Student Solutions Manual to accompany Atkins' Physical Chemistry 11th  edition
Student Solutions Manual to accompany Atkins' Physical Chemistry 11th edition
11th Edition
ISBN: 9780198807773
Author: ATKINS
Publisher: Oxford University Press
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Chapter 16, Problem 16C.6AE
Interpretation Introduction

Interpretation:

The effective radius of a sucrose molecule in water has to be calculated at 25 °C.

Concept introduction:

Viscosity is called the property of a fluid that is “a measure of its resistance to flow”.  It is the consequence of a molecular attraction and denotes the internal friction of a moving fluid.  A fluid with high viscosity resists motion due to its high molecular interaction.  The substances with low intermolecular interaction have lower viscosity.

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Q1: For each molecule, assign each stereocenter as R or S. Circle the meso compounds. Label each compound as chiral or achiral. OH HO CI Br H CI CI Br CI CI Xf x f g Br D OH Br Br H₂N R. IN Ill I -N S OMe D II H CO₂H 1/111 DuckDuckG
These are synthesis questions. You need to show how the starting material can be converted into the product(s) shown. You may use any reactions we have learned. Show all the reagents you need. Show each molecule synthesized along the way and be sure to pay attention to the regiochemistry and stereochemistry preferences for each reaction. If a racemic molecule is made along the way, you need to draw both enantiomers and label the mixture as "racemic". All of the carbon atoms of the products must come from the starting material! ? H H
Q5: Draw every stereoisomer for 1-bromo-2-chloro-1,2-difluorocyclopentane. Clearly show stereochemistry by drawing the wedge-and-dashed bonds. Describe the relationship between each pair of the stereoisomers you have drawn.

Chapter 16 Solutions

Student Solutions Manual to accompany Atkins' Physical Chemistry 11th edition

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