LL ORG CHEM
LL ORG CHEM
6th Edition
ISBN: 9781264840083
Author: SMITH
Publisher: MCG
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From the following potentials, calculate the activity of Cl- in saturated KCl. E0 (calomel electrode)= 0.268 V E (calomel electrode, saturated KCl)= 0.241 V
Calculate the voltage of each of the following cells. a) Fe(s)/Fe2+ (1.55 x 10-2 M)//Cu2+ (6.55 x 10-3 M)/Cu(s) b) Pt, H2 (0.255 bar)/HCl (4.55 x 10-4 M), AgCl (sat'd)/Ag Fe2+ +2e- = Fe   E0= -0.44 V Cu2+ + 2e- = Cu  E0= 0.337 V Ag+ + e- = Ag   E0= 0.799 V AgCl(s) + e- = Ag(s) + Cl-  E0= 0.222 V 2H+ + 2e- = H2   E0= 0.000 V
A solution contains 0.097 M Ce3+, 1.55x10-3 M Ce4+, 1.55x10-3 M Mn2+, 0.097 M MnO4-, and 1.00 M HClO4 (F= 9.649 x 104 C/mol). a) Write a balanced net reaction that can occur between species in this solution. b) Calculate deltaG0 and K for the reaction. c) Calculate E and deltaG for the conditions given. Ce4+ + e- = Ce3+  E0= 1.70 V MnO4- + 8H+ + 5e- = Mn2+ + 4H2O   E0= 1.507 V
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