If CH 3 COO − acts as a strong base, a weak base or a species with negligible basicity; the formula of its conjugate acid; if this conjugate acid is a strong acid, a weak acid or a species with negligible acidity.

Question

Write structural formulas for the major products by doing addition reactions 1. You must add H2 as Pt is catalyst it does not take part in reactions only speed up the process H₂ CH2=CH-CH3 Pt 2. Add HCI break it into H and Cl CH3 HCI 3. Add Br2 only CC14 is catalyst CH3-CH=CH2 B12 CCl4 4. Add water to this and draw major product, H2SO4 is catalyst you have add water H20 in both the reaction below H₂SO4 CH3-CH=CH2 CH3 H2SO4/H₂O CH3-C=CH2 reflux ?

Answer 1

Question

Chapter 16, Problem 21E

(a)

Interpretation Introduction

To determine: If CH3COO− acts as a strong base, a weak base or a species with negligible basicity; the formula of its conjugate acid; if this conjugate acid is a strong acid, a weak acid or a species with negligible acidity.

(b)

Interpretation Introduction

To determine: If HCO3− acts as a strong base, a weak base or a species with negligible basicity; the formula of its conjugate acid; if this conjugate acid is a strong acid, a weak acid or a species with negligible acidity.

(c)

Interpretation Introduction

To determine: If O2− acts as a strong base, a weak base or a species with negligible basicity; the formula of its conjugate acid; if this conjugate acid is a strong acid, a weak acid or a species with negligible acidity.

(d)

Interpretation Introduction

To determine: If Cl− acts as a strong base, a weak base or a species with negligible basicity; the formula of its conjugate acid; if this conjugate acid is a strong acid, a weak acid or a species with negligible acidity.

(e)

Interpretation Introduction

To determine: If NH3 acts as a strong base, a weak base or a species with negligible basicity; the formula of its conjugate acid; if this conjugate acid is a strong acid, a weak acid or a species with negligible acidity.

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Write structural formulas for the major products by doing addition reactions 1. You must add H2 as Pt is catalyst it does not take part in reactions only speed up the process H₂ CH2=CH-CH3 Pt 2. Add HCI break it into H and Cl CH3 HCI 3. Add Br2 only CC14 is catalyst CH3-CH=CH2 B12 CCl4 4. Add water to this and draw major product, H2SO4 is catalyst you have add water H20 in both the reaction below H₂SO4 CH3-CH=CH2 CH3 H2SO4/H₂O CH3-C=CH2 reflux ?

Plan the synthesis of the following compound using the starting material provided and any other reagents needed as long as carbon based reagents have 3 carbons or less. Either the retrosynthesis or the forward synthesis (mechanisms are not required but will be graded if provided) will be accepted if all necessary reagents and intermediates are shown (solvents and temperature requirements are not needed unless specifically involved in the reaction, i.e. DMSO in the Swern oxidation or heat in the KMnO4 oxidation). H H

Hint These are benzene substitution reactions. ALCI3 and UV light are catalyst no part in reactions and triangle A means heating. A. Add ethyl for Et in benzene ring alkylation reaction EtCl = CH3CH2CL 1) EtC1 / AlCl3 / A ? B: Add Br to benzene ring ( substitution) 2) Br₂ / uv light ? C Add (CH3)2 CHCH2 in benzene ring ( substitution) (CH3)2CHCH,C1 / AICI, ?

Answer 2

Question

Chapter 16, Problem 21E

(a)

Interpretation Introduction

To determine: If CH3COO− acts as a strong base, a weak base or a species with negligible basicity; the formula of its conjugate acid; if this conjugate acid is a strong acid, a weak acid or a species with negligible acidity.

(b)

Interpretation Introduction

To determine: If HCO3− acts as a strong base, a weak base or a species with negligible basicity; the formula of its conjugate acid; if this conjugate acid is a strong acid, a weak acid or a species with negligible acidity.

(c)

Interpretation Introduction

To determine: If O2− acts as a strong base, a weak base or a species with negligible basicity; the formula of its conjugate acid; if this conjugate acid is a strong acid, a weak acid or a species with negligible acidity.

(d)

Interpretation Introduction

To determine: If Cl− acts as a strong base, a weak base or a species with negligible basicity; the formula of its conjugate acid; if this conjugate acid is a strong acid, a weak acid or a species with negligible acidity.

(e)

Interpretation Introduction

To determine: If NH3 acts as a strong base, a weak base or a species with negligible basicity; the formula of its conjugate acid; if this conjugate acid is a strong acid, a weak acid or a species with negligible acidity.

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Answer 3

Question

Chapter 16, Problem 21E

(a)

Interpretation Introduction

To determine: If CH3COO− acts as a strong base, a weak base or a species with negligible basicity; the formula of its conjugate acid; if this conjugate acid is a strong acid, a weak acid or a species with negligible acidity.

(b)

Interpretation Introduction

To determine: If HCO3− acts as a strong base, a weak base or a species with negligible basicity; the formula of its conjugate acid; if this conjugate acid is a strong acid, a weak acid or a species with negligible acidity.

(c)

Interpretation Introduction

To determine: If O2− acts as a strong base, a weak base or a species with negligible basicity; the formula of its conjugate acid; if this conjugate acid is a strong acid, a weak acid or a species with negligible acidity.

(d)

Interpretation Introduction

To determine: If Cl− acts as a strong base, a weak base or a species with negligible basicity; the formula of its conjugate acid; if this conjugate acid is a strong acid, a weak acid or a species with negligible acidity.

(e)

Interpretation Introduction

To determine: If NH3 acts as a strong base, a weak base or a species with negligible basicity; the formula of its conjugate acid; if this conjugate acid is a strong acid, a weak acid or a species with negligible acidity.

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Answer 4

Question

Chapter 16, Problem 21E

(a)

Interpretation Introduction

To determine: If CH3COO− acts as a strong base, a weak base or a species with negligible basicity; the formula of its conjugate acid; if this conjugate acid is a strong acid, a weak acid or a species with negligible acidity.

(b)

Interpretation Introduction

To determine: If HCO3− acts as a strong base, a weak base or a species with negligible basicity; the formula of its conjugate acid; if this conjugate acid is a strong acid, a weak acid or a species with negligible acidity.

(c)

Interpretation Introduction

To determine: If O2− acts as a strong base, a weak base or a species with negligible basicity; the formula of its conjugate acid; if this conjugate acid is a strong acid, a weak acid or a species with negligible acidity.

(d)

Interpretation Introduction

To determine: If Cl− acts as a strong base, a weak base or a species with negligible basicity; the formula of its conjugate acid; if this conjugate acid is a strong acid, a weak acid or a species with negligible acidity.

(e)

Interpretation Introduction

To determine: If NH3 acts as a strong base, a weak base or a species with negligible basicity; the formula of its conjugate acid; if this conjugate acid is a strong acid, a weak acid or a species with negligible acidity.

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Answer 5

Chapter 16, Problem 21E

(a)

Interpretation Introduction

To determine: If CH3COO− acts as a strong base, a weak base or a species with negligible basicity; the formula of its conjugate acid; if this conjugate acid is a strong acid, a weak acid or a species with negligible acidity.

(b)

Interpretation Introduction

To determine: If HCO3− acts as a strong base, a weak base or a species with negligible basicity; the formula of its conjugate acid; if this conjugate acid is a strong acid, a weak acid or a species with negligible acidity.

(c)

Interpretation Introduction

To determine: If O2− acts as a strong base, a weak base or a species with negligible basicity; the formula of its conjugate acid; if this conjugate acid is a strong acid, a weak acid or a species with negligible acidity.

(d)

Interpretation Introduction

To determine: If Cl− acts as a strong base, a weak base or a species with negligible basicity; the formula of its conjugate acid; if this conjugate acid is a strong acid, a weak acid or a species with negligible acidity.

(e)

Interpretation Introduction

To determine: If NH3 acts as a strong base, a weak base or a species with negligible basicity; the formula of its conjugate acid; if this conjugate acid is a strong acid, a weak acid or a species with negligible acidity.

Answer 6

Chapter 16, Problem 21E

(a)

Interpretation Introduction

To determine: If CH3COO− acts as a strong base, a weak base or a species with negligible basicity; the formula of its conjugate acid; if this conjugate acid is a strong acid, a weak acid or a species with negligible acidity.

Answer 7

Chapter 16, Problem 21E

(a)

Interpretation Introduction

To determine: If CH3COO− acts as a strong base, a weak base or a species with negligible basicity; the formula of its conjugate acid; if this conjugate acid is a strong acid, a weak acid or a species with negligible acidity.

Answer 8

(b)

Interpretation Introduction

To determine: If HCO3− acts as a strong base, a weak base or a species with negligible basicity; the formula of its conjugate acid; if this conjugate acid is a strong acid, a weak acid or a species with negligible acidity.

Answer 9

(b)

Interpretation Introduction

To determine: If HCO3− acts as a strong base, a weak base or a species with negligible basicity; the formula of its conjugate acid; if this conjugate acid is a strong acid, a weak acid or a species with negligible acidity.

Answer 10

(c)

Interpretation Introduction

To determine: If O2− acts as a strong base, a weak base or a species with negligible basicity; the formula of its conjugate acid; if this conjugate acid is a strong acid, a weak acid or a species with negligible acidity.

Answer 11

(c)

Interpretation Introduction

To determine: If O2− acts as a strong base, a weak base or a species with negligible basicity; the formula of its conjugate acid; if this conjugate acid is a strong acid, a weak acid or a species with negligible acidity.

Answer 12

(d)

Interpretation Introduction

To determine: If Cl− acts as a strong base, a weak base or a species with negligible basicity; the formula of its conjugate acid; if this conjugate acid is a strong acid, a weak acid or a species with negligible acidity.

Answer 13

(d)

Interpretation Introduction

To determine: If Cl− acts as a strong base, a weak base or a species with negligible basicity; the formula of its conjugate acid; if this conjugate acid is a strong acid, a weak acid or a species with negligible acidity.

Answer 14

(e)

Interpretation Introduction

To determine: If NH3 acts as a strong base, a weak base or a species with negligible basicity; the formula of its conjugate acid; if this conjugate acid is a strong acid, a weak acid or a species with negligible acidity.

Answer 15

(e)

Interpretation Introduction

To determine: If NH3 acts as a strong base, a weak base or a species with negligible basicity; the formula of its conjugate acid; if this conjugate acid is a strong acid, a weak acid or a species with negligible acidity.

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Ch. 16.2 - Practice Exercise 1 Consider the following...Ch. 16.2 - Prob. 16.1.2PE Ch. 16.2 - Prob. 16.2.1PE Ch. 16.2 - Practice Exercise 2 When lithium oxide (Li2O) is...Ch. 16.2 - Based on information in Figure 16.4, place the...Ch. 16.2 - Practice Exercise 2 For each reaction, use Figure...Ch. 16.3 - Practice Exercise 1 In a certain acidic solution...Ch. 16.3 - Practice Exercise 2 Indicate whether solutions...Ch. 16.3 - Prob. 16.5.1PE Ch. 16.3 - Prob. 16.5.2PE

If CH 3 COO − acts as a strong base, a weak base or a species with negligible basicity; the formula of its conjugate acid; if this conjugate acid is a strong acid, a weak acid or a species with negligible acidity.

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To determine: If CH3COO− acts as a strong base, a weak base or a species with negligible basicity; the formula of its conjugate acid; if this conjugate acid is a strong acid, a weak acid or a species with negligible acidity.

To determine: If HCO3− acts as a strong base, a weak base or a species with negligible basicity; the formula of its conjugate acid; if this conjugate acid is a strong acid, a weak acid or a species with negligible acidity.

To determine: If O2− acts as a strong base, a weak base or a species with negligible basicity; the formula of its conjugate acid; if this conjugate acid is a strong acid, a weak acid or a species with negligible acidity.

To determine: If Cl− acts as a strong base, a weak base or a species with negligible basicity; the formula of its conjugate acid; if this conjugate acid is a strong acid, a weak acid or a species with negligible acidity.

To determine: If NH3 acts as a strong base, a weak base or a species with negligible basicity; the formula of its conjugate acid; if this conjugate acid is a strong acid, a weak acid or a species with negligible acidity.

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