EBK INTRODUCTORY CHEMISTRY: AN ACTIVE L
6th Edition
ISBN: 9780100547506
Author: CRACOLICE
Publisher: YUZU
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Chapter 16, Problem 5CLE
Interpretation Introduction
Interpretation:
A brief description of the relationships among normality, equivalent, and equivalent mass is to be stated.
Concept introduction:
The concentration of the solution is made up of compounds that can be expressed in many terms as per need. Some of the examples of concentration terms used in the chemistry are molarity, normality, molality mass by volume and mass by mass.
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(a
4 shows scanning electron microscope (SEM) images of extruded
actions of packing bed for two capillary columns of different diameters,
al 750 (bottom image) and b) 30-μm-i.d. Both columns are packed with the
same stationary phase, spherical particles with 1-um diameter.
A) When the columns were prepared, the figure shows that the column with
the larger diameter has more packing irregularities. Explain this observation.
B) Predict what affect this should have on band broadening and discuss your
prediction using the van Deemter terms.
C) Does this figure support your explanations in application question 33?
Explain why or why not and make any changes in your answers in light of
this figure.
Figure 4 SEM images of
sections of packed columns
for a) 750 and b) 30-um-i.d.
capillary columns.³
fcrip
= ↓ bandwidth Il temp
32. What impact (increase, decrease, or no change) does each of the following conditions have on the individual
components of the van Deemter equation and consequently, band broadening?
Increase temperature
Longer column
Using a gas mobile phase
instead of liquid
Smaller particle stationary phase
Multiple Paths
Diffusion
Mass Transfer
34. Figure 3 shows Van Deemter plots for a solute molecule using different column inner diameters (i.d.).
A) Predict whether decreasing the column inner diameters increase or decrease bandwidth.
B) Predict which van Deemter equation coefficient (A, B, or C) has the greatest effect on increasing or
decreasing bandwidth as a function of i.d. and justify your answer.
Figure 3 Van Deemter plots for hydroquinone using different column inner diameters (i.d. in μm). The data was
obtained from liquid chromatography experiments using fused-silica capillary columns packed with 1.0-μm particles.
35
20
H(um)
큰 20
15
90
0+
1500
100
75
550
01
02
594
05
μ(cm/sec)
30
15
10
Chapter 16 Solutions
EBK INTRODUCTORY CHEMISTRY: AN ACTIVE L
Ch. 16 - Mixtures of gases are always true solutions. True...Ch. 16 - Every pure substance has a definite and fixed set...Ch. 16 - Can you see particles in a solution? If yes, give...Ch. 16 - What kinds of solute particles are present in a...Ch. 16 - Distinguish between the solute and solvent in each...Ch. 16 - Explain why the distinction between solute and...Ch. 16 - Prob. 7ECh. 16 - Prob. 8ECh. 16 - What happens if you add a very small amount of...Ch. 16 - Prob. 10E
Ch. 16 - Prob. 11ECh. 16 - Prob. 12ECh. 16 - Prob. 13ECh. 16 - Prob. 14ECh. 16 - Prob. 15ECh. 16 - What does it mean to say that a solute particle is...Ch. 16 - Prob. 17ECh. 16 - Prob. 18ECh. 16 - Describe the changes that occur between the time...Ch. 16 - Prob. 20ECh. 16 - Prob. 21ECh. 16 - Prob. 22ECh. 16 - Prob. 23ECh. 16 - Prob. 24ECh. 16 - Prob. 25ECh. 16 - Prob. 26ECh. 16 - Prob. 27ECh. 16 - Which of the following solutes do you expect to be...Ch. 16 - Prob. 29ECh. 16 - Prob. 30ECh. 16 - Prob. 31ECh. 16 - Prob. 32ECh. 16 - Prob. 33ECh. 16 - Prob. 34ECh. 16 - Prob. 35ECh. 16 - Prob. 36ECh. 16 - Prob. 37ECh. 16 - A student weighs out a 4.80-g sample of aluminum...Ch. 16 - Prob. 39ECh. 16 - Prob. 40ECh. 16 - Prob. 41ECh. 16 - Prob. 42ECh. 16 - Potassium hydroxide is used in making liquid soap....Ch. 16 - You need to make an aqueous solution of 0.123M...Ch. 16 - What volume of concentrated sulfuric acid, which...Ch. 16 - Prob. 46ECh. 16 - Prob. 47ECh. 16 - Prob. 48ECh. 16 - Prob. 49ECh. 16 - Prob. 50ECh. 16 - Despite its intense purple color, potassium...Ch. 16 - Prob. 52ECh. 16 - 53. The density of 3.30M potassium nitrate is...Ch. 16 - Prob. 54ECh. 16 - Prob. 55ECh. 16 - Prob. 56ECh. 16 - Prob. 57ECh. 16 - Prob. 58ECh. 16 - Prob. 59ECh. 16 - Prob. 60ECh. 16 - Prob. 61ECh. 16 - Prob. 62ECh. 16 - Prob. 63ECh. 16 - Prob. 64ECh. 16 - Prob. 65ECh. 16 - Prob. 66ECh. 16 - Prob. 67ECh. 16 - Prob. 68ECh. 16 - What are the equivalent mass of Cu(OH)2 and...Ch. 16 - Prob. 70ECh. 16 - Prob. 71ECh. 16 - Prob. 72ECh. 16 - Prob. 73ECh. 16 - Prob. 74ECh. 16 - Prob. 75ECh. 16 - Prob. 76ECh. 16 - Prob. 77ECh. 16 - Prob. 78ECh. 16 - Prob. 79ECh. 16 - Prob. 80ECh. 16 - Prob. 81ECh. 16 - Prob. 82ECh. 16 - What is the molarity of the acetic acid solution...Ch. 16 - Prob. 84ECh. 16 - Prob. 85ECh. 16 - Prob. 86ECh. 16 - Prob. 87ECh. 16 - Prob. 88ECh. 16 - Prob. 89ECh. 16 - Prob. 90ECh. 16 - Prob. 91ECh. 16 - Prob. 92ECh. 16 - Calculate the mass of calcium phosphate that will...Ch. 16 - How many milliliters of 0.464M nitric acid...Ch. 16 - Prob. 95ECh. 16 - Prob. 96ECh. 16 - What volume of 0.842M sodium hydroxide solution...Ch. 16 - Prob. 98ECh. 16 - The equation for a reaction by which a solution of...Ch. 16 - Potassium hydrogen phthalate is a solid,...Ch. 16 - Prob. 101ECh. 16 - Oxalic acid dihydrate is a solid, diprotic acid...Ch. 16 - A student finds that 37.80mL of a 0.4052MNaHCO3...Ch. 16 - Prob. 104ECh. 16 - Prob. 105ECh. 16 - Prob. 106ECh. 16 - Prob. 107ECh. 16 - Prob. 108ECh. 16 - Prob. 109ECh. 16 - Prob. 110ECh. 16 - Prob. 111ECh. 16 - Prob. 112ECh. 16 - Prob. 113ECh. 16 - Prob. 114ECh. 16 - Prob. 115ECh. 16 - Prob. 116ECh. 16 - Prob. 117ECh. 16 - The specific gravity of a solution of KCl is...Ch. 16 - A student dissolves 27.2g of aniline, C6H5NH2, in...Ch. 16 - Prob. 120ECh. 16 - Prob. 121ECh. 16 - Prob. 122ECh. 16 - Prob. 123ECh. 16 - Prob. 124ECh. 16 - Prob. 125ECh. 16 - Prob. 126ECh. 16 - When 12.4g of an unknown solute is dissolved in...Ch. 16 - Prob. 128ECh. 16 - Prob. 129ECh. 16 - When 19.77g of glucose, C6H12O6(180.2g/mol), is...Ch. 16 - Prob. 131ECh. 16 - Prob. 132ECh. 16 - When you heat water on a stove, small bubbles...Ch. 16 - Antifreeze is put into the water in an automobile...Ch. 16 - Prob. 135ECh. 16 - Prob. 136ECh. 16 - Prob. 137ECh. 16 - Prob. 138ECh. 16 - Prob. 139ECh. 16 - Prob. 140ECh. 16 - The density of 18.0%HCl is 1.09g/mL. Calculate its...Ch. 16 - Prob. 142ECh. 16 - Prob. 143ECh. 16 - Prob. 144ECh. 16 - Prob. 145ECh. 16 - A student adds 25.0mL of 0.350M sodium hydroxide...Ch. 16 - Prob. 147ECh. 16 - An analytical procedure for finding the chloride...Ch. 16 - Prob. 149ECh. 16 - Prob. 150ECh. 16 - Prob. 151ECh. 16 - A chemist combines 60.0mL of 0.322M potassium...Ch. 16 - A solution is defined as a homogeneous mixture. Is...Ch. 16 - Prob. 154ECh. 16 - Prob. 16.1TCCh. 16 - 0.100gof A is dissolved in 1.00 103mL of water,...Ch. 16 - Prob. 16.3TCCh. 16 - If you are given the structural formulas of two...Ch. 16 - Prob. 1CLECh. 16 - Prob. 2CLECh. 16 - Write a brief description of the relationships...Ch. 16 - Prob. 4CLECh. 16 - Prob. 5CLECh. 16 - Write a brief description of the relationships...Ch. 16 - Prob. 1PECh. 16 - What mass of sodium chloride and what volume of...Ch. 16 - Prob. 3PECh. 16 - Prob. 4PECh. 16 - Prob. 5PECh. 16 - Prob. 6PECh. 16 - Prob. 7PECh. 16 - Determine the number of equivalents of acid and...Ch. 16 - Prob. 9PECh. 16 - Prob. 10PECh. 16 - Prob. 11PECh. 16 - Prob. 12PECh. 16 - Prob. 13PECh. 16 - Prob. 14PECh. 16 - Prob. 15PECh. 16 - Prob. 16PECh. 16 - What volume of 0.105M lithium nitrate must be...Ch. 16 - Prob. 18PECh. 16 - Prob. 19PECh. 16 - Prob. 20PECh. 16 - Prob. 21PECh. 16 - Prob. 22PECh. 16 - The freezing point of cyclohexane is 6.50C, and...
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Solutions: Crash Course Chemistry #27; Author: Crash Course;https://www.youtube.com/watch?v=9h2f1Bjr0p4;License: Standard YouTube License, CC-BY