Essential Organic Chemistry Study Guide & Solution Manual, Books a la Carte Edition
Essential Organic Chemistry Study Guide & Solution Manual, Books a la Carte Edition
3rd Edition
ISBN: 9780134255644
Author: Bruice, Paula Yurkanis
Publisher: PEARSON
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Chapter 16, Problem 34P

a)

Interpretation Introduction

Interpretation:

The structure of βD-talopyranose is to be drawn.

Concept Introduction:

The structural representation of sugar molecule in cyclic form is known as Haworth projection.  Sugar molecule that has six-membered-ring is known as pyranose and sugar molecule that has five-membered-ring is called furanose.  A sugar molecule in which hydroxyl groups of first and sixth carbon atom are on the same side is known as α sugar, otherwise β sugar.

b)

Interpretation Introduction

Interpretation:

The structure of αD-idopyranose is to be drawn.

Concept Introduction:

The structural representation of sugar molecule in cyclic form is known as Haworth projection. Sugar molecule that has six-membered-ring is known as pyranose and sugar molecule that has five-membered-ring is called furanose. A sugar molecule in which hydroxyl groups of first and sixth carbon atom are on the same side is known as α sugar, otherwise β sugar.

c)

Interpretation Introduction

Interpretation:

The structure of αD-tagatopyranose is to be drawn.

Concept Introduction:

The structural representation of sugar molecule in cyclic form is known as Haworth projection.  Sugar molecule that has six-membered-ring is known as pyranose and sugar molecule that has five-membered-ring is called furanose.  A sugar molecule in which hydroxyl groups of first and sixth carbon atom are on the same side is known as α sugar, otherwise β sugar.

d)

Interpretation Introduction

Interpretation:

The structure of βD-psicofuranose is to be drawn.

Concept Introduction:

The structural representation of sugar molecule in cyclic form is known as Haworth projection.  Sugar molecule that has six-membered-ring is known as pyranose and sugar molecule that has five-membered-ring is called furanose.  A sugar molecule in which hydroxyl groups of first and sixth carbon atom are on the same side is known as α sugar, otherwise β sugar.

e)

Interpretation Introduction

Interpretation:

The structure of βL-talopyranose is to be drawn.

Concept Introduction:

The structural representation of sugar molecule in cyclic form is known as Haworth projection. Sugar molecule that has six-membered-ring is known as pyranose and sugar molecule that has five-membered-ring is called furanose. A sugar molecule in which hydroxyl groups of first and sixth carbon atom are on the same side is known as α sugar, otherwise β sugar.

f)

Interpretation Introduction

Interpretation:

The structure of αL-tagatopyranose is to be drawn.

Concept Introduction:

The structural representation of sugar molecule in cyclic form is known as Haworth projection.  Sugar molecule that has six-membered-ring is known as pyranose and sugar molecule that has five-membered-ring is called furanose.  A sugar molecule in which hydroxyl groups of first and sixth carbon atom are on the same side is known as α sugar, otherwise β sugar.

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There are 48 pairs of students in the following table. Each pair has quantitatively determined the mass of taurine in a 250 mL can of the popular energy drink marketed as “Munster” using High Performance Liquid Chromatography (HPLC). The class results are presented below:  QUESTION: Calculate the measurement of uncertainty and provide the data in a spreadsheet table.   Mass of Taurine (mg) Mass of Taurine (mg) (Table continued) 152.01 152.23 151.87 151.45 154.11 152.64 152.98 153.24 152.88 151.45 153.49 152.48 150.68 152.33 151.52 153.63 152.48 151.68 153.17 153.40 153.77 153.67 152.34 153.16 152.57 153.02 152.86 151.50 151.23 152.57 152.72 151.54 146.47 152.38 152.44 152.54 152.53 152.54 151.32 152.87 151.24 153.26 152.02 152.90 152.87 151.49 152.46 152.58
1. Predict the organic product(s) of the following reactions. Assume excess of reagents unless otherwise noted. a) &l BH3 •THF b) 1) NaOH 2) H3O+ solve d) ala 1) EtMgBr 2) H3O+ e) H2N سكر CuLi NH2 1) SOCI2 2) EtMgBr 3) H3O+ NC H3O+ Δ
There are 48 pairs of students in the following table. Each pair has quantitatively determined the mass of taurine in a 250 mL can of the popular energy drink marketed as “Munster” using High Performance Liquid Chromatography (HPLC). The class results are presented below:  QUESTION: Summarise and report these results including an indication of measurement uncertainty.  In both calculation samples calculate if an outlier is present, max value, number of samples, mean, standard deviation, g (suspect), g (critical) and t (critical).   Mass of Taurine (mg) Mass of Taurine (mg) (Table continued) 152.01 152.23 151.87 151.45 154.11 152.64 152.98 153.24 152.88 151.45 153.49 152.48 150.68 152.33 151.52 153.63 152.48 151.68 153.17 153.40 153.77 153.67 152.34 153.16 152.57 153.02 152.86 151.50 151.23 152.57 152.72 151.54 146.47 152.38 152.44 152.54 152.53 152.54 151.32…
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