CHEMISTRY
2nd Edition
ISBN: 9781593995782
Author: OpenStax
Publisher: XANEDU PUBLISHING
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Chapter 16, Problem 36E
Is the formation of ozone (O3(g)) from oxygen (O2(g)) spontaneous at room temperature under standard state conditions?
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Technetium is the first element in the periodic chart that does not have any stable isotopes.
Technetium-99m is an especially interesting and valuable isotope as it emits a gamma ray with a half
life ideally suited for medical tests. It would seem that the decay of technetium should fit the
treatment above with the result In(c/c) = -kt. The table below includes data from the two sites:
http://dailymed.nlm.nih.gov/dailymed/druginfo.cfm?id=7130
http://wiki.medpedia.com/Clinical: Neutrospec_(Technetium_(99m Tc)_fanolesomab).
a.
b.
C.
Graph the fraction (c/c.) on the vertical axis versus the time on the horizontal axis. Also
graph In(c/c.) on the vertical axis versus time on the horizontal axis.
When half of the original amount of starting material has hours fraction remaining
disappeared, c/c = ½ and the equation In(c/c.) = -kt becomes
In(0.5) = -kt1/2 where t₁₂ is the half life (the time for half of the
material to decay away). Determine the slope of your In(c/c.) vs
t graph and…
Please correct answer and don't use hand rating
1.
a) Assuming that an atom of arsenic has hydrogen-like atomic orbitals, sketch the radial
probability plots for 4p and 4d orbitals of S atom. Indicate angular and radial nodes in
these orbitals.
(4 points)
b) Calculate Zeff experienced by and electron in 4p AO's in a arsenic atom. Use Slater rules
that were discussed in lecture.
(3 points)
Chapter 16 Solutions
CHEMISTRY
Ch. 16 - What is a spontaneous reaction?Ch. 16 - What is a nonspontaneous reaction?Ch. 16 - Indicate whether the following processes are...Ch. 16 - A helium-filled balloon spontaneously deflates...Ch. 16 - Many plastic materials are organic polymers that...Ch. 16 - In Figure 16.8 all possible distributions and...Ch. 16 - In Figure 16.8 all of the possible distributions...Ch. 16 - How does the process described in the previous...Ch. 16 - Consider a system similar to the one in Figure...Ch. 16 - Consider the system shown in Figure 16.9. What is...
Ch. 16 - Consider the system shown in Figure 16.9. What is...Ch. 16 - Arrange the following sets of systems in order of...Ch. 16 - At room temperature, the entropy of the halogens...Ch. 16 - Consider two processes: sublimation of I2(s) and...Ch. 16 - Indicate which substance in the given pairs has...Ch. 16 - Predict the sign of the entropy change for the...Ch. 16 - Predict the sign of the entropy change for the...Ch. 16 - Write the balanced chemical equation for the...Ch. 16 - Write the balanced chemical equation for the...Ch. 16 - What is the difference between S, S , and S 298...Ch. 16 - Calculate S298 for the following changes. (a)...Ch. 16 - Determine the entropy change for the combustion of...Ch. 16 - Determine the entropy change for the combustion of...Ch. 16 - Thermite reactions have been used for welding...Ch. 16 - Using the relevant S 298 values listed in Appendix...Ch. 16 - From the following information, determine S298 for...Ch. 16 - By calculating Suniv, at each temperature,...Ch. 16 - Use the standard entropy data in Appendix G to...Ch. 16 - Use the standard entropy data in Appendix G to...Ch. 16 - What is the difference between G, G, and G 298 for...Ch. 16 - A reaction has H298=100 kj/mol and S298=250 J/mol ...Ch. 16 - Explain what happens as a reaction starts with G0...Ch. 16 - Use the standard free energy of formation data in...Ch. 16 - Use the standard free energy data in Appendix G to...Ch. 16 - Given: P4(s)+5O2(g)P4O10(s)G298=2697.0kJ/mol...Ch. 16 - Is the formation of ozone (O3(g)) from oxygen...Ch. 16 - Consider the decomposition of red mercury(II)...Ch. 16 - Among other things, an ideal fuel for the control...Ch. 16 - Calculate G for each of the following reactions...Ch. 16 - Calculate G for each of the following reactions...Ch. 16 - Calculate the equilibrium constant at 25 C for...Ch. 16 - Calculate the equilibrium constant at 25 C for...Ch. 16 - Calculate the equilibrium constant temperature...Ch. 16 - Calculate the equilibrium constant temperature...Ch. 16 - Consider the following reaction at 298 K:...Ch. 16 - Determine the normal boiling point (in kelvin) of...Ch. 16 - Under what conditions is N2O3(g)NO(g)+NO2(g)...Ch. 16 - At mom temperature, the equilibrium constant (Kw)...Ch. 16 - Hydrogen sulfide is a pollutant found in natural...Ch. 16 - Consider the decomposition of CaCO3(s) into CaO(s)...Ch. 16 - In the laboratory, hydrogen chloride (HCl(g)) and...Ch. 16 - Benzene can be prepared from acetylene....Ch. 16 - Carbon dioxide decomposes into CO and O2 at...Ch. 16 - Carbon tetrachloride, an important industrial...Ch. 16 - Acetic acid, CH3CO2H, can form a dimer,...Ch. 16 - Nitric acid, HNO3, can be prepared by the...Ch. 16 - Determine G for the following reactions. (a)...Ch. 16 - Given that the Gf for Pb2+(aq) and Cl-(aq) is...Ch. 16 - Determine the standard free energy change, Gf, for...Ch. 16 - Determine the standard enthalpy change, entropy...Ch. 16 - The evaporation of one mole of water at 298 K has...Ch. 16 - In glycolysis, the reaction of glucose (Glu) to...Ch. 16 - One of the important reactions in the biochemical...Ch. 16 - Without doing a numerical calculation, determine...Ch. 16 - When ammonium chloride is added to water and...Ch. 16 - An important source of copper is from the copper...Ch. 16 - What happens to G (becomes more negative or more...
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