ORGANIC CHEMISTRY (LL) W/ACCESS
ORGANIC CHEMISTRY (LL) W/ACCESS
4th Edition
ISBN: 9781119856122
Author: Klein
Publisher: WILEY
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Chapter 16, Problem 72IP
Interpretation Introduction

Interpretation:

The reactivity of nitroethylene and ethylene in a Diels-Alder reaction should be compared.

Concept introduction:

  • Diels-Alder reaction is a [4+2] cycloaddition reaction, in which a π-system having four atoms (diene) and a π-system having two atoms (dienophile) are undergoing in cycloaddition reaction and producing a substituted cyclohexene.
  • The reactivity of dienophiles are depending upon the substituents attached to it, the electron-withdrawing substituent such as carbonyl groups or nitro-groups activate the dienophile for Diels-Alder reaction by making the dienophiles more reactive to dienes.

To compare: the reactivity of nitroethylene and ethylene in a Diels-Alder reaction.

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