a)

Interpretation Introduction

Interpretation:

The plausible mechanism for the formation of the product B has to be proposed.

Concept introduction:

There are mainly three types of pericyclic reactions,

1) Electrocyclic reactions

2) Cycloaddition reactions

3) Sigmatropic reactions

In a cycloaddition reaction “ two new sigma-bonds are formed or brocken”

Click reaction:

Azide reaction with alkyne in the presence of CuSO4 and provides trazole as a product.

(b)

Interpretation Introduction

Interpretation:

The structure of compound C has to be drawn.

Concept introduction:

There are mainly three types of pericyclic reactions,

1) Electrocyclic reactions

2) Cycloaddition reactions

3) Sigmatropic reactions

In a cycloaddition reaction “ two new sigma-bonds are formed or brocken”

Click reaction:

Azide reaction with alkyne in the presence of CuSO4 and provides trazole as a product.

(c)

Interpretation Introduction

Interpretation:

The reason for decrease in rate if the alkyne A is replaced by alkynes from D-F has to be determined.

Concept introduction:

Angle strain: The strain experienced because of existence of the non-bonded interactions of the atoms which are placed spatially close to each other is called the angle strain.

The angle strain will be very much low for sp-hybridised carbon in linear alkyne but is more in cyclic alkyne.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Chapter 16, Problem 78CP

(a)

Interpretation Introduction

Interpretation:

The plausible mechanism for the formation of the product B has to be proposed.

Concept introduction:

There are mainly three types of pericyclic reactions,

1) Electrocyclic reactions

2) Cycloaddition reactions

3) Sigmatropic reactions

In a cycloaddition reaction “ two new sigma-bonds are formed or brocken”

Click reaction:

Azide reaction with alkyne in the presence of CuSO4 and provides trazole as a product.

(b)

Interpretation Introduction

Interpretation:

The structure of compound C has to be drawn.

Concept introduction:

There are mainly three types of pericyclic reactions,

1) Electrocyclic reactions

2) Cycloaddition reactions

3) Sigmatropic reactions

In a cycloaddition reaction “ two new sigma-bonds are formed or brocken”

Click reaction:

Azide reaction with alkyne in the presence of CuSO4 and provides trazole as a product.

(c)

Interpretation Introduction

Interpretation:

The reason for decrease in rate if the alkyne A is replaced by alkynes from D-F has to be determined.

Concept introduction:

Angle strain: The strain experienced because of existence of the non-bonded interactions of the atoms which are placed spatially close to each other is called the angle strain.

The angle strain will be very much low for sp-hybridised carbon in linear alkyne but is more in cyclic alkyne.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 5

Chapter 16, Problem 78CP

(a)

Interpretation Introduction

Interpretation:

The plausible mechanism for the formation of the product B has to be proposed.

Concept introduction:

There are mainly three types of pericyclic reactions,

1) Electrocyclic reactions

2) Cycloaddition reactions

3) Sigmatropic reactions

In a cycloaddition reaction “ two new sigma-bonds are formed or brocken”

Click reaction:

Azide reaction with alkyne in the presence of CuSO4 and provides trazole as a product.

(b)

Interpretation Introduction

Interpretation:

The structure of compound C has to be drawn.

Concept introduction:

There are mainly three types of pericyclic reactions,

1) Electrocyclic reactions

2) Cycloaddition reactions

3) Sigmatropic reactions

In a cycloaddition reaction “ two new sigma-bonds are formed or brocken”

Click reaction:

Azide reaction with alkyne in the presence of CuSO4 and provides trazole as a product.

(c)

Interpretation Introduction

Interpretation:

The reason for decrease in rate if the alkyne A is replaced by alkynes from D-F has to be determined.

Concept introduction:

Angle strain: The strain experienced because of existence of the non-bonded interactions of the atoms which are placed spatially close to each other is called the angle strain.

The angle strain will be very much low for sp-hybridised carbon in linear alkyne but is more in cyclic alkyne.

Answer 6

Chapter 16, Problem 78CP

(a)

Interpretation Introduction

Interpretation:

The plausible mechanism for the formation of the product B has to be proposed.

Concept introduction:

There are mainly three types of pericyclic reactions,

1) Electrocyclic reactions

2) Cycloaddition reactions

3) Sigmatropic reactions

In a cycloaddition reaction “ two new sigma-bonds are formed or brocken”

Click reaction:

Azide reaction with alkyne in the presence of CuSO4 and provides trazole as a product.

Answer 7

Chapter 16, Problem 78CP

(a)

Interpretation Introduction

Interpretation:

The plausible mechanism for the formation of the product B has to be proposed.

Concept introduction:

There are mainly three types of pericyclic reactions,

1) Electrocyclic reactions

2) Cycloaddition reactions

3) Sigmatropic reactions

In a cycloaddition reaction “ two new sigma-bonds are formed or brocken”

Click reaction:

Azide reaction with alkyne in the presence of CuSO4 and provides trazole as a product.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The structure of compound C has to be drawn.

Concept introduction:

There are mainly three types of pericyclic reactions,

1) Electrocyclic reactions

2) Cycloaddition reactions

3) Sigmatropic reactions

In a cycloaddition reaction “ two new sigma-bonds are formed or brocken”

Click reaction:

Azide reaction with alkyne in the presence of CuSO4 and provides trazole as a product.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The structure of compound C has to be drawn.

Concept introduction:

There are mainly three types of pericyclic reactions,

1) Electrocyclic reactions

2) Cycloaddition reactions

3) Sigmatropic reactions

In a cycloaddition reaction “ two new sigma-bonds are formed or brocken”

Click reaction:

Azide reaction with alkyne in the presence of CuSO4 and provides trazole as a product.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The reason for decrease in rate if the alkyne A is replaced by alkynes from D-F has to be determined.

Concept introduction:

Angle strain: The strain experienced because of existence of the non-bonded interactions of the atoms which are placed spatially close to each other is called the angle strain.

The angle strain will be very much low for sp-hybridised carbon in linear alkyne but is more in cyclic alkyne.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The reason for decrease in rate if the alkyne A is replaced by alkynes from D-F has to be determined.

Concept introduction:

Angle strain: The strain experienced because of existence of the non-bonded interactions of the atoms which are placed spatially close to each other is called the angle strain.

The angle strain will be very much low for sp-hybridised carbon in linear alkyne but is more in cyclic alkyne.

Answer 12

Expert Solution & Answer

Answer 13

Expert Solution & Answer

Answer 14

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 15

Ch. 16.1 - Prob. 1CC Ch. 16.2 - Prob. 2CC Ch. 16.2 - Prob. 3CC Ch. 16.2 - Prob. 4CC Ch. 16.3 - Prob. 5CC Ch. 16.4 - Prob. 1LTS Ch. 16.4 - Prob. 6PTS Ch. 16.4 - Prob. 7PTS Ch. 16.4 - Prob. 8ATS Ch. 16.5 - Prob. 2LTS

Concept explainers

Want to see the full answer?

Chapter 16 Solutions